(Bio)isosteres of Nucleotides: When the Furanosyl Unit is Modified

National audienc

One-pot synthesis of tertiary alkyl fluorides from methyl oxalates by radical deoxyfluorination under photoredox catalysis

International audienceTertiary alkyl fluorides have been prepared from methyl oxalates derived from tertiary alcohols by a sequential one-pot hydrolysis/photoredox catalyzed radical deoxyfluorination sequence. The reaction operates under mild conditions and tolerates a wide range of functional groups. This method provides an alternative approach to ionic deoxyfluorination transformations for the incorporation of Carbone–Fluorine quaternary centers into organic molecules

An investigation of the stereoselective synthesis and synthetic applications of functionalised pyrans

EThOS - Electronic Theses Online ServiceGBUnited Kingdo

One-pot synthesis of tertiary alkyl fluorides frommethyl oxalates by radical deoxyfluorination underphotoredox catalysis

International audienc

Synthesis of Alkyl Fluorides by Silver‐Catalyzed Radical Decarboxylative Fluorination of Cesium Oxalates

International audienc

SYNTHESIS OF ALKYL FLUORIDES BY RADICAL DEOXYFLUORINATION OF CESIUM OXALATES

International audienc

Synthèse de Fluoroalkyles par Fluoration Radicalaire Décarboxylative d'Oxalates de Césium

International audienc

Synthèse de Fluoroalkyles par Fluoration Radicalaire Décarboxylative d'Oxalates de Césium

International audienc

Passerini Three-Component Reaction of Alcohols under Catalytic Aerobic Oxidative Conditions

Alcs. instead of aldehydes were used in the Passerini three-component reaction under catalytic aerobic conditions. Mixing alcs., isocyanides, and carboxylic acids in toluene in the presence of a catalytic amt. of cupric chloride, NaNO2, and TEMPO afforded, under an oxygen atm., the P-3CR adducts in good yields. [on SciFinder (R)

Synthesis of Fluorinated Modified Dinucleotide

International audienc