The impact of lithium nitrate on the physical and mechanical properties of Portland cement)

The effectiveness of lithium nitrate as a chemical additive which reduces the negative effects of alkali aggregate reaction was subject to research by scientists in many centres around the world. The literature data on the impact of lithium nitrate on the physical and mechanical properties of cements are rare. Without a precise definition of the impact of lithium nitrate on the cement properties, it is extremely hard to determine its real advantages in practical usage. In this paper, studies were undertaken to assess the impact of LiNO3 on the properties of pastes and mortars with Portland cement. The rate of hydration of the cement with lithium additive was examined by isothermal calorimetry, measurements of setting time and phase composition of cement pastes in the initial stages of hydration. The influence of the admixture on the compressive strength development of mortars after 2, 7 and 28 days of hardening was also researched. Results indicate that lithium nitrate accelerates the early hydration of Portland cement, affecting the precipitation of hydration products. The compressive strength of mortars with lithium admixture decrease after 28 days, although 2 an 7-day strength were greater than the control mortars

Monitoring of the Impact of Lithium Nitrate on the Alkali–aggregate Reaction Using Acoustic Emission Methods

The study analyzed the possibility of using the acoustic emission method to analyse the reaction of alkali with aggregate in the presence of lithium nitrate. Lithium nitrate is a chemical admixture used to reduce adverse effects of corrosion. The tests were carried out using mortars with reactive opal aggregate, stored under the conditions defined by ASTM C227. The acoustic activity of mortars with a corrosion inhibitor was referred to linear changes and microstructure of specimens in the initial reaction stages. The study found a low acoustic activity of mortars with lithium nitrate. Analysis of characteristic parameters of acoustic emission signals, combined with the observation of changes in the microstructure, made it possible to describe the corrosion processes. As the reaction progressed, signals with different characteristics were recorded, indicating aggregate cracking at the initial stage of the reaction, followed by cracking of the cement paste. The results, which were referred to the acoustic activity of reference mortars, confirmed that the reaction of opal aggregate with alkali was mitigated in mortars with lithium nitrate, and the applied acoustic emission method enabled the detection and monitoring of ASR progress

Impact of the air-entrained concrete with the blast-furnace slag cement on the intensity of reinforcement corrosion process

The concrete cover has significant impact on the intensity of reinforcement corrosion process in reinforced concrete elements. Depending on the type of corrosion risk different types of cement are recommended for concrete. In conditions of chloride corrosion, due to, for example, the use of de-icing agents in winter, it is recommended to use concrete with cement containing granulated blast-furnace slag. The risk of chloride corrosion due to the use of de-icing agents is often additionally associated with the frost and repeated freezing and thawing actions of structural elements. The liquid freezing in the pores of concrete increases its volume, which causes the increase of internal stresses and leads to cracks in the concrete cover increasing the diffusion of chlorides. In order to reduce this phenomenon the introduction of air-entraining admixture is beneficial. The paper presents the experimental results that allow to determinate the effect of the air-entraining admixture addition on the intensity of reinforcement corrosion in concrete with blast-furnace slag cement. The tests were carried out on two groups of reinforced concrete specimens subjected to freezing and thawing cycles in 3% NaCl solution. One group of specimens was prepared with the airentraining admixture addition and the other without it. The electrochemical tests of the reinforcement corrosion activity, based on the measurements of the corrosion current density were curried. The phase composition by X-ray diffraction and microstructure of concrete under the scanning electron microscope (SEM) coupled with the X-ray microanalyser (EDS) were examined. The results allowed to comprehensively assess the effect of airentrained concrete with blast-furnace slag cement on the degree of reinforcement corrosion risk in concrete caused by the simultaneous action of chlorides and frost

Sposoby ograniczenia reaktywności kruszywa żwirowego

Effectiveness of selected chemical admixtures and mineral additives to mitigate alkali-silica reaction was compared based on reactive gravel aggregate. Lithium compounds in the form of nitrate and lithium polysilicate were used as chemical admixtures. Natural pozzolans containing zeolite were used as mineral additive. Efficiency of the additive was enhanced by modification with ammonium ions. Linear changes of mortars with crushed gravel aggregates were studied with the accelerated and long-term methods. Additionally, scanning electron microscopy was used for microstructural observations. It was demonstrated that at elevated temperatures the application of lithium compounds provided better protection. Under conditions similar to those in the field, 20-30% of natural pozzolans proved to be more effective in inhibiting the expansion. Regardless of the method of protection applied, the presence of alkali-silica reaction products was detected in the microstructure of the mortars.Na przykładzie reaktywnego kruszywa żwirowego porównano efektywność ograniczenia reakcji alkalia-kruszywo przy pomocy wybranych domieszek chemicznych i dodatków mineralnych. Jako domieszki chemiczne zastosowano związki litu w postaci azotanu i polikrzemianu litu. W przypadku dodatków mineralnych zastosowano naturalną pucolanę, zawierającą zeolit, której efektywność zwiększano poprzez modyfikację jonami amonowymi. Wykonano badania zmian liniowych zapraw z rozdrobnionym kruszywem żwirowym metodą przyspieszoną i długoterminową. Dodatkowo wykonano obserwacje mikrostruktury z wykorzystaniem elektronowego mikroskopu skaningowego. Wykazano, że w warunkach podwyższonej temperatury lepsze zabezpieczenie uzyskano po zastosowaniu związków litu. W warunkach zbliżonych do eksploatacyjnych zastosowanie 20-30% pucolany naturalnej skuteczniej hamowało ekspansję zapraw z kruszywem reaktywnym. Niezależnie od sposobu zabezpieczenia, w mikrostrukturze zapraw wykryto obecność produktów reakcji alkalia-krzemionka

Impact of the air-entrained concrete with the blast-furnace slag cement on the intensity of reinforcement corrosion process

The concrete cover has significant impact on the intensity of reinforcement corrosion process in reinforced concrete elements. Depending on the type of corrosion risk different types of cement are recommended for concrete. In conditions of chloride corrosion, due to, for example, the use of de-icing agents in winter, it is recommended to use concrete with cement containing granulated blast-furnace slag. The risk of chloride corrosion due to the use of de-icing agents is often additionally associated with the frost and repeated freezing and thawing actions of structural elements. The liquid freezing in the pores of concrete increases its volume, which causes the increase of internal stresses and leads to cracks in the concrete cover increasing the diffusion of chlorides. In order to reduce this phenomenon the introduction of air-entraining admixture is beneficial. The paper presents the experimental results that allow to determinate the effect of the air-entraining admixture addition on the intensity of reinforcement corrosion in concrete with blast-furnace slag cement. The tests were carried out on two groups of reinforced concrete specimens subjected to freezing and thawing cycles in 3% NaCl solution. One group of specimens was prepared with the airentraining admixture addition and the other without it. The electrochemical tests of the reinforcement corrosion activity, based on the measurements of the corrosion current density were curried. The phase composition by X-ray diffraction and microstructure of concrete under the scanning electron microscope (SEM) coupled with the X-ray microanalyser (EDS) were examined. The results allowed to comprehensively assess the effect of airentrained concrete with blast-furnace slag cement on the degree of reinforcement corrosion risk in concrete caused by the simultaneous action of chlorides and frost

Properties of ashes formed after the combustion of sewage sludge

The objective of the research presented in the paper was to analyze the ash formed in the process of incineration in the thermal sewage sludge treatment facility being a part of Sitkówka-Nowiny wastewater treatment plant, located in the vicinity of Kielce. The research involved the investigation of heavy metal and total phosphorus content, leachability of certain ions and X-ray phase analysis. The comparison of the obtained results with those available in literature revealed similarities in the crystallographic structure of ashes from different treatment plants. Then, the differences observed in the content of heavy metals in particular ashes are related to the composition of sewage flowing into treatment plants. Attention was also paid to a significant sulphate content revealed in the leachability analysis, found both in the ash from Sitkówka-Nowiny treatment plant and in the ash analyses results available in the literature sources. High sulphate concentration can limit the use of ash for construction purposes

Properties of ashes formed after the combustion of sewage sludge

The objective of the research presented in the paper was to analyze the ash formed in the process of incineration in the thermal sewage sludge treatment facility being a part of Sitkówka-Nowiny wastewater treatment plant, located in the vicinity of Kielce. The research involved the investigation of heavy metal and total phosphorus content, leachability of certain ions and X-ray phase analysis. The comparison of the obtained results with those available in literature revealed similarities in the crystallographic structure of ashes from different treatment plants. Then, the differences observed in the content of heavy metals in particular ashes are related to the composition of sewage flowing into treatment plants. Attention was also paid to a significant sulphate content revealed in the leachability analysis, found both in the ash from Sitkówka-Nowiny treatment plant and in the ash analyses results available in the literature sources. High sulphate concentration can limit the use of ash for construction purposes