NO adsorption and thermal behavior on Pd surfaces. A detailed comparative study

The adsorption and thermal behavior of NO on `flat¿ Pd(111) and `stepped¿ Pd(112) surfaces has been investigated by temperature programmed desorption (TPD), high resolution electron energy loss spectroscopy (HREELS), and electron stimulated desorption ion angular distribution (ESDIAD) techniques. NO is shown to molecularly adsorb on both Pd(111) and Pd(112) in the temperature range 100¿373 K. NO thermally desorbs predominantly molecularly from Pd(111) near 500 K with an activation energy and pre-exponential factor of desorption which strongly depend on the initial NO surface coverage. In contrast, NO decomposes substantially on Pd(112) upon heating, with relatively large amounts of N2 and N2O desorbing near 500 K, in addition to NO. The fractional amount of NO dissociation on Pd(112) during heating is observed to be a strong function of the initial NO surface coverage. HREELS results indicate that the thermal dissociation of NO on both Pd(111) and Pd(112) occurs upon annealing to 490 K, forming surface-bound O on both surfaces. Evidence for the formation of sub-surface O via NO thermal dissociation is found only on Pd(112), and is verified by dissociative O2 adsorption experiments. Both surface-bound O and sub-surface O dissolve into the Pd bulk upon annealing of both surfaces to 550 K. HREELS and ESDIAD data consistently indicate that NO preferentially adsorbs on the (111) terrace sites of Pd(112) at low coverages, filling the (001) step sites only at high coverage. This result was verified for adsorption temperatures in the range 100¿373 K. In addition, the thermal dissociation of NO on Pd(112) is most prevalent at low coverages, where only terrace sites are occupied by NO. Thus, by direct comparison to NO/Pd(111), this study shows that the presence of steps on the Pd(112) surface enhances the thermal dissociation of NO, but that adsorption at the step sites is not the criterion for this decomposition

Interactions between uptake of amino acids and inorganic nitrogen in wheat plants

Soil-borne amino acids may constitute a source of nitrogen (N) for plants in various terrestrial ecosystems but their importance for total N nutrition is unclear, particularly in nutrient-rich arable soils. One reason for this uncertainty is lack of information on how the absorption of amino acids by plant roots is affected by the simultaneous presence of inorganic N forms. The objective of the present study was to study absorption of glycine (Gly) and glutamine (Gln) by wheat roots and their interactions with nitrate (NO<sub>3</sub><sup>−</sup>) and ammonium (NH<sub>4</sub><sup>+</sup>) during uptake. The underlying hypothesis was that amino acids, when present in nutrient solution together with inorganic N, may lead to down-regulation of the inorganic N uptake, thereby resulting in similar total N uptake rates. Amino acids were enriched with double-labelled <sup>15</sup>N and <sup>13</sup>C, while NO<sub>3</sub><sup>−</sup> and NH<sub>4</sub><sup>+</sup> acquisition was determined by their rate of removal from the nutrient solution surrounding the roots. The uptake rates of NO<sub>3</sub><sup>−</sup> and NH<sub>4</sub><sup>+</sup> did not differ from each other and were generally about twice as high as the uptake rate of organic N when the different N forms were supplied separately in concentrations of 2 mM. Nevertheless, replacement of 50% of the inorganic N with organic N was able to restore the N uptake to the same level as that in the presence of only inorganic N. Co-provision of NO<sub>3</sub><sup>−</sup> did not affect glycine uptake, while the presence of glycine down-regulated NO<sub>3</sub><sup>−</sup> uptake. The ratio between <sup>13</sup>C and <sup>15</sup>N were lower in shoots than in roots and also lower than the theoretical values, reflecting higher C losses via respiratory processes compared to N losses. It is concluded that organic N can constitute a significant N-source for wheat plants and that there is an interaction between the uptake of inorganic and organic N

Does the quark-gluon plasma contain stable hadronic bubbles?

We calculate the thermodynamic potential of bubbles of hadrons embedded in quark-gluon plasma, and of droplets of quark-gluon plasma embedded in hadron phase. This is a generalization of our previous results to the case of non-zero chemical potentials. As in the zero chemical potential case, we find that a quark-gluon plasma in thermodynamic equilibrium may contain stable bubbles of hadrons of radius $R \simeq 1$ fm. The calculations are performed within the MIT Bag model, using an improved multiple reflection expansion. The results are of relevance for neutron star phenomenology and for ultrarelativistic heavy ion collisions.Comment: 12 pages including 8 figures. To appear in Phys. Rev.

Soft versus Hard Dynamics for Field-driven Solid-on-Solid Interfaces

Analytical arguments and dynamic Monte Carlo simulations show that the microstructure of field-driven Solid-on-Solid interfaces depends strongly on the dynamics. For nonconservative dynamics with transition rates that factorize into parts dependent only on the changes in interaction energy and field energy, respectively (soft dynamics), the intrinsic interface width is field-independent. For non-factorizing rates, such as the standard Glauber and Metropolis algorithms (hard dynamics), it increases with the field. Consequences for the interface velocity and its anisotropy are discussed.Comment: 9 pages LaTex with imbedded .eps figs. Minor revision

Chiral phase properties of finite size quark droplets in the Nambu--Jona-Lasinio model

Chiral phase properties of finite size hadronic systems are investigated within the Nambu--Jona-Lasinio model. Finite size effects are taken into account by making use of the multiple reflection expansion. We find that, for droplets with relatively small baryon numbers, chiral symmetry restoration is enhanced by the finite size effects. However the radius of the stable droplet does not change much, as compared to that without the multiple reflection expansion.Comment: RevTex4, 9 pages, 6 figures, to be published in Phys. Rev.

How do women prepare for pregnancy? Preconception experiences of women attending antenatal services and views of health professionals

Copyright: © 2014 Stephenson et al. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.Main objective - To determine the extent to which women plan and prepare for pregnancy. Methods - Cross-sectional questionnaire survey of pregnant women attending three maternity services in London about knowledge and uptake of preconception care; including a robust measure of pregnancy planning, and phone interviews with a range of health care professionals. Main results - We recruited 1173/1288 (90%) women, median age of 32 years. 73% had clearly planned their pregnancy, 24% were ambivalent and only 3% of pregnancies were unplanned. 51% of all women and 63% of those with a planned pregnancy took folic acid before pregnancy. 21% of all women reported smoking and 61% reported drinking alcohol in the 3 months before pregnancy; 48% of smokers and 41% of drinkers reduced or stopped before pregnancy. The 51% of all women who reported advice from a health professional before becoming pregnant were more likely to adopt healthier behaviours before pregnancy [adjusted odds ratios for greatest health professional input compared with none were 2.34 (95% confidence interval 1.54–3.54) for taking folic acid and 2.18 (95% CI 1.42–3.36) for adopting a healthier diet before pregnancy]. Interviews with 20 health professionals indicated low awareness of preconception health issues, missed opportunities and confusion about responsibility for delivery of preconception care. Significance of the findings - Despite a high level of pregnancy planning, awareness of preconception health among women and health professionals is low, and responsibility for providing preconception care is unclear. However, many women are motivated to adopt healthier behaviours in the preconception period, as indicated by halving of reported smoking rates in this study. The link between health professional input and healthy behaviour change before pregnancy is a new finding that should invigorate strategies to improve awareness and uptake of pre-pregnancy health care, and bring wider benefits for public health.Department of Healt

Universality class of the restricted solid-on-solid model with hopping

We study the restricted solid-on-solid (RSOS) model with finite hopping distance $l_{0}$, using both analytical and numerical methods. Analytically, we use the hard-core bosonic field theory developed by the authors [Phys. Rev. E {\bf 62}, 7642 (2000)] and derive the Villain-Lai-Das Sarma (VLD) equation for the $l_{0}=\infty$ case which corresponds to the conserved RSOS (CRSOS) model and the Kardar-Parisi-Zhang (KPZ) equation for all finite values of $l_{0}$. Consequently, we find that the CRSOS model belongs to the VLD universality class and the RSOS models with any finite hopping distance belong to the KPZ universality class. There is no phase transition at a certain finite hopping distance contrary to the previous result. We confirm the analytic results using the Monte Carlo simulations for several values of the finite hopping distance.Comment: 13 pages, 3 figure