3 research outputs found
Co(III) Complexes as p‑Dopants in Solid-State Dye-Sensitized Solar Cells
Following our recent work on the
use of CoÂ(III) complexes as p-type
dopants for triarylamine-based organic hole-conductors, we herein
report on two new CoÂ(III) complexes for doping applications. With
the aim of ameliorating the dopant’s suitability for its use
in solid-state dye-sensitized solar cells, we show how the properties
of the dopant can be easily adjusted by a slight modification of the
molecular structure. We prove the eligibility of the two new dopants
by characterizing their optical and electrochemical properties and
give evidence that both of them can be used to oxidize the molecular
hole-transporter spiro-MeOTAD. Finally, we fabricate high-performance
solid-state dye-sensitized solar cells using a state-of-the-art metal-free
organic sensitizer in order to elucidate the influence of the type
of dopant on device performance
Molecular Engineering of Organic Dyes for Improved Recombination Lifetime in Solid-State Dye-Sensitized Solar Cells
A major limitation of solid-state
dye-sensitized solar cells is
a short electron diffusion length, which is due to fast recombination
between electrons in the TiO<sub>2</sub> electron-transporting layer
and holes in the 2,2′,7,7′-tetrakisÂ(<i>N</i>,<i>N</i>-di-<i>p</i>-methoxyphenylamine)-9,9′-spirobifluorene
(Spiro-OMeTAD) hole-transporting layer. In this report, the sensitizing
dye that separates the TiO<sub>2</sub> from the Spiro-OMeTAD was engineered
to slow recombination and increase device performance. Through the
synthesis and characterization of three new organic D-Ï€-A sensitizing
dyes (WN1, WN3, and WN3.1), the quantity and placement of alkyl chains
on the sensitizing dye were found to play a significant role in the
suppression of recombination. In solid-state devices using Spiro-OMeTAD
as the hole-transport material, these dyes achieved the following
efficiencies: 4.9% for WN1, 5.9% for WN3, and 6.3% for WN3.1, compared
to 6.6% achieved with Y123 as a reference dye. Of the dyes investigated
in this study, WN3.1 is shown to be the most effective at suppressing
recombination in solid-state dye-sensitized solar cells, using transient
photovoltage and photocurrent measurements
Tris(2-(1<i>H</i>-pyrazol-1-yl)pyridine)cobalt(III) as p-Type Dopant for Organic Semiconductors and Its Application in Highly Efficient Solid-State Dye-Sensitized Solar Cells
Chemical doping is an important strategy to alter the charge-transport properties of both molecular and polymeric organic semiconductors that find widespread application in organic electronic devices. We report on the use of a new class of Co(III) complexes as p-type dopants for triarylamine-based hole conductors such as spiro-MeOTAD and their application in solid-state dye-sensitized solar cells (ssDSCs). We show that the proposed compounds fulfill the requirements for this application and that the discussed strategy is promising for tuning the conductivity of spiro-MeOTAD in ssDSCs, without having to rely on the commonly employed photo-doping. By using a recently developed high molar extinction coefficient organic D-π-A sensitizer and p-doped spiro-MeOTAD as hole conductor, we achieved a record power conversion efficiency of 7.2%, measured under standard solar conditions (AM1.5G, 100 mW cm<sup>–2</sup>). We expect these promising new dopants to find widespread applications in organic electronics in general and photovoltaics in particular