Theoretical studies of a hydrogen abstraction tool for nanotechnology

In the design of a nanoscale, site-specific hydrogen abstraction tool, the authors suggest the use of an alkynyl radical tip. Using ab initio quantum-chemistry techniques including electron correlation they model the abstraction of hydrogen from dihydrogen, methane, acetylene, benzene and isobutane by the acetylene radical. By conservative estimates, the abstraction barrier is small (less than 7.7 kcal mol^-1) in all cases except for acetylene and zero in the case of isobutane. Thermal vibrations at room temperature should be sufficient to supply the small activation energy. Several methods of creating the radical in a controlled vacuum setting should be feasible. The authors show how nanofabrication processes can be accurately and inexpensively designed in a computational framework

Elastic moduli approximation of higher symmetry for the acoustical properties of an anisotropic material

The issue of how to define and determine an optimal acoustical fit to a set of anisotropic elastic constants is addressed. The optimal moduli are defined as those which minimize the mean squared difference in the acoustical tensors between the given moduli and all possible moduli of a chosen higher material symmetry. The solution is shown to be identical to minimizing a Euclidean distance function, or equivalently, projecting the tensor of elastic stiffness onto the appropriate symmetry. This has implications for how to best select anisotropic constants to acoustically model complex materials.Comment: 20 page

Junctions and thin shells in general relativity using computer algebra I: The Darmois-Israel Formalism

We present the GRjunction package which allows boundary surfaces and thin-shells in general relativity to be studied with a computer algebra system. Implementing the Darmois-Israel thin shell formalism requires a careful selection of definitions and algorithms to ensure that results are generated in a straight-forward way. We have used the package to correctly reproduce a wide variety of examples from the literature. We present several of these verifications as a means of demonstrating the packages capabilities. We then use GRjunction to perform a new calculation - joining two Kerr solutions with differing masses and angular momenta along a thin shell in the slow rotation limit.Comment: Minor LaTeX error corrected. GRjunction for GRTensorII is available from http://astro.queensu.ca/~grtensor/GRjunction.htm

Lax pair tensors in arbitrary dimensions

A recipe is presented for obtaining Lax tensors for any n-dimensional Hamiltonian system admitting a Lax representation of dimension n. Our approach is to use the Jacobi geometry and coupling-constant metamorphosis to obtain a geometric Lax formulation. We also exploit the results to construct integrable spacetimes, satisfying the weak energy condition.Comment: 8 pages, uses IOP style files. Minor correction. Submitted to J. Phys

Evidence of micro-continent entrainment during crustal accretion

Peer reviewedPublisher PD

A proposal of a UCN experiment to check an earthquake waves model

Elastic waves with transverse polarization inside incidence plane can create longitudinal surface wave (LSW) after reflection from a free surface. At a critical incidence angle this LSW accumulates energy density, which can be orders of magnitude higher than energy density of the incident transverse wave. A specially arranged vessel for storage of ultracold neutrons (UCN) can be used to verify this effect.Comment: 8 pages 3 figures added a paragraph on vibrations along surface at critical angl

Thermo-elasticity for anisotropic media in higher dimensions

In this note we develop tools to study the Cauchy problem for the system of thermo-elasticity in higher dimensions. The theory is developed for general homogeneous anisotropic media under non-degeneracy conditions. For degenerate cases a method of treatment is sketched and for the cases of cubic media and hexagonal media detailed studies are provided.Comment: 33 pages, 5 figure

Gravitational Collapse of Dust with a Cosmological Constant

The recent analysis of Markovic and Shapiro on the effect of a cosmological constant on the evolution of a spherically symmetric homogeneous dust ball is extended to include the inhomogeneous and degenerate cases. The histories are shown by way of effective potential and Penrose-Carter diagrams.Comment: 2 pages, 2 figures (png), revtex. To appear in Phys. Rev.