Effect of Nanoscale Confinement on the \beta-\alpha Phase Transition in Ag2Se

The confinement of silver selenide was investigated using mesoporous silica. Results from x-ray diffraction and electron microscopy show that the confined material still exhibits a \beta to \alpha transition similar to the one that takes place in the bulk crystalline state but with a transition temperature that depends significantly on the confinement conditions. Decreasing the pore size leads to an increase of the transition temperature, opposite to the behavior of the melting point observed in several metallic and organic materials. In the free particles, on the other hand, no size dependence is observed with particle sizes down to 4 nm

Specific heat of heavy fermion CePd2Si2 in high magnetic fields

We report specific heat measurements on the heavy fermion compound CePd2Si2 in magnetic fields up to 16 T and in the temperature range 1.4-16 K. A sharp peak in the specific heat signals the antiferromagnetic transition at T_N ~ 9.3 K in zero field. The transition is found to shift to lower temperatures when a magnetic field is applied along the crystallographic a-axis, while a field applied parallel to the tetragonal c-axis does not affect the transition. The magnetic contribution to the specific heat below T_N is well described by a sum of a linear electronic term and an antiferromagnetic spin wave contribution. Just below T_N, an additional positive curvature, especially at high fields, arises most probably due to thermal fluctuations. The field dependence of the coefficient of the low temperature linear term, gamma_0, extracted from the fits shows a maximum at about 6 T, at the point where an anomaly was detected in susceptibility measurements. The relative field dependence of both T_N and the magnetic entropy at T_N scales as [1-(B/B_0)^2] for B // a, suggesting the disappearance of antiferromagnetism at B_0 ~ 42 T. The expected suppression of the antiferromagnetic transition temperature to zero makes the existence of a magnetic quantum critical point possible.Comment: to be published in Journal of Physics: Condensed Matte

Superconductivity mediated by a soft phonon mode: specific heat, resistivity, thermal expansion and magnetization of YB6

The superconductor YB6 has the second highest critical temperature Tc among the boride family MBn. We report measurements of the specific heat, resistivity, magnetic susceptibility and thermal expansion from 2 to 300 K, using a single crystal with Tc = 7.2 K. The superconducting gap is characteristic of medium-strong coupling. The specific heat, resistivity and expansivity curves are deconvolved to yield approximations of the phonon density of states, the spectral electron-phonon scattering function and the phonon density of states weighted by the frequency-dependent Grueneisen parameter respectively. Lattice vibrations extend to high frequencies >100 meV, but a dominant Einstein-like mode at ~8 meV, associated with the vibrations of yttrium ions in oversized boron cages, appears to provide most of the superconducting coupling and gives rise to an unusual temperature behavior of several observable quantities. A surface critical field Hc3 is also observed.Comment: 29 pages, 5 tables, 17 figures. Accepted for publication in Phys. Rev.

Thermodynamic transitions in inhomogeneous d-wave superconductors

We study the spectral and thermodynamic properties of inhomogeneous d-wave superconductors within a model where the inhomogeneity originates from atomic scale pair disorder. This assumption has been shown to be consistent with the small charge and large gap modulations observed by scanning tunnelling spectroscopy (STS) on BSCCO. Here we calculate the specific heat within the same model, and show that it gives a semi-quantitative description of the transition width in this material. This model therefore provides a consistent picture of both surface sensitive spectroscopy and bulk thermodynamic properties.Comment: 4 pages, 4 figure

Inequivalent representations of commutator or anticommutator rings of field operators and their applications

Hamiltonian of a system in quantum field theory can give rise to infinitely many partition functions which correspond to infinitely many inequivalent representations of the canonical commutator or anticommutator rings of field operators. This implies that the system can theoretically exist in infinitely many Gibbs states. The system resides in the Gibbs state which corresponds to its minimal Helmholtz free energy at a given range of the thermodynamic variables. Individual inequivalent representations are associated with different thermodynamic phases of the system. The BCS Hamiltonian of superconductivity is chosen to be an explicit example for the demonstration of the important role of inequivalent representations in practical applications. Its analysis from the inequivalent representations' point of view has led to a recognition of a novel type of the superconducting phase transition.Comment: 25 pages, 6 figure

The magnetoresistance of homogeneous and heterogeneous silver-rich silver selenide

The magnetoresistance (MR) effect of the low-temperature phase of silver selenide (-Ag2 + Se) is measured as a function of composition. Very small composition variations in the order of = 10–6 are achieved by coulometric titration and can be performed simultaneously during the MR measurement. A homogeneous Ag2 + Se shows an ordinary magnetoresistance (OMR) effect, which can be well described by the two-band model. For silver selenide with a heterogenous silver excess, we found quite a different MR behavior. Up to a minor silver excess of 1×10–4 10–2) shows again an OMR effect

Peculiarities of electronic heat capacity of thulium cuprates in pseudogap state

Precise calorimetric measurements have been carried out in the 7 - 300 K temperature range on two ceramic samples of thulium 123 cuprates TmBa2Cu3O6.92 and TmBa2Cu3O6.70. The temperature dependence of the heat capacity was analyzed in the region where the pseudogap state (PGS) takes place. The lattice contribution was subtracted from the experimental data. The PGS component has been obtained by comparing electronic heat capacities of two investigated samples because the PGS contribution for the 6.92 sample is negligible. The anomalous behavior of the electronic heat capacity near the temperature boundary of PGS was found. It is supposed that this anomaly is due to peculiarities in N(E) function where N is the density of electronic states and E is the energy of carriers of charge.Comment: 12 pages, 3 Postscript figure

Magnetic resonance at 41 meV and charge dynamics in YBa_2Cu_3O_6.95

We report an Eliashberg analysis of the electron dynamics in YBa_2Cu_3O_6.95. The magnetic resonance at 41 meV couples to charge carriers and defines the characteristic shape in energy of the scattering rate \tau^{-1}(T,\omega) which allows us to construct the charge-spin spectral density I^2\chi(\omega,T) at temperature T. The T dependence of the weight under the resonance peak in I^2\chi(\omega,T) agrees with experiment as does that of the London penetration depth and of the microwave conductivity. Als, at T=0 condensation energy, the fractional oscillator strength in the condensate, and the ratio of gap to critical temperature agree well with the data.Comment: 7 Pages, 3 Figures, accepted for publication in Europhysics Letter

Superconducting Diamagnetic Fluctuations in MgB2

The fluctuating diamagnetic magnetization Mfl at constant field H as a function of temperature and the isothermal magnetization Mfl vs H are measured in MgB2, above the superconducting transition temperature. The expressions for Mfl in randomly oriented powders are derived in the Gaussian approximation of local Ginzburg-Landau theory and used for the analysis of the data. The scaled magnetization Mfl/H^{1/2}*T is found to be field dependent. In the limit of evanescent field the behaviour for Gaussian fluctuations is obeyed while for H>~ 100 Oe the field tends to suppress the fluctuating pairs, with a field dependence of Mfl close to the one expected when short wavelength fluctuations and non-local electrodynamic effects are taken into account. Our data, besides providing the isothermal magnetization curves for T>Tc(0) in a BCS-type superconductor such as MgB2, evidence an enhancement of the fluctuating diamagnetism which is related to the occurrence in this new superconductor of an anisotropic spectrum of the superconducting fluctuations.Comment: Tex file, 4 pages, 3 ps figures, submitted to Phys. Rev. Let