The pressure-volume-temperature relationship of cellulose

Pressure–volume–temperature (PVT) mea- surements of a-cellulose with different water contents, were performed at temperatures from 25 to 180 °C and pressures from 19.6 to 196 MPa. PVT measurements allowed observation of the combined effects of pressure and temperature on the specific volume during cellulose thermo-compression. All isobars showed a decrease in cellulose specific volume with temperature. This densification is associated with a transition process of the cellulose, occurring at a temperature defined by the inflection point Tt of the isobar curve. Tt decreases from 110 to 40 °C with pressure and is lower as moisture content increases. For isobars obtained at high pressures and high moisture contents, after attaining a minimum, an increase in volume is observed with temperature that may be related to free water evaporation. PVT a-cellulose experimental data was compared with predicted values from a regression analysis of the Tait equations of state, usually applied to synthetic polymers. Good correla- tions were observed at low temperatures and low pressures. The densification observed from the PVT experimental data, at a temperature that decreases with pressure, could result from a sintering phenomenon, but more research is needed to actually understand the cohesion mechanism under these conditions

Precision measurement of the neutron β-decay asymmetry

A new measurement of the neutron β-decay asymmetry A_0 has been carried out by the UCNA Collaboration using polarized ultracold neutrons (UCNs) from the solid deuterium UCN source at the Los Alamos Neutron Science Center. Improvements in the experiment have led to reductions in both statistical and systematic uncertainties leading to A_0=−0.11954(55)_(stat)(98)_(syst), corresponding to the ratio of axial-vector to vector coupling λ ≡ g_A/g_V = −1.2756(30)

Urban informality and confinement: toward a relational framework

In the 21st century, a growing number of people live ‘informal’ lives within fissures between legality and informality. Concomitantly, power relations are increasingly expressed through devices of confinement. While urban informality and confinement are on the rise often occurring simultaneously, scholars have so far studied them separately. By contrast, this article proposes a new framework for analysing urban informality and confinement relationally. It generates new insights into the role of informality in the (re)production of confinement and, vice versa, the role of confinement in shaping informal practices. While these insights are valuable for urban studies in general, the article charts new lines of research on urban marginality. It also discusses how the six articles included in this special issue signal the heuristic potential of this relational framework by empirically examining distinct urban configurations of ‘confined informalities’ and ‘informal confinements’ across the Global North and the Global South

First direct constraints on Fierz interference in free-neutron β decay

Precision measurements of free-neutron β decay have been used to precisely constrain our understanding of the weak interaction. However, the neutron Fierz interference term b_n, which is particularly sensitive to beyond-standard-model tensor currents at the TeV scale, has thus far eluded measurement. Here we report the first direct constraints on this term, finding b_n=0.067±0.005_(stat)^(+0.090)_(−0.061)_(sys), consistent with the standard model. The uncertainty is dominated by absolute energy reconstruction and the linearity of the β spectrometer energy response

MeV-mass dark matter and primordial nucleosynthesis

The annihilation of new dark matter candidates with masses $m_X$ in the MeV range may account for the galactic positrons that are required to explain the 511 keV $\gamma$-ray flux from the galactic bulge. We study the impact of MeV-mass thermal relic particles on the primordial synthesis of $^2$H, $^4$He, and $^7$Li. If the new particles are in thermal equilibrium with neutrinos during the nucleosynthesis epoch they increase the helium mass fraction for m_X\alt 10 MeV and are thus disfavored. If they couple primarily to the electromagnetic plasma they can have the opposite effect of lowering both helium and deuterium. For $m_X=4$--10 MeV they can even improve the overall agreement between the predicted and observed $^2$H and $^4$He abundances.Comment: 11 pages, 10 figures, references and two appendices added, conclusions unchanged; accepted for publication in Phys.Rev.

A diffuse scattering model of ultracold neutrons on wavy surfaces

Metal tubes plated with nickel-phosphorus are used in many fundamental physics experiments using ultracold neutrons (UCN) because of their ease of fabrication. These tubes are usually polished to a average roughness of 25-150 nm. However, there is no scattering model that accurately describes UCN scattering on such a rough guide surface with a mean-square roughness larger than 5 nm. We therefore developed a scattering model for UCN in which scattering from random surface waviness with a size larger than the UCN wavelength is described by a microfacet Bidirectional Reflectance Distribution Function model (mf-BRDF model), and scattering from smaller structures by the Lambert's cosine law (Lambert model). For the surface waviness, we used the statistical distribution of surface slope measured by an atomic force microscope on a sample piece of guide tube as input of the model. This model was used to describe UCN transmission experiments conducted at the pulsed UCN source at J-PARC. In these experiments, a UCN beam collimated to a divergence angle smaller than $\pm 6^{\circ}$ was directed into a guide tube with a mean-square roughness of 6.4 nm to 17 nm at an oblique angle, and the UCN transport performance and its time-of-flight distribution were measured while changing the angle of incidence. The mf-BRDF model combined with the Lambert model with scattering probability $p_{L} = 0.039\pm0.003$ reproduced the experimental results well. We have thus established a procedure to evaluate the characteristics of UCN guide tubes with a surface roughness of approximately 10 nm.Comment: 15 pages, 11 figure

Tryptophan catabolites in bipolar disorder: a meta-analysis

Objective Tryptophan catabolites (TRYCATs) are implicated in the pathophysiology of mood disorders by mediating immune-inflammation and neurodegenerative processes. We performed a meta-analysis of TRYCAT levels in bipolar disorder (BD) patients compared to healthy controls.MethodsA systematic literature search in seven electronic databases (PubMed, Embase, Web of Science, Cochrane, Emcare, PsycINFO, Academic Search Premier) was conducted on TRYCAT levels in cerebrospinal fluid or peripheral blood according to the PRISMA statement. A minimum of three studies per TRYCAT was required for inclusion. Standardized mean differences (SMD) were computed using random effect models. Subgroup analyses were performed for BD patients in a different mood state (depressed, manic). The methodological quality of the studies was rated using the modified Newcastle-Ottawa Quality assessment Scale.ResultsTwenty-one eligible studies were identified. Peripheral levels of tryptophan (SMD = -0.44; p Stress-related psychiatric disorders across the life spa