23,349 research outputs found
Coulomb interaction effects on nonlinear optical response in C60, C70, and higher fullerenes
Nonlinear optical properties in the fullerene C and the extracted
higher fullerenes -- C, C, C, and C -- are
theoretically investigated by using the exciton formalism and the
sum-over-states method. We find that off-resonant third order susceptibilities
of higher fullerenes are a few times larger than those of C. The
magnitude of nonlinearity increases as the optical gap decreases in higher
fullerenes. The nonlinearity is nearly proportional to the fourth power of the
carbon number when the onsite Coulomb repulsion is or , being the
nearest neighbor hopping integral. This result, indicating important roles of
Coulomb interactions, agrees with quantum chemical calculations of higher
fullerenes.Comment: 8 pages; 3 figures; Figures should be requested to the author
(E-mail: [email protected]
Nonlinear ac response of anisotropic composites
When a suspension consisting of dielectric particles having nonlinear
characteristics is subjected to a sinusoidal (ac) field, the electrical
response will in general consist of ac fields at frequencies of the
higher-order harmonics. These ac responses will also be anisotropic. In this
work, a self-consistent formalism has been employed to compute the induced
dipole moment for suspensions in which the suspended particles have nonlinear
characteristics, in an attempt to investigate the anisotropy in the ac
response. The results showed that the harmonics of the induced dipole moment
and the local electric field are both increased as the anisotropy increases for
the longitudinal field case, while the harmonics are decreased as the
anisotropy increases for the transverse field case. These results are
qualitatively understood with the spectral representation. Thus, by measuring
the ac responses both parallel and perpendicular to the uniaxial anisotropic
axis of the field-induced structures, it is possible to perform a real-time
monitoring of the field-induced aggregation process.Comment: 14 pages and 4 eps figure
Optical properties of diamond like carbon films prepared by DC-PECVD
Diamond-like carbon (DLC) thin films were deposited at different substrate temperatures using methane and hydrogen gas in DC-PECVD at 2x10-1Torr. From the light transmission using UV-VIS spectroscopy it was found that the optical transition had changed from allowed indirect transition to allowed direct transition as the substrate temperature increased. The Optical gap increased with temperature, highest of 3.034 eV was observed at 573 K, beyond which it dropped. Colour of the film changed from light brownish to a colourless transparent film in the higher temperature. The Urbach energy decreased from 1.25 eV to 0.75 eV with increasing substrate temperature till 573 K and a slight increase after it. This trend is attributed to change in sp3/sp2 ratio or change in structure. The cluster size decreases with temperature, resulting in larger band gap and the structure more ordered. Similar pattern is also witnessed in the emission spectrum of the photoluminescence
Novel method for refinement of retained austenite in micro/nano-structured bainitic steels
A comparative study was conducted to assess the effects of two different heat treatments on the amount and morphology of the retained austenite in a micro/nano-structured bainitic steel. The heat treatments used in this work were two-stage bainitic transformation and bainitic-partitioning transformation. Both methods resulted in the generation of a multi-phase microstructure containing nanoscale bainitic ferrite, and/or fresh martensitic phases and much finer retained austenite. Both heat treatments were verified to be effective in refining the retained austenite in micro/nano-structured bainite and increasing the hardness. However, the bainitic transformation followed by partitioning cycle was proved to be a more viable approach than the two-stage bainitic transformation due to much shorter processing time, i.e. ∼2 h compared to ∼4 day, respectively
Spin Waves in Random Spin Chains
We study quantum spin-1/2 Heisenberg ferromagnetic chains with dilute, random
antiferromagnetic impurity bonds with modified spin-wave theory. By describing
thermal excitations in the language of spin waves, we successfully observe a
low-temperature Curie susceptibility due to formation of large spin clusters
first predicted by the real-space renormalization-group approach, as well as a
crossover to a pure ferromagnetic spin chain behavior at intermediate and high
temperatures. We compare our results of the modified spin-wave theory to
quantum Monte Carlo simulations.Comment: 3 pages, 3 eps figures, submitted to the 47th Conference on Magnetism
and Magnetic Material
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