Major, Trace, and Rare-Earth Element Geochemistry of Nb-V Rich Andradite-Schorlomite-Morimotoite Garnet from Ambadungar-Saidivasan Alkaline Carbonatite Complex, India: Implication for the Role of Hydrothermal Fluid-Induced Metasomatism

In situ major, trace and rare-earth element composition of Ti-rich garnets from Ambadungar-Saidivasan alkaline carbonatite complex (ASACC) are presented to constrain its likely genesis. The garnets are characterized by high andradite (42.7–57.3), schorolomite (22.0–31.0), and morimotoite (15.6–26.5) end members. No distinct chemical zonation is noticed except for minor variations in Ti content. The garnets are enriched in LREE (average 731 ppm) and relatively depleted in HREE (average 186 ppm) and show an M-type first tetrad that leads to a convex upward pattern between Ce and Gd. Mildly positive to no Eu anomalies are observed (Eu/Eu* = 1.06–1.17). The REE patterns (LaN/YbN = 1.11–2.11) are similar to those of garnets from skarn deposits. The presence of tetrad effect in the LREE pattern suggests an active role of metasomatic processes involving hydrothermal fluids during the growth of the garnets. These garnets also contain high Nb (282–2283 ppm) and V (1083–2155 ppm) concentrations, which stand out against the composition of the host rock. Therefore, late-stage metasomatic reactions of earlier formed minerals with hydrothermal fluid enriched in Fe, Si, LREE, Nb, V, and Ti led to the formation of garnet. The primary source for these elements could be magnetite, ilmenite, and pyrochlore present in different varieties of carbonatites in the ASACC, with the required elements being released during their interaction with the hydrothermal fluid. The hydrothermal fluid was likely to be moderately acidic, and having fluoride and sulfate as the primary ligands

Detrital zircon evidence for change in geodynamic regime of continental crust formation 3.7–3.6 billion years ago

The nature of the early terrestrial crust and how it evolved through time remains highly controversial. Whether conventional plate tectonics operated in the Hadean and early Archean and when it came into existence remains unclear. Here, we describe U-Pb ages, Hf isotope composition and trace element chemistry of 3.95–3.10 Ga old detrital zircons from the Singhbhum Craton in eastern India. The >3.7 Ga old zircons of this suite have crust-like Hf isotope compositions with strongly negative εHfi and their granitoid sources formed by intra-crustal reworking of a Hadean protolith that was extracted from primitive mantle at 4.4–4.5 Ga. The trace element and Hf isotope compositions of the zircons record a transition from higher Nb/Th (0.070 ± 0.010), Nb/U (0.045 ± 0.005), crust-like Hf isotope compositions, and longer crustal residence times of the protoliths prior to 3.7–3.6 Ga, to lower Nb/Th (0.032 ± 0.012), Nb/U (0.024 ± 0.009; 1σ), mantle-like Hf isotope compositions, and shorter protolith residence times post 3.7–3.6 Ga. The Nb/Th and Nb/U fractionation at 3.7 Ga seen in the detrital zircon record can be explained by transition to granitoid production at greater depths in an oceanic plateau-like regime. However, had that been the case, the crustal residence times of the protoliths of the granitoids from which the detrital zircons were sourced should have progressively increased with time, given the >1.1 billion years protracted history of granitoid magmatism in the craton, which is contrary to what is observed. We suggest that the changes in the granitoid chemistry recorded by the detrital zircons document a significant change in the depth of melting of the protoliths as well as in the tectonic setting of continental crust formation, and argue that it marks the transition to granitoid production from oceanic plateaus to arc-like tectonic environments. Broadly similar transitions at ca. 3.6 Ga have been documented in gneisses from the Acasta Gneiss Complex, the Jack Hills zircons and in detrital zircons from the Wyoming Province, which suggest that the end of the Eoarchean may have been marked by widespread transition in planetary tectonic regime

The Basement of the Deccan Traps and Its Madagascar Connection: Constraints from Xenoliths

Paleogeographic reconstructions of India and Madagascar before their late Cretaceous rifting juxtapose the Antongil Block of Madagascar against the Deccan Traps of India, indicating that the Western Dharwar Craton extends below the Deccan lavas. Some recent studies have suggested that the South Maharashtra Shear Zone along the northern Konkan coast of India limits the northern extent of the Western Dharwar Craton, implying that the craton does not extend below the Deccan Traps, raising a question mark on paleogeographic reconstructions of India and Madagascar. The continuity of the Western Dharwar Craton north of the South Maharashtra Shear Zone below the Deccan Traps—or its lack thereof—is critical for validating tectonic models correlating Madagascar with India. In this study, zircons in tonalitic basement xenoliths hosted in Deccan Trap dykes were dated in situ, using the U-Pb isotope system. The data furnish U-Pb ages that define three populations at 2527 ± 6, 2456 ± 6, and 2379 ± 9 Ma. The 2527 ± 6 Ma ages correspond to the igneous crystallization of the tonalites, whereas the 2456 ± 6 and 2379 ± 9 Ma ages date metamorphic overprints. The results help to establish for the first time that the basement is a part of the Neoarchean granitoid suite of the Western Dharwar Craton, which extends northward up to at least Talvade in central and Kihim beach in the western Deccan. By implication, the South Maharashtra Shear Zone cannot be the northern limit of the Western Dharwar Craton. The granitoids are correlated with the Neoarchean felsic intrusions (2.57–2.49) of the Masaola suite in the Antongil Block of Madagascar, supporting the existence of a Neoarchean Greater Dharwar Craton comprising the Western Dharwar Craton and the Antongil-Masora Block

Geochronology, whole-rock geochemistry and Sr-Nd isotopes of the Bhanupratappur mafic dyke swarm : Evidence for a common Paleoproterozoic LIP event at 2.37–2.36 Ga in the Bastar and Dharwar cratons

Mafic dykes and dyke swarms in continental settings provide information on the evolution of the subcontinental mantle and can be key elements in the reconstruction of paleo-geographic settings of now separated crustal terranes. This study focuses on the petrogenesis and geochronology of mafic dykes of the WNW (~125°) trending Bhanupratappur swarm in the central Bastar Craton, central India. Dykes of the Bhanupratappur swarm yield an average U-Pb (ID-TIMS) baddeleyite age of 2360 ± 4 Ma, which is interpreted as their emplacement age. The compositions of the dykes range from tholeiitic basalt to basaltic-andesite. Their rare earth element and multi-element patterns indicate the involvement of a crustal component in their petrogenesis. The whole rock initial 87Sr/86Sr2360 Ma ranges from 0.70097 to 0.70506 with most being more radiogenic than the contemporaneous undifferentiated mantle reservoir (i.e. 87Sr/86Sr2360 Ma = 0.70173). The initial εNd 2360 Ma (+0.85 to −2.7) are chondritic to sub-chondritic. The Sr-Nd Isotope composition and major- and trace element chemistry suggest an enriched-heterogeneous mantle source. The closely matching ages and chemistry of the Bhanupratappur swarm (2360 Ma) and the Karimnagar-Bangalore swarms (2363–2369 Ma) of the Dharwar Craton indicate affinities to a common Large Igneous Province, which further implies that the Bastar and Dharwar cratons were already juxtaposed at 2.37–2.36 Ga. The dykes of the Bhanupratappur (WNW-trending) and Bangalore (E-W trending) swarms converge towards the east indicating a plume center in the east. If the Karimnagar swarm was also linked (and was converging) to the same plume, the present-day mismatch in the orientations of the Karimnagar dykes (NE- to ENE-trending) with the Bangalore and Bhanupratappur dykes may indicate a ~55° counterclockwise rotation of the northern block of the Eastern Dharwar Craton with respect to the southern block after 2.37–2.36 Ga

Integrated subsurface investigation for magmatic sulfide mineralization in Betul Fold Belt, central India

Magnetotelluric (MT), Electrical Resistivity Tomography (ERT), Time-Domain Induced Polarization (TDIP), Geochemical and Geological studies followed by drilling and down-hole logging were undertaken with in the Betul Fold Belt (BFB) in Central India, to demarcate zones of magmatic Ni-Cu-PGE sulfide mineralization. The BFB is predominantly composed of circular to elongate gabbro bodies of the Padhar Mafic-Ultramafic Complex, intruded into a sequence of bimodal volcanic rocks and quartzites. Near-surface samples of ultramafic rocks were subjected to precise geochemical analysis and scanned by an electron microscopy with an energy dispersive spectrometer (SEM-EDS). This work indicated the presence of pyrite, pyrrhotite, chalcopyrite, pentlandite, and minor amounts of W-Cd bearing boweiite and palladenite assemblage. These minerals are regarded as favorable to the occurrence of Ni-Cu-PGE sulfide mineralization. MT data derived from two profiles were analyzed and modeled using 2D and 3D inversion algorithms. The robust conductivity anomalies obtained from the MT model have been interpreted coupled with electrical tomography, geology, and geochemistry data. The near-surface shallow depth conductors observed in the ERT sections are interpreted as the sulfide mineralized zones. They corroborate the MT results. These conductive zones reflect the occurrence of the magmatic Ni-Cu-PGE bearing sulfide mineralization associated with rocks of the mantle-derived Padhar Mafic Ultramafic Complex. This geophysical data, in conjunction with petrological and geochemical analysis of drill core samples have allowed the identification of the origin and paragenesis of sulphide mineralization in the study area. Geochemical studies suggest that the parental magma was generated from a subduction modified, metasomatized and an enriched mantle source that was subsequently emplaced in a magmatic continental arc setting. The interpreted conductors, observed at shallow depths (similar to 200-300 m), have been generated by secondary hydrothermal fluid circulation leading to vein formation in the host Padhar Mafic-Ultramafic Complex. The MT and electrical tomography models delineate the geological boundaries of the sulfide-bearing mineralized deposits in the BFB