Universal Phase Diagram for High-Piezoelectric Perovskite Systems

Strong piezoelectricity in the perovskite-type PbZr(1-x)TixO3 (PZT) and Pb(Zn1/3Nb2/3)O3-PbTiO3 (PZN-PT) systems is generally associated with the existence of a morphotropic phase boundary (MPB) separating regions with rhombohedral and tetragonal symmetry. An x-ray study of PZN-9%PT has revealed the presence of a new orthorhombic phase at the MPB, and a near-vertical boundary between the rhombohedral and orthorhombic phases, similar to that found for PZT between the rhombohedral and monoclinic phases. We discuss the results in the light of a recent theoretical paper by Vanderbilt and Cohen, which attributes these low-symmetry phases to the high anharmonicity in these oxide systems.Comment: REVTeX file. 4 pages,=A0 4 figures embedde

Phase transition in Pr0.5Ca0.5CoO3 and related cobaltites

We present an extensive investigation (magnetic, electric and thermal measurements and X-ray absorption spectroscopy) of the Pr0.5Ca0.5CoO3 and (Pr1-yYy)0.7Ca0.3CoO3 (y=0.0625-0.15) perovskites, in which a peculiar metal-insulator (M-I) transition, accompanied with pronounced structural and magnetic anomalies, occurs at 76 K and 40-132 K, respectively. The inspection of the M-I transition using the XANES data of Pr L3-edge and Co K-edge proofs the presence of Pr4+ ions at low temperatures and indicates simultaneously the intermediate spin to low spin crossover of Co species on lowering the temperature. The study thus definitively confirms the synchronicity of the electron transfer between Pr3+ ions and Co^(3+/4+)O3 subsystem and the transition to the low-spin, less electrically conducting phase. The large extent of the transfer is evidenced by the good quantitative agreement of the determined amount of the Pr4+ species, obtained either from the temperature dependence of the XANES spectra or via integration of the magnetic entropy change over the Pr4+ related Schottky peak in the low-temperature specific heat. These results show that the average valence of Pr3+/Pr4+ ions increases (in concomitance with the decrease of the formal Co valence) below TMI for (Pr0.925Y0.075)0.7Ca0.3CoO3 up to 3.16+ (the doping level of the CoO3 subsystem decreases from 3.30+ to 3.20+), for (Pr0.85Y0.15)0.7Ca0.3CoO3 up to 3.28+ (the decrease of doping level from 3.30+ to 3.13+) and for Pr0.5Ca0.5CoO3 up to 3.46+ (the decrease of doping level from 3.50+ to 3.27+).Comment: 19 pages, 11 figure

A new concept of a hybrid trapped field magnet lens

In this paper, a new concept of a hybrid trapped field magnet lens (HTFML) is proposed. The HTMFL exploits the “vortex pinning effect” of an outer superconducting bulk cylinder, which is magnetized as a trapped field magnet (TFM) using field-cooled magnetization (FCM), and the “diamagnetic shielding effect” of an inner bulk magnetic lens to generate a concentrated magnetic field higher than the trapped field from the TFM in the bore of the magnetic lens. This requires that, during the FCM process, the outer cylinder is in the normal state (T > superconducting transition temperature, Tc) and the inner lens is in the superconducting state (T < Tc) when the external magnetizing field is applied, followed by cooling to an appropriate operating temperature, then removing the external field. This is explored for two potential cases: 1) exploiting the difference in Tc of two different bulk materials (“case-1”), e.g. MgB2 (Tc = 39 K) and GdBaCuO (Tc = 92 K) or 2) using the same material for the whole HTFML, e.g., GdBaCuO, but utilizing individually-controlled cryostats, the same cryostat with different cooling loops or coolants, or heaters that keep the outer bulk cylinder at a temperature above Tc to achieve the same desired effect. The HTFML is verified using numerical simulations for “case-1” using an MgB2 cylinder and GdBaCuO lens pair and for “case-2” using a GdBaCuO cylinder and GdBaCuO lens pair. As a result, the HTFML could reliably generate a concentrated magnetic field Bc = 4.73 T with the external magnetizing field Bapp = 3 T in the “case-1, and a higher Bc = 13.49 T with higher Bapp = 10 T in the “case-2,” respectively. This could, for example, be used to enhance the magnetic field in the bore of a bulk superconducting NMR/MRI system to improve its resolution

Simulation study for magnetic levitation in pure water exploiting the ultra-high magnetic field gradient product of a hybrid trapped field magnet lens (HTFML)

A hybrid trapped field magnet lens (HTFML) is a promising device that is able to concentrate a magnetic field higher than the applied field continuously, even after removing an external field, which was conceptually proposed by the authors in 2018. In this study, we propose a new additional advantage of the HTFML, which could be applicable for magnetic levitation and separation. The HTFML device consisting of a GdBaCuO bulk cylinder and a GdBaCuO magnetic lens, after the magnetization process from an applied field, Bapp = 10 T, can generate a maximum trapped field, Bc = 11.4 T, as well as an ultra-high magnetic field gradient product, Bz⋅dBz/dz, over ±3000 T2/m at Ts = 20 K, which is higher than that of existing superconducting magnets and large-scale hybrid magnets. Through detailed numerical simulations, the HTFML device is considered for the magnetic separation of a mixture of precious metal particles (Pt, Au, Ag, and Cu) dispersed in pure water, by exploiting the magneto-Archimedes effect. The HTFML can be realized as a compact and mobile desktop-type superconducting bulk magnet system, and there are a wide range of potential industrial applications, such as in the food and medical industries.Adaptable and Seamless Technology Transfer Program through Target-driven R&D (A-STEP), Japan Science and Technology Agency (JST), Grant No. VP30218088419 JSPS KAKENHI Grant No. 19K0524

Pulsed-Field Magnetizing Characteristics of Rectangular-Shaped Gd-Ba-Cu-O Bulk Using Split- and Solenoid-Type Coils

We have investigated the trapped-held characteristics of a rectangular-shaped Gd-Ba-Cu-O bulk (33 × 33 × 15 mm$^3$) magnetized by pulsed-field magnetization (PFM) using split- and solenoid-type coils. A soft iron yoke was set below the bulk for the solenoid coil and two yokes are inserted in the bores of the split coil. The maximum trapped held B$_{Zmax}$ at the center of the bulk surface was 1.73 T at 40 K in the case of the solenoid coil, with a distorted profile. On the other hand B$_{Zmax}$ was enhanced to 3.05 T at 40 K for the split coil with two yokes for which a symmetric trapped-held profile was observed. The behavior of the magnetic flux motion indicated two conditions for the enhancement of the trapped held: that the magnetic flux intrudes easily into the bulk even for lower applied fields and then saturates with minimal flux creep. We have also investigated the electromagnetic and thermal properties of the bulk during PFM using a numerical simulation in which the magnetic flux tended to align along the z-axis due to the presence of the soft iron yoke. The use of the split coil with two yokes is effective in enhancing the trapped held for the rectangular-shaped bulks.This work was supported by Open Partnership Joint Projects of Japan Society for the Promotion of Science (JSPS) Bilateral Joint Research Projects, and JSPS KAKENHI grant number 23560002 and 15K04646. Dr. Mark Ainslie would like to acknowledge the support of a Royal Academy of Engineering Research Fellowship

The Retroperitoneum Protects Prosthetic Graft Material from Intraperitoneal Contamination: An Experimental Study

AbstractObjectivesTo evaluate the ability of the retroperitoneum to serve as a barrier, against bacterial contamination, between the peritoneal cavity to the retroperitoneal space.MethodsSeventy rats had a small piece of knitted Dacron graft placed in the retroperitoneal space and 106–109 colony forming unit (cfu) Enterococcus faecalis was injected into the peritoneal cavity. In half the retroperitoneal (RP) group, the retroperitoneum was preserved and in the remainder, the open peritoneal (OP) group, needle holes were created. Grafts were harvested after 1, 4, or 7 days and cultured for E. faecalis. A blood sample was collected from three rats in each group for culture before the graft was harvested.ResultsGraft infection did not develop in any rat injected with 106 or 107 cfu in the RP group, while seven out of the 10 graft cultures of the OP group grew E. faecalis (P=0.003). In rats injected with 108 or 109 cfu, five out of the 10 graft cultures in the RP group and eight out of 10 in the OP group grew E. faecalis. All blood cultures were negative when the injected bacterial count was 107 cfu or less. One out of the three blood cultures was positive at 108 cfu, and all were positive at 109 cfu.ConclusionsThese results suggest that an intact retroperitroneum acts as a protective barrier against intraperitoneal bacterial contamination, particularly when blood cultures are negative

Trapped Field Enhancement of a Thin, High-Jc MgB2 Bulk without Flux Jumps using Pulsed Field Magnetization with a Split-type Coil with a Soft Iron Yoke

We have investigated the suppression of flux jumps and the enhancement of trapped field on a thin, high-J$_{c}$ MgB₂ bulk (30 mm in diameter and 7 mm in thickness) for the pulsed field magnetization (PFM) using a split-type coil with a soft iron yoke, and compared the results to those magnetized using the split-type coil without a yoke and a solenoid-type coil with a yoke. A maximum-trapped field, B$_{z}$, of 0.71 T at 14 K was achieved on the bulk surface without flux jumps by using the split coil with yoke. On the other hand, low B$_{z}$ values with flux jumps were observed for the cases using the split-type coil without a soft iron yoke, and the solenoid-type coil with a yoke. These results reproduce previous ones for a thick, high-J$_{c}$ MgB₂ bulk (22 mm in diameter and 15 mm in thickness), for which the trapped field was enhanced to a record high value of B$_{z}$=1.10 T at 13 K by PFM using the split-type coil with a yoke