287 research outputs found
Structure and absolute configuration of phenanthro-perylene quinone pigments from the deep-sea crinoid Hypalocrinus naresianus
Two new water-soluble phenanthroperylene quinones, gymnochrome H (2) and monosulfated gymnochrome A (3), as well as the known compounds gymnochrome A (4) and monosulfated gymnochrome D (5) were isolated from the deep-sea crinoid Hypalocrinus naresianus, which had been collected in the deep sea of Japan. The structures of the compounds were elucidated by spectroscopic analysis including HRMS, 1D 1H and 13C NMR, and 2D NMR. The absolute configuration was determined by ECD spectroscopy, analysis of J-couplings and ROE contacts, and DFT calculations. The configuration of the axial chirality of all isolated phenanthroperylene quinones (2–5) was determined to be (P). For gymnochrome H (2) and monosulfated gymnochrome A (3), a (2′S,2″R) configuration was determined, whereas for monosulfated gymnochrome D (5) a (2′R,2″R), configuration was determined. Acetylated quinones are unusual among natural products from an echinoderm and gymnochrome H (2) together with the recently reported gymnochrome G (1) represent the first isolated acetylated phenanthroperylene quinones
Absence of a structural transition up to 40 Gpa in MgB2 and the relevance of magnesium non-stoichiometry
We report measurements on MgB2 up to ~40GPa. Increasing pressure yields a
monotonous decrease of the lattice parameters and of the c/a ratio, but no
structural transition down to parameters smaller than those of AlB2. The
transition superconducting temperature also decreases with temperature in a
sample dependent way. The results are explained by an increase of the filling
of the 2D pxy bands with pressure, the Mg stoichiometry determining the
starting position of the Fermi level. Our measurements indicate that these hole
bands are the relevant ones for superconductivity.Comment: submitted March 9th 2001, PRB accepte
Development of an inducible mouse model of iRFP713 to track recombinase activity and tumour development in vivo
While the use of bioluminescent proteins for molecular imaging is a powerful technology to further our understanding of complex processes, fluorescent labeling with visible light fluorescent proteins such as GFP and RFP suffers from poor tissue penetration and high background autofluorescence. To overcome these limitations, we generated an inducible knock-in mouse model of iRFP713. This model was used to assess Cre activity in a Rosa Cre-ER background and quantify Cre activity upon different tamoxifen treatments in several organs. We also show that iRFP can be readily detected in 3D organoid cultures, FACS analysis and in vivo tumour models. Taken together we demonstrate that iRFP713 is a progressive step in in vivo imaging and analysis that widens the optical imaging window to the near-infrared spectrum, thereby allowing deeper tissue penetration, quicker image acquisition without the need to inject substrates and a better signal to background ratio in genetically engineered mouse models (GEMMs)
High pressure effects in fluorinated HgBa2Ca2Cu3O(8+d)
We have measured the pressure sensitivity of Tc in fluorinated
HgBa2Ca2Cu3O(8+d) (Hg-1223) ceramic samples with different F contents, applying
pressures up to 30 GPa. We obtained that Tc increases with increasing pressure,
reaching different maximum values, depending on the F doping level, and
decreases for a further increase of pressure. A new high Tc record (166 K +/- 1
K) was achieved by applying pressure (23 GPa) in a fluorinated Hg-1223 sample
near the optimum doping level. Our results show that all our samples are at the
optimal doping, and that fluorine incorporation decreases the crystallographic
-parameter concomitantly increasing the maximum attainable Tc. This effect
reveals that the compression of the axes is one of the keys that controls
the Tc of high temperature superconductors.Comment: 4 pages, 4 figures, submitted to Phys. Rev.
High pressure transport studies of the LiFeAs analogues CuFeTe2 and Fe2As
We have synthesized two iron-pnictide/chalcogenide materials, CuFeTe2 and
Fe2As, which share crystallographic features with known iron-based
superconductors, and carried out high-pressure electrical resistivity
measurements on these materials to pressures in excess of 30 GPa. Both
compounds crystallize in the Cu2Sb-type crystal structure that is
characteristic of LiFeAs (with CuFeTe2 exhibiting a disordered variant). At
ambient pressure, CuFeTe2 is a semiconductor and has been suggested to exhibit
a spin-density-wave transition, while Fe2As is a metallic antiferromagnet. The
electrical resistivity of CuFeTe2, measured at 4 K, decreases by almost two
orders of magnitude between ambient pressure and 2.4 GPa. At 34 GPa, the
electrical resistivity decreases upon cooling the sample below 150 K,
suggesting the proximity of the compound to a metal-insulator transition.
Neither CuFeTe2 nor Fe2As superconduct above 1.1 K throughout the measured
pressure range.Comment: 6 pages, 7 figure
A Survey of Local Group Galaxies Currently Forming Stars. I. UBVRI Photometry of Stars in M31 and M33
We present UBVRI photometry obtained from Mosaic images of M31 and M33 using
the KPNO 4-m telescope. The survey covers 2.2 sq degrees of M31, and 0.8 sq
degrees of M33, chosen so as to include all of the regions currently active in
forming massive stars. The catalog contains 371,781 and 146,622 stars in M31
and M33, respectively, where every star has a counterpart (at least) in B, V,
and R. We compare our photometry to previous studies. We provide cross
references to the stars confirmed as members by spectroscopy, and compare the
location of these to the complete set in color-magnitude diagrams. While
follow-up spectroscopy is needed for many projects, we demonstrate the success
of our photometry in being able to distinguish M31/M33 members from foreground
Galactic stars. We also present the results of newly obtained spectroscopy,
which identifies 34 newly confirmed members, including B-A supergiants, the
earliest O star known in M31, and two new Luminous Blue Variable candidates
whose spectra are similar to that of P Cygni.Comment: Accepted by the Astronomical Journal. A version with higher
resolution figures can be found at:
http://www.lowell.edu/users/massey/M3133.pdf.g
A Survey of Local Group Galaxies Currently Forming Stars: III. A Search for Luminous Blue Variables and Other H-alpha Emission-Lined Stars
We describe a search for H-alpha emission-lined stars in M31, M33, and seven
dwarfs in or near the Local Group (IC 10, NGC 6822, WLM, Sextans B, Sextans A,
Pegasus and the Phoenix dwarf) using interference filter imaging with the KPNO
and CTIO 4-m telescope and Mosaic cameras. The survey is aimed primarily at
identifying new Luminous Blue Variables (LBVs) from their spectroscopic
similarity to known LBVs, avoiding the bias towards photometric variability,
which may require centuries to manifest itself if LBVs go through long
quiescent periods. Followup spectroscopy with WIYN confirms that our survey
detected a wealth of stars whose spectra are similar to the known LBVs. We
"classify" the spectra of known LBVs, and compare these to the spectra of the
new LBV candidates. We demonstrate spectacular spectral variability for several
of the new LBV candidates, such as AM2, previously classified as a Wolf-Rayet
star, which now shows FeI, FeII and Balmer emission lines but neither the NIII
4634,42 nor HeII 4686 emission that it did in 1982. Profound spectral changes
are also noted for other suspected and known LBVs. Several of the LBV
candidates also show >0.5 mag changes in V over the past 10-20 years. The
number of known or suspected LBVs is now 24 in M31, 37 in M33, 1 in NGC 6822,
and 3 in IC 10. We estimate that the total number of LBVs in M31 and M33 may be
several hundred, in contrast to the 8 known historically through large-scale
photometric variability. This has significant implications for the time scale
of the LBV phase. We also identify a few new WRs and peculiar emission-lined
objects.Comment: Accepted by the Astronomical Journal. Version with higher quality
figures may be downloaded from http://www.lowell.edu/users/massey/has.pdf.g
Electric field gradients in s-, p- and d-metal diborides and the effect of pressure on the band structure and T in MgB
Results of FLMTO-GGA (full-potential linear muffin-tin orbital -- generalized
gradient approximation) calculations of the band structure and boron electric
field gradients (EFG) for the new medium-T superconductor (MTSC), MgB,
and related diborides MB, M=Be, Al, Sc, Ti, V, Cr, Mo and Ta are reported.
The boron EFG variations are found to be related to specific features of their
band structure and particularly to the M-B hybridization. The strong charge
anisotropy at the B site in MgB is completely defined by the valence
electrons - a property which sets MgB apart from other diborides. The boron
EFG in MgB is weakly dependent of applied pressure: the B p electron
anisotropy increases with pressure, but it is partly compensated by the
increase of core charge assymetry. The concentration of holes in bonding
bands is found to decrease slightly from 0.067 to 0.062 holes/B under
a pressure of 10 GPa. Despite a small decrease of N(E), the Hopfield
parameter increases with pressure and we believe that the main reason for the
reduction under pressure of the superconducting transition temperature, T,
is the strong pressure dependence of phonon frequencies, which is sufficient to
compensate the electronic effects.Comment: 12 pages, 3 figure
Raman spectrum and lattice parameters of MgB2 as a function of pressure
We report Raman spectra and synchrotron x-ray diffraction measurements of
lattice parameters of polycrystalline MgB2 under hydrostatic pressure
conditions up to 15 GPa. An anomalously broadened Raman band at 620 cm-1 is
observed that exhibits a large linear pressure shift of its frequency. The
large mode damping and Gruneisen parameter indicate a highly anharmonic nature
of the mode, broadly consistent with theoretical predictions for the E2g
in-plane boron stretching mode. The results obtained may provide additional
constraints on the electron-phonon coupling in the system.Comment: 3 pages, 3 figure
Pressure Effects and Large Polarons in Layered MgB_2 Superconductor
We consider the dependence of the MgB_2 superconducting critical temperature
on the pressure. Our model exploits the influence of the large polarons on the
band structure of the layered MgB_2 superconductor. Namely, the hole
Pekar-Froehlich polarons form quasi two-dimensional potential wells in the
boron plane which shift the positions of the sigma- and pi-bands. This energy
shift depends on the pressure and the Cooper pairing of the correlated
sigma-electrons happens inside polaron wells. The results obtained are as
follows: dT_c/dp = -\alpha (5.2 \pm 0.9) K/GPa or dT_c/dp = -\alpha (6.9\pm
1.1) K/GPa for a different choice of the Grueneisen parameter. Being compared
with known experimental data they give us a resonable interval for the value of
the Froehlich electron-phonon coupling constant: \alpha = 0.15 - 0.45.Comment: 6 pages, 1 fig, LaTeX, subm. to Phys. Rev.
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