Steady Characteristics of High- Speed Micro-Gas Journal Bearings With Different Gaseous Lubricants and Extreme Temperature Difference

High-speed micro-gas journal bearing is one of the essential components of micro-gas turbines. As for the operating conditions of bearings, the high-speed, high-temperature, ultra-high temperature difference along the axial direction and the species of gaseous lubricants are extremely essential to be taken into account, and the effects of these factors are examined in this paper. The first-order modified Reynolds equation including the thermal creep, which results from the extremely large temperature gradient along the axial direction, is first derived and coupled with the simplified energy equation to investigate the steady hydrodynamic characteristics of the micro-gas bearings. Under the isothermal condition, it is found that CO 2 can not only improve the stability of bearings but also generate a relatively higher load capacity by some comparisons. Thus, CO 2 is chosen as the lubricant to further explore the influence of thermal creep. As the rotation speed and eccentricity ratio change, the thermal creep hardly has any effect on the gas film pressure. However, the shorter bearing length can augment the thermal creep. Compared with the cases without the thermal creep, the thermal creep could remarkably destroy the stability of gas bearing, but it might slightly enhance the load capacity

Comparison between anterolateral thigh perforator free flaps and pectoralis major pedicled flap for reconstruction in oral cancer patients-A quality of life analysis

The aim of this study was to compare the differences between anterolateral thigh perforator free flaps (ALTFF) and pectoralis major myocutaneous flap (PMMF) for reconstruction in oral cancer patients. Method and Patients: who received free flap or PMMF reconstruction after ablation surgeries were eligible for the current study. The patients' demographic data, medical history, and quality of life scores(Medical Outcomes Study-Short Form-36 (MOS SF-36) and the University of Washington Quality of Life (UW-QOL) questionnaires were collected. Results: 81 of 118 questionnaires were returned (68.64%). There was signi.cant differences between two groups in the gender (P<0.005). Patients reconstructed with ALTFF had better appearance domains and better shoulders domains, in addition to better role emotion domains. Conclusions: Using either PMMF or ALTFF for reconstruction of oral defects after cancer resection signi.cantly in.uences a patient's quality of life. Data from this study provide useful information for physicians and patients during their discussion of reconstruction modalities for oral cancers

Fabrication Process Independent And Robust Aggregation Of Detonation Nanodiamonds In Aqueous Media

In the past detonation nanodiamonds (DNDs), sized 3–5 nm, have been praised for their colloidal stability in aqueous media, thereby attracting vast interest in a wide range of applications including nanomedicine. More recent studies have challenged the consensus that DNDs are monodispersed after their fabrication process, with their aggregate formation dynamics poorly understood. Here we reveal that DNDs in aqueous solution, regardless of their post-synthesis de-agglomeration and purification methods, exhibit hierarchical aggregation structures consisting of chain-like and cluster aggregate morphologies. With a novel characterization approach combining machine learning with direct cryo-transmission electron microscopy and with X-ray scattering and vibrational spectroscopy, we show that their aggregate morphologies of chain and cluster ratios and the corresponding size and fractal dimension distributions vary with the post-synthesis treatment methods. In particular DNDs with positive ζ-potential form to a hierarchical structure that assembles aggregates into large networks. DNDs purified with the gas phase annealing and oxidation tend to have more chain-like aggregates. Our findings provide important contribution in understanding the DND interparticle interactions to control the size, polydispersity and aggregation of DNDs for their desired applications

Lewis Acidity and Basicity of Mixed Chlorometallate Ionic Liquids: Investigations from Surface Analysis and Fukui Function

Mixed chlorometallate ionic liquids (ILs) have been regarded as potential solvents, catalysts, and reagents for many organic processes. The acidity and basicity of these ILs were correlated with theoretically estimated parameters such as electrostatic surface potential maxima and minima, average local surface ionization energy, and Fukui and dual descriptor functions. The introduction of metal chloride into the anions would influence the acidity/basicity of ILs by withdrawing the electron density from the cationic counterpart. For the [C4mim]-based ILs with the mixed-metal anions, the acidity tends to attenuate while the basicity becomes stronger, as compared to the corresponding chloroaluminate ILs. However, the acidity of [(C2H5)3NH]-based ILs with the mixed-metal anions are greater than that of the net chloroaluminate ILs. The Fukui function values showed that most of the mixed chlorometallate ILs belong to bifunctional distribution. The mixed chlorometallate ILs both have electrophilic and nucleophilic sites, which would be beneficial for their applications

Mixed Chlorometallate Ionic Liquids as C₄ Alkylation Catalysts: A Quantitative Study of Acceptor Properties

The acceptor properties of mixed chlorometallate ionic liquids for isobutane-butene alkylation (C4 alkylation) reaction were studied. These ionic liquids were prepared by mixing metal chlorides with either triethylamine hydrochloride or 1-butyl-3-methylimidazolium chloride in various molar ratios. Using triethylphosphine oxide as a probe, Gutmann Acceptor Numbers (AN) of the catalysts were determined, and the Lewis acidity of mixed chlorometallate ionic liquids was quantitatively measured. Additionally, AN value was developed to determine the relationship between Lewis acidity and catalytic selectivity. The favorite AN value for the C4 alkylation reaction should be around 93.0. The [(C2H5)3NH]Cl&#8315;AlCl3&#8722;CuCl appears to be more Lewis acidity than that of [(C2H5)3NH]Cl&#8315;AlCl3. The correlation of the acceptor numbers to speciation of the mixed chlorometallate ionic liquids has also been investigated. [AlCl4]&#8722;, [Al2Cl7]&#8722;, and [MAlCl5]&#8722; (M = Cu, Ag) are the main anionic species of the mixed chlorometallate ILs. While the presence of [(C2H5)3N&#183;M]+ cation always decreases the acidity of the [(C2H5)3NH]Cl&#8722;AlCl3&#8722;MCl ionic liquids

RAMRSGL: A Robust Adaptive Multinomial Regression Model for Multicancer Classification

In view of the challenges of the group Lasso penalty methods for multicancer microarray data analysis, e.g., dividing genes into groups in advance and biological interpretability, we propose a robust adaptive multinomial regression with sparse group Lasso penalty (RAMRSGL) model. By adopting the overlapping clustering strategy, affinity propagation clustering is employed to obtain each cancer gene subtype, which explores the group structure of each cancer subtype and merges the groups of all subtypes. In addition, the data-driven weights based on noise are added to the sparse group Lasso penalty, combining with the multinomial log-likelihood function to perform multiclassification and adaptive group gene selection simultaneously. The experimental results on acute leukemia data verify the effectiveness of the proposed method