3,484 research outputs found
Structural Features of Layered Iron Pnictide Oxides (Fe2As2)(Sr4M2O6)
Structural features of newly found perovskite-based iron pnictide oxide
system have been systematically studied. Compared to REFePnO system,
perovskite-based system tend to have lower Pn-Fe-Pn angle and higher pnictogen
height owing to low electronegativity of alkaline earth metal and small
repulsive force between pnictogen and oxygen atoms. As-Fe-As angles of
(Fe2As2)(Sr4Cr2O6), (Fe2As2)(Sr4V2O6) and (Fe2Pn2)(Sr4MgTiO6) are close to
ideal tetrahedron and those pnictogen heights of about 1.40 A are close to
NdFeAsO with optimized carrier concentration. These structural features of this
system may leads to realization of high Tc superconductivity.Comment: 3pages, 2figures, 1table, proceedings of M2S 200
Superconductivity at 38 K in Iron-Based Compound with Platinum-Arsenide Layers Ca10(Pt4As8)(Fe2-xPtxAs2)5
We report superconductivity in novel iron-based compounds
Ca10(PtnAs8)(Fe2-xPtxAs2)5 with n = 3 and 4. Both compounds crystallize in
triclinic structures (space group P-1), in which Fe2As2 layers alternate with
PtnAs8 spacer layers. Superconductivity with a transition temperature of 38 K
is observed in the n = 4 compound with a Pt content of x ~ 0.36 in the Fe2As2
layers. The compound with n = 3 exhibits superconductivity at 13 K.Comment: OPEN SELECT article, 11 pages, 5 figures, 2 table
Effects of metallic spacer in layered superconducting Sr2(MgTi)O3FeAs
The highly two-dimensional superconducting system
Sr2(MgTi)O3FeAs, recently synthesized in the range of 0.2 < y <
0.5, shows an Mg concentration-dependent . Reducing the Mg concentration
from y=0.5 leads to a sudden increase in , with a maximum ~40 K at
y=0.2. Using first principles calculations, the unsynthesized stoichiometric
y=0 and the substoichiometric y=0.5 compounds have been investigated. For the
50% Mg-doped phase (y=0.5), Sr2(MgTi)O3 layers are completely
insulating spacers between FeAs layers, leading to the fermiology such as that
found for other Fe pnictides. At y=0, representing a phase with metallic
Sr2TiO3 layers, the -centered Fe-derived Fermi surfaces (FSs)
considerably shrink or disappear. Instead, three -centered Ti FSs
appear, and in particular two of them have similar size, like in MgB2.
Interestingly, FSs have very low Fermi velocity in large fractions: the lowest
being 0.6 cm/s. Furthermore, our fixed spin moment calculations
suggest the possibility of magnetic ordering, with magnetic Ti and nearly
nonmagnetic Fe ions. These results indicate a crucial role of
Sr2(MgTi)O3 layers in this superconductivity.Comment: 7 pages; Proceedings of ICSM-201
Pressure Dependence of Superconducting Transition Temperature on Perovskite-Type Fe-Based Superconductors and NMR Study of Sr2VFeAsO3
We report the pressure dependences of the superconducting transition
temperature (T_c) in several perovskite-type Fe-based superconductors through
the resistivity measurements up to ~4 GPa. In Ca_4(Mg,Ti)_3Fe_2As_2O_y with the
highest T_c of 47 K in the present study, the T_c keeps almost constant up to
~1 GPa, and starts to decrease above it. From the comparison among several
systems, we obtained a tendency that low T_c with the longer a-axis length at
ambient pressure increases under pressure, but high T_c with the shorter a-axis
length at ambient pressure hardly increases. We also report the ^75As-NMR
results on Sr_2VFeAsO_3. NMR spectrum suggests that the magnetic ordering
occurs at low temperatures accompanied by some inhomogeneity. In the
superconducting state, we confirmed the anomaly by the occurrence of
superconductivity in the nuclear spin lattice relaxation rate 1/T_1, but the
spin fluctuations unrelated with the superconductivity are dominant. It is
conjectured that the localized V-3d moments are magnetically ordered and their
electrons do not contribute largely to the Fermi surface and the
superconductivity in Sr_2VFeAsO_3.Comment: 7 pages, 9 figure
A New Iron Pnictide Oxide (Fe2As2)(Ca5(Mg,Ti)4Oy) and a New Phase in Fe-As-Ca-Mg-Ti-O system
A new layered iron arsenide oxide (Fe2As2)(Ca5(Mg,Ti)4Oy) and its structural
derivative were found in the Fe-As-Ca-Mg-Ti-O system. The crystal structure of
(Fe2As2)(Ca5(Mg,Ti)4Oy) is identical to that of (Fe2As2)(Ca5(Sc,Ti)4Oy), which
was reported in our previous study. The lattice constants of this compound are
a = 3.86(4) A and c = 41.05(2) A. In addition, another phase with a thicker
blocking layer was found. The structure of the compound and its derivative was
tentatively assigned through STEM observation as (Fe2As2)(Ca8(Mg,Ti)6Oy) with
sextuple perovskite-type sheets divided by a rock salt layer. The interlayer
Fe-Fe distance of this compound is ~30 A. The compound and its derivative
exhibited bulk superconductivity, as found from magnetization and resistivity
measurements.Comment: 9 pages, 7 figure
Evidence for Nodal superconductivity in SrScFePO
Point contact Andreev reflection spectra have been taken as a function of
temperature and magnetic field on the polycrystalline form of the newly
discovered iron-based superconductor Sr2ScFePO3. A zero bias conductance peak
which disappears at the superconducting transition temperature, dominates all
of the spectra. Data taken in high magnetic fields show that this feature
survives until 7T at 2K and a flattening of the feature is observed in some
contacts. Here we inspect whether these observations can be interpreted within
a d-wave, or nodal order parameter framework which would be consistent with the
recent theoretical model where the height of the P in the Fe-P-Fe plane is key
to the symmetry of the superconductivity. However, in polycrystalline samples
care must be taken when examining Andreev spectra to eliminate or take into
account artefacts associated with the possible effects of Josephson junctions
and random alignment of grains.Comment: Published versio
Initial vs. non-initial placement of agent constructions in spoken clauses: A corpus-based study of language production under time pressure
In this exploratory study we test the hypothesis that the retrieval from memory of proper noun Agents (PNAs) under processing pressure causes a greater proportion of such semantic arguments to be placed to the right of the initial position in a clause than would be the case if such retrieval from memory were not necessary. This effect is manifest in sports commentary. Processing pressure on sports commentators is modulated by the speed at which the sport is played and reported. Non-initial placement is also facilitated by formulae which have slots in non-initial position. It follows that the non-initial placement of PNAs is not always semantically or pragmatically motivated. This finding therefore runs counter to a strong form of the functionalist hypothesis that syntactic choices available in the systemic structure of the syntax of a language offer solely semantic or pragmatic choices. It is an open question in a weak functionalist account of language and language use how processing and communicative functions interact in general
Evolution of superconductivity by oxygen annealing in FeTe0.8S0.2
Oxygen annealing dramatically improved the superconducting properties of
solid-state-reacted FeTe0.8S0.2, which showed only a broad onset of
superconducting transition just after the synthesis. The zero resistivity
appeared and reached 8.5 K by the oxygen annealing at 200\degree C. The
superconducting volume fraction was also enhanced from 0 to almost 100%. The
lattice constants were compressed by the oxygen annealing, indicating that the
evolution of bulk superconductivity in FeTe0.8S0.2 was correlated to the
shrinkage of lattice.Comment: 13 pages, 6 figure
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