Prediction of Orbital Ordering in Single-Layered Ruthenates

The key role of the orbital degree of freedom to understand the magnetic properties of layered ruthenates is here discussed. In the G-type antiferromagnetic phase of Ca$_2$RuO$_4$, recent X-ray experiments reported the presence of 0.5 hole per site in the $d_{xy}$ orbital, while the $d_{\rm yz}$ and $d_{zx}$ orbitals contain 1.5 holes. This unexpected $t_{2g}$ hole distribution is explained by a novel state with orbital ordering (OO), stabilized by a combination of Coulomb interactions and lattice distortions. In addition, the rich phase diagram presented here suggests the possibility of large magnetoresistance effects, and predicts a new ferromagnetic OO phase in ruthenates.Comment: 4 pages, Revtex, with 2 figures embedded in the text. Submitted to Phys. Rev. Let

Orbital Properties of Sr3Ru2O7 and Related Ruthenates Probed by 17O-NMR

We report a site-separated $^{17}$O-NMR study of the layered perovskite ruthenate Sr$_3$Ru$_2$O$_7$, which exhibits nearly two-dimensional transport properties and itinerant metamagnetism at low temperatures. The local hole occupancies and the spin densities in the oxygen $2p$ orbitals are obtained by means of tight-binding analyses of electric field gradients and anisotropic Knight shifts. These quantities are compared with two other layered perovskite ruthenates: the two-dimensional paramagnet Sr$_2$RuO$_4$ and the three-dimensional ferromagnet SrRuO$_3$. The hole occupancies at the oxygen sites are very large, about one hole per ruthenium atom. This is due to the strong covalent character of the Ru-O bonding in this compound. The magnitude of the hole occupancy might be related to the rotation or tilt of the RuO$_6$ octahedra. The spin densities at the oxygen sites are also large, 20-40% of the bulk susceptibilities, but in contrast to the hole occupancies, the spin densities strongly depend on the dimensionality. This result suggests that the density-of-states at the oxygen sites plays an essential role for the understanding of the complex magnetism found in the layered perovskite ruthenates.Comment: 9 pages, 5 figures, to be published in Phys. Rev.

Magnetic ordering in Sr2RuO4 induced by nonmagnetic impurities

We report unusual effects of nonmagnetic impurities on the spin-triplet superconductor Sr2RuO4. The substitution of nonmagnetic Ti4+ for Ru4+ induces localized-moment magnetism characterized by unexpected Ising anisotropy with the easy axis along the interlayer c direction. Furthermore, for x(Ti) > 0.03 magnetic ordering occurs in the metallic state with the remnant magnetization along the c-axis. We argue that the localized moments are induced in the Ru4+ and/or oxygen ions surrounding Ti4+ and that the ordering is due to their interaction mediated by itinerant Ru-4d electrons with strong spin fluctuations.Comment: 5 pages, 4figure

Characteristics of the wavelength of ripples on icicles

It is known that the wavelength of the ripples on icicles in nature is of centimeter-scale. Such study on morphological instability of ice-water interface during ice growth from flowing supercooled water film with one side being a free surface has recently been made [K. Ueno, Phys. Rev. E 68, 021603 (2003)]. This is a first theoretical study taking into account the influence of the shape of the water-air surface on the growth condition of infinitesimal disturbances of the ice-water interface. A simpler formula to determine the wavelength of the ripples than that in the previous paper is derived. It seems that the wavelength of ripples is insensitive to the water supply rates, diameters of the icicles and surrounding air temperatures. The details of dependence of the wavelengh of ripples on these parameters are investigated.Comment: 15 pages, 6 figure

Multiple first-order metamagnetic transitions and quantum oscillations in ultrapure

We present measurements on ultra clean single crystals of the bilayered ruthenate metal Sr3Ru2O7, which has a magnetic-field-tuned quantum critical point. Quantum oscillations of differing frequencies can be seen in the resistivity both below and above its metamagnetic transition. This frequency shift corresponds to a small change in the Fermi surface volume that is qualitatively consistent with the small moment change in the magnetisation across the metamagnetic transition. Very near the metamagnetic field, unusual behaviour is seen. There is a strong enhancement of the resistivity in a narrow field window, with a minimum in the resistivity as a function of temperature below 1 K that becomes more pronounced as the disorder level decreases. The region of anomalous behaviour is bounded at low temperatures by two first-order phase transitions. The implications of the results are discussed. PACS: 68.35.Rh, 71.27.+a, 72.15.-v, 74.70.PqComment: 12 pages 4 figures, submitte

Observation of Andreev Surface Bound States in the 3-K phase Region of Sr_2RuO_4

The tunneling spectrum of the superconducting phase with T_c ~ 3.0 K has been measured in the Ru-embedded region of Sr_2RuO_4 using cleaved junctions. A sharp zero-bias conductance peak (ZBCP) has been observed below 3 K. All characteristics of this ZBCP suggest that it originates from Andreev surface bound states, indicating that the pairing in the 3-K phase is also non-s-wave. Below the bulk T_c of Sr_2RuO_4 (~1.5 K), a bell-shaped ZBCP was found. This supports that there is a phase transition in the 3-K phase region near the bulk T_c.Comment: 4 pages, to appear in Phys. Rev. Lett. 87 (2001

Gap Structure of the Spin-Triplet Superconductor Sr2RuO4 Determined from the Field-Orientation Dependence of Specific Heat

We report the field-orientation dependent specific heat of the spin-triplet superconductor Sr2RuO4 under the magnetic field aligned parallel to the RuO2 planes with high accuracy. Below about 0.3 K, striking 4-fold oscillations of the density of states reflecting the superconducting gap structure have been resolved for the first time. We also obtained strong evidence of multi-band superconductivity and concluded that the superconducting gap in the active band, responsible for the superconducting instability, is modulated with a minimum along the [100] direction.Comment: 4 pages, 4 figure

Cyclotron Resonance in the Layered Perovskite Superconductor Sr2RuO4

We have measured the cyclotron masses in Sr2RuO4 through the observation of periodic-orbit-resonances - a magnetic resonance technique closely related to cyclotron resonance. We obtain values for the alpha, beta and gamma Fermi surfaces of (4.33+/-0.05)me, (5.81+/-0.03)me and (9.71+/-0.11)me respectively. The appreciable differences between these results and those obtained from de Haas- van Alphen measurements are attributable to strong electron-electron interactions in this system. Our findings appear to be consistent with predictions for a strongly interacting Fermi liquid; indeed, semi-quantitative agreement is obtained for the electron pockets beta and gamma.Comment: 4 pages + 3 figure