1,184 research outputs found

    Fundamental approach to laminar flame propagation

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    The complete system of equations for a theory of laminar flame equations is presented, taking into account both heat conduction and diffusion, for the case of an arbitrary number of simultaneous reactions. The eigenvalue problem determining the flame velocity is formulated. Two examples are given in order to show that explicit analytical expressions for the flame velocity can be obtained, which are in good agreement with the results obtained by numerical integration of the equations. In the first example (hydrazine decomposition) one reaction is considered as global, i.e., rate-controlling, reaction. In the second example (ozone decomposition) a hypothesis is introduced for the concentration of the free radical O, which corresponds to the steady-state approximation generally used in classical chemical kinetics. In both cases approximate explicit formulae are obtained for the flame velocity using legitimate approximation methods, without making drastic assumptions. The steady-state assumption used for the ozone flame has a bearing on a better understanding of the mechanism of chain reactions in general. The method indicated in the paper gives hope that the more complicated chain reactions, such as the combustion of hydrocarbons, will also be made accessible to theoretical computation

    The thermal theory of constant-pressure deflagration for first-order global reactions

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    The one-dimensional thermal theory of constant-pressure deflagration has been discussed in a recent publication by the senior author and G. Millán. In this paper an explicit relation was given for the linear burning velocity in flames supported by first-order global reactions. It is the purpose of the present analysis to extend this work by dropping the assumptions (a) that the average molecular weight of the gas mixture remains constant, and (b) that the thermal conductivity is constant. As the result, the one-dimensional theory of constant-pressure deflagration described in this paper is complete except in so far as the following reasonable approximations are concerned: (a) a constant average specific heat equal to the ratio of heat release per gram of reactant to total temperature rise may be used; (b) the ideal gas law constitutes a satisfactory equation of state for reacting gas mixtures

    The Price of Succession: Diplomatic Negotiations Around the Acknowledgment of György Rákóczi II as a Prince of Transylvania

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    Külföldi diplomaták Bethlen Gábor szolgálatában

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    Kísérletek svéd szövetség biztosítására II. Rákóczi Ferenc szabadságharcához

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    Zülfikár aga portai főtolmács

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