Momentum distribution, vibrational dynamics and the potential of mean force in ice

By analyzing the momentum distribution obtained from path integral and phonon calculations we find that the protons in hexagonal ice experience an anisotropic quasi-harmonic effective potential with three distinct principal frequencies that reflect molecular orientation. Due to the importance of anisotropy, anharmonic features of the environment cannot be extracted from existing experimental distributions that involve the spherical average. The full directional distribution is required, and we give a theoretical prediction for this quantity that could be verified in future experiments. Within the quasi-harmonic context, anharmonicity in the ground state dynamics of the proton is substantial and has quantal origin, a finding that impacts the interpretation of several spectroscopies

Structural reliability prediction of a steel bridge element using dynamic object oriented Bayesian Network (DOOBN)

Different from conventional methods for structural reliability evaluation, such as, first/second-order reliability methods (FORM/SORM) or Monte Carlo simulation based on corresponding limit state functions, a novel approach based on dynamic objective oriented Bayesian network (DOOBN) for prediction of structural reliability of a steel bridge element has been proposed in this paper. The DOOBN approach can effectively model the deterioration processes of a steel bridge element and predict their structural reliability over time. This approach is also able to achieve Bayesian updating with observed information from measurements, monitoring and visual inspection. Moreover, the computational capacity embedded in the approach can be used to facilitate integrated management and maintenance optimization in a bridge system. A steel bridge girder is used to validate the proposed approach. The predicted results are compared with those evaluated by FORM method

A non-Gaussian continuous state space model for asset degradation

The degradation model plays an essential role in asset life prediction and condition based maintenance. Various degradation models have been proposed. Within these models, the state space model has the ability to combine degradation data and failure event data. The state space model is also an effective approach to deal with the multiple observations and missing data issues. Using the state space degradation model, the deterioration process of assets is presented by a system state process which can be revealed by a sequence of observations. Current research largely assumes that the underlying system development process is discrete in time or states. Although some models have been developed to consider continuous time and space, these state space models are based on the Wiener process with the Gaussian assumption. This paper proposes a Gamma-based state space degradation model in order to remove the Gaussian assumption. Both condition monitoring observations and failure events are considered in the model so as to improve the accuracy of asset life prediction. A simulation study is carried out to illustrate the application procedure of the proposed model

Estimating medical costs from a transition model

Nonparametric estimators of the mean total cost have been proposed in a variety of settings. In clinical trials it is generally impractical to follow up patients until all have responded, and therefore censoring of patient outcomes and total cost will occur in practice. We describe a general longitudinal framework in which costs emanate from two streams, during sojourn in health states and in transition from one health state to another. We consider estimation of net present value for expenditures incurred over a finite time horizon from medical cost data that might be incompletely ascertained in some patients. Because patient specific demographic and clinical characteristics would influence total cost, we use a regression model to incorporate covariates. We discuss similarities and differences between our net present value estimator and other widely used estimators of total medical costs. Our model can accommodate heteroscedasticity, skewness and censoring in cost data and provides a flexible approach to analyses of health care cost.Comment: Published in at http://dx.doi.org/10.1214/193940307000000266 the IMS Collections (http://www.imstat.org/publications/imscollections.htm) by the Institute of Mathematical Statistics (http://www.imstat.org