Preparation and properties of new elastomeric systems containing alternative fillers

The present paper deals with a preparation of new elastomeric compounds containing two kinds of alternative additives based on wastes from glass production and energetics. Named alternative fillers were mixed into rubber compounds asa replacement of commonly used fillers – carbon black and silica. Rheological properties, vulcanization characteristics as well as hardness and rebound resilience of vulcanizates, which are important parameters for their industrial application, have been studied in the new prepared elastomeric systems. The resulting vulcanizates containing alternative fillers exhibit improved properties, in particular low rolling resistance and high rebound resilience, while maintaining optimal hardness values. Used raw material substitution can also bring significant environmental and economic effects

Preparation and properties of new elastomeric systems containing alternative fillers

The present paper deals with a preparation of new elastomeric compounds containing two kinds of alternative additives based on wastes from glass production and energetics. Named alternative fillers were mixed into rubber compounds asa replacement of commonly used fillers – carbon black and silica. Rheological properties, vulcanization characteristics as well as hardness and rebound resilience of vulcanizates, which are important parameters for their industrial application, have been studied in the new prepared elastomeric systems. The resulting vulcanizates containing alternative fillers exhibit improved properties, in particular low rolling resistance and high rebound resilience, while maintaining optimal hardness values. Used raw material substitution can also bring significant environmental and economic effects

Targeted modification of the composition of polymer systems for industrial applications

The targeted modification of the material composition is a common procedure used to improve the parameters of the final products. This paper deals with the targeted modification of polymer systems composition using two various types of alternative fillers. The first type of alternative filler (SVD) has been obtained from energetics where it arises as a by-product of flue gas desulfurization. The second alternative filler used (KAL) is based on waste from glass production. The elastomeric systems designed for the production of car tires and solid wheels for transport systems were used in the role of modified polymer systems. Alternative fillers (SVD, KAL) have been applied as a substitution of commonly used fillers (carbon black, silica). The filler – elastomeric matrix interaction, rheology, cure characteristics, as well as hardness and rebound resilience of vulcanizates, which are important parameters for their industrial application, have been studied in the new prepared polymeric systems. The main output of the work is a new formulation of an elastomeric system for industrial applications with high rebound resilience and low rolling resistance, which is the subject of the international patent. The modification of composition using raw material substitution can also bring significant environmental and economic effects

The Effect of High-Energy Ionizing Radiation on the Mechanical Properties of a Melamine Resin, Phenol-Formaldehyde Resin, and Nitrile Rubber Blend

Irradiation by ionizing radiation is a specific type of controllable modification of the physical and chemical properties of a wide range of polymers, which is, in comparison to traditional chemical methods, rapid, non-polluting, simple, and relatively cheap. In the presented paper, the influence of high-energy ionizing radiation on the basic mechanical properties of the melamine resin, phenol-formaldehyde resin, and nitrile rubber blend has been studied for the first time. The mechanical properties of irradiated samples were compared to those of non-irradiated materials. It was found that radiation doses up to 150 kGy improved the mechanical properties of the tested materials in terms of a significant increase in stress at break, tensile strength, and tensile modulus at 40% strain, while decreasing the value of strain at break. At radiation doses above 150 kGy, the irradiated polymer blend is already degrading, and its tensile characteristics significantly deteriorate. An radiation dose of 150 kGy thus appears to be optimal from the viewpoint of achieving significant improvement, and the radiation treatment of the given polymeric blend by a beam of accelerated electrons is a very promising alternative to the traditional chemical mode of treatment which impacts the environment

Untersuchung des Einflusses von Chitosan auf ausgewählte Eigenschaften von Elastomermischunge

The current trend of greening production is increasingly bringing to the fore alternative types of fillers, such as biofillers, which are obtained from renewable sources or waste [1, 2]. Unfortunately, biofillers cannot be used as majority fillers due to their incompatibility with elastomer matrices and high biodegradability susceptibility [3, 4]. Therefore, the way to their efficient industrial use leads through supplementary fillers to the commonly used inorganic fillers and the partial replacement of these fillers in the blend. The influence of Chitosan as the majority filler has been investigated and its combination with carbon black filler on the elastomeric matrix of natural rubber was investigated in the presented work. The results were compared with natural rubber blends filled exclusively with carbon black. Natural rubber blends with different content of Chitosan and carbon black and their various combinations were subjected to the determination of vulcanization parameters, mechanical properties before and after thermo-oxidative aging, and scanning electron microscopy. Although the scanning electron microscopy analysis confirmed the expected negative impact of Chitosan as the majority filler on the tensile properties of the vulcanizate, its significant impact on the main vulcanization parameters such as scorch time and optimal vulcanization time was also demonstrated. In the case of blends with a combination of carbon black and Chitosan, it has been shown that Chitosan, in addition to the filler function, also acts as an antioxidant agent through its functional groups, limiting the process of degradation of mechanical properties of natural rubber blends due to their thermo-oxidative aging. It can be concluded that precisely because of its antioxidant and anti-degradation effects, Chitosan can be, in addition to carbon black filler, an excellent additional filler for elastomeric blends.Web of Science54444042