Crystallographically oriented magnetic ZnFe2O4 nanoparticles synthesized by Fe implantation into ZnO

In this paper, a correlation between structural and magnetic properties of Fe implanted ZnO is presented. High fluence Fe^+ implantation into ZnO leads to the formation of superparamagnetic alpha-Fe nanoparticles. High vacuum annealing at 823 K results in the growth of alpha-Fe particles, but the annealing at 1073 K oxidized the majority of the Fe nanoparticles. After a long term annealing at 1073 K, crystallographically oriented ZnFe2O4 nanoparticles were formed inside ZnO with the orientation relationship of ZnFe2O4(111)[110]//ZnO(0001)[1120]. These ZnFe2O4 nanoparticles show a hysteretic behavior upon magnetization reversal at 5 K.Comment: 21 pages, 7 figures, accepted by J. Phys. D: Appl. Phy

Superconductivity and Magnetism in REFeAsO1-xFx (RE=Rare Earth Elements)

Fluoride-doped iron-based oxypnictides containing rare-earth gadolinium (GdFeAsO0.8F0.2) and co-doping with yttrium (Gd0.8Y0.2FeAsO0.8F0.2) have been prepared via conventional solid state reaction at ambient pressure. The non-yttrium substituted oxypnictide show superconducting transition as high as 43.9 K from temperature dependent resistance measurements with the Meissner effect observed at a lower temperature of 40.8 K from temperature dependent magnetization measurements. By replacing a small amount of gadolinium with yttrium Tc was observed to be lowered by 10 K which might be caused by a change in the electronic or magnetic structures since the crystal structure was not altered.Comment: 4 pages, 4 figures, Journal of Physics: Conference Series (Proceedings in the LT25 Low Temperature Physics Conference) Submitte

Chain Formation by Spin Pentamers in eta-Na9V14O35

The nature of the gapped ground state in the quasi-one-dimensional compound eta-Na9V14O35 cannot easily be understood, if one takes into account the odd number of spins on each structural element. Combining the results of specific heat, susceptibility and electron spin resonance measurements we show that eta-Na9V14O35 exhibits a novel ground state where multi-spin objects build up a linear chain. These objects - pentamers - consist of five antiferromagnetically arranged spins with effective spin 1/2. Their spatial extent results in an exchange constant along the chain direction comparable to the one in the high-temperature state.Comment: 6 pages, 5 figure

The effect of ultrafine WO3 nanoparticles on the organization of thylakoids enriched in photosystem II and energy transfer in photosystem II complexes

In this work, a new approach to construct self-assembled hybrid systems based on natural PSII-enriched thylakoid membranes (PSII BBY) is demonstrated. Superfine m-WO3 NPs (≈1–2 nm) are introduced into PSII BBY. Transmission electron microscopy (TEM) measurements showed that even the highest concentrations of NPs used did not degrade the PSII BBY membranes. Using atomic force microscopy (AFM), it is shown that the organization of PSII BBY depends strongly on the concentration of NPs applied. This proved that the superfine NPs can easily penetrate the thylakoid membrane and interact with its components. These changes are also related to the modified energy transfer between the external light-harvesting antennas and the PSII reaction center, shown by absorption and fluorescence experiments. The biohybrid system shows stability at pH 6.5, the native operating environment of PSII, so a high rate of O2 evolution is expected. In addition, the light-induced water-splitting process can be further stimulated by the direct interaction of superfine WO3 NPs with the donor and acceptor sides of PSII. The water-splitting activity and stability of this colloidal system are under investigation

Heat Capacity and Magnetic Phase Diagram of the Low-Dimensional Antiferromagnet Y2_2BaCuO5_5

A study by specific heat of a polycrystalline sample of the low-dimensional magnetic system Y$_2$BaCuO$_5$ is presented. Magnetic fields up to 14 T are applied and permit to extract the ($T$,$H$) phase diagram. Below $\mu_0H^*\simeq2$ T, the N\'eel temperature, associated with a three-dimensional antiferromagnetic long-range ordering, is constant and equals $T_N=15.6$ K. Above $H^*$, $T_N$ increases linearly with $H$ and a field-induced increase of the entropy at $T_N$ is related to the presence of an isosbestic point at $T_X\simeq20$ K, where all the specific heat curves cross. A comparison is made between Y$_2$BaCuO$_5$ and the quasi-two-dimensional magnetic systems BaNi$_{2}$V$_{2}$O$_{8}$, Sr$_2$CuO$_2$Cl$_2$, and Pr$_2$CuO$_4$, for which very similar phase diagrams have been reported. An effective field-induced magnetic anisotropy is proposed to explain these phase diagrams.Comment: 14 pages, 7 figure

Interacting spin-2 fields in three dimensions

Using the frame formulation of multi-gravity in three dimensions, we show that demanding the presence of secondary constraints which remove the Boulware-Deser ghosts restricts the possible interaction terms of the theory and identifies invertible frame field combinations whose effective metric may consistently couple to matter. The resulting ghost-free theories can be represented by theory graphs which are trees. In the case of three frame fields, we explicitly show that the requirement of positive masses and energies for the bulk spin-2 modes in AdS$_3$ is consistent with a positive central charge for the putative dual CFT$_2$.Comment: 26 pages, 3 figures, v2: minor changes, matches published versio

Space-time defects and teleparallelism

We consider the class of space-time defects investigated by Puntigam and Soleng. These defects describe space-time dislocations and disclinations (cosmic strings), and are in close correspondence to the actual defects that arise in crystals and metals. It is known that in such materials dislocations and disclinations require a small and large amount of energy, respectively, to be created. The present analysis is carried out in the context of the teleparallel equivalent of general relativity (TEGR). We evaluate the gravitational energy of these space-time defects in the framework of the TEGR and find that there is an analogy between defects in space-time and in continuum material systems: the total gravitational energy of space-time dislocations and disclinations (considered as idealized defects) is zero and infinit, respectively.Comment: 22 pages, no figures, to appear in the Class. Quantum Gravit

Potential of gene therapy for the treatment of pituitary tumors

Pituitary adenomas constitute the most frequent neuroendocrine pathology, comprising up to 15% of primary intracranial tumors. Current therapies for pituitary tumors include surgery and radiotherapy, as well as pharmacological approaches for some types. Although all of these approaches have shown a significant degree of success, they are not devoid of unwanted side effects, and in most cases do not offer a permanent cure. Gene therapy-the transfer of genetic material for therapeutic purposes-has undergone an explosive development in the last few years. Within this context, the development of gene therapy approaches for the treatment of pituitary tumors emerges as a promising area of research. We begin by presenting a brief account of the genesis of prolactinomas, with particular emphasis on how estradiol induces prolactinomas in animals. In so doing, we discuss the role of each of the recently discovered growth inhibitory and growth stimulatory substances and their interactions in estrogen action. We also evaluate the cell-cell communication that may govern these growth factor interactions and subsequently promote the growth and survival of prolactinomas. Current research efforts to implement gene therapy in pituitary tumors include the treatment of experimental prolactinomas or somatomammotropic tumors with adenoviral vector-mediated transfer of the suicide gene for the herpes simplex type 1 (HSV1) thymidine kinase, which converts the prodrug ganciclovir into a toxic metabolite. In some cases, the suicide transgene has been placed under the control of pituitary cell-type specific promoters, like the human prolactin or human growth hormone promoters. Also, regulatable adenoviral vector systems are being assessed in gene therapy approaches for experimental pituitary tumors. In a different type of approach, an adenoviral vector, encoding the human retinoblastoma suppressor oncogene, has been successfully used to rescue the phenotype of spontaneous pituitary tumors of the pars intermedia in mice. We close the article by discussing the future of molecular therapies. We point out that although, gene therapy represents a key step in the development of molecular medicine, it has inherent limitations. As a consequence, it is our view that at some point, genetic therapies will have to move from exogenous gene transfer (i.e. gene therapy) to endogenous gene repair. This approach will call for radically new technologies, such as nanotechnology, whose present state of development is outlined.Instituto de Investigaciones Bioquímicas de La Plat