1 research outputs found
Dendrite-Free Polygonal Sodium Deposition with Excellent Interfacial Stability in a NaAlCl<sub>4</sub>–2SO<sub>2</sub> Inorganic Electrolyte
Room-temperature
Na-metal-based rechargeable batteries, including Na–O<sub>2</sub> and Na–S systems, have attracted attention due to their high
energy density and the abundance of sodium resources. Although these
systems show considerable promise, concerns regarding the use of Na
metal should be addressed for their success. Here, we report dendrite-free
Na-metal electrode for a Na rechargeable battery, engineered by employing
nonflammable and highly Na<sup>+</sup>-conductive NaAlCl<sub>4</sub>·2SO<sub>2</sub> inorganic electrolyte, as a result, showing
superior electrochemical performances to those in conventional organic
electrolytes. We have achieved a hard-to-acquire combination of nondendritic
Na electrodeposition and highly stable solid electrolyte interphase
at the Na-metal electrode, enabled by inducing polygonal growth of
Na deposit using a highly concentrated Na<sup>+</sup>-conducting inorganic
electrolyte and also creating highly dense passivation film mainly
composed of NaCl on the surface of Na-metal electrode. These results
are highly encouraging in the development of room-temperature Na rechargeable
battery and provide another strategy for highly reliable Na-metal-based
rechargeable batteries