2,763 research outputs found
Ferromagnetism in Fe-doped Ba6Ge25 Chiral Clathrate
We have successfully synthesized a Ba6Ge25 clathrate, substituting 3 Fe per
formula unit by Ge. This chiral clathrate has Ge sites forming a framework of
closed cages and helical tunnel networks. Fe atoms randomly occupy these sites,
and exhibit high-spin magnetic moments. A ferromagnetic transition is observed
with Tc = 170 K, the highest observed Tc for a magnetic clathrate. However, the
magnetic phase is significantly disordered, and exhibits a transformation to a
re-entrant spin glass phase. This system has a number of features in common
with other dilute magnetic semiconductors.Comment: Submitted to Applied Physics Letters. Fig. 1 resolution reduced for
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Data catalog series for space science and applications flight missions. Volume 6: Master index volume
The main purpose of the data catalog series is to provide descriptive references to data generated by space science flight missions. The data sets described include all of the actual holdings of the Space Science Data Center (NSSDC), all data sets for which direct contact information is available, and some data collections held and serviced by foreign investigators, NASA, and other U.S. government agencies. This volume contains the Master Index. The following spacecraft are included: Mariner, Pioneer, Pioneer Venus, Venera, Viking, Voyager, and Helios. Separate indexes to the planetary and interplanetary missions are also provided
Prognostic Launch Vehicle Probability of Failure Assessment Methodology for Conceptual Systems Predicated on Human Causal Factors
Lessons learned from past failures of launch vehicle developments and operations were used to create a new method to predict the probability of failure of conceptual systems. Existing methods such as Probabilistic Risk Assessments and Human Risk Assessments were considered but found to be too cumbersome for this type of system-wide application for yet-to-be-flown vehicles. The basis for this methodology were historic databases of past failures, where it was determined that various faulty human-interactions were the predominant root causes of failure rather than deficient component reliabilities evaluated through statistical analysis. This methodology contains an expert scoring part which can be used in either a qualitative or a quantitative mode. The method produces two products: a numerical score of the probability of failure or guidance to program management on critical areas in need of increased focus to improve the probability of success. In order to evaluate the effectiveness of this new method, data from a concluded vehicle program (USAF's Titan IV with the Centaur G-Prime upper stage) was used as a test case. Although the theoretical vs. actual probability of failure was found to be in reasonable agreement (4.46% vs. 6.67% respectively) the underlying sub-root cause scoring had significant disparities attributable to significant organizational changes and acquisitions. Recommendations are made for future applications of this method to ongoing launch vehicle development programs
NMR relaxation studies of electronic structure in NbSe3
NMR spin-lattice relaxation measurements of the Nb93 resonance for each Nb site were performed on an aligned, multicrystalline NbSe3 sample at different temperatures. Results are associated with local electron densities of states for each of the three crystallographic sites, demonstrating Fermi-surface changes associated with the two charge-density-wave phase transitions. The most significant Fermi-surface changes occur for the yellow and orange crystallographic sites, at the high- and low-temperature phase transitions, respectively. The third site, however, is found to be noninsulating. A comparison is made to band theory and other experimental results
Direct Measure of Giant Magnetocaloric Entropy Contributions in Ni-Mn-In
Off-stoichiometric alloys based on Ni 2 MnIn have drawn attention due to the
coupled first order magnetic and structural transformations, and the large
magnetocaloric entropy associated with the transformations. Here we describe
calorimetric and magnetic studies of four compositions. The results provide a
direct measure of entropy changes contributions including at the first-order
phase transitions, and thereby a determination of the maximum field-induced
entropy change corresponding to the giant magnetocaloric effect. We find a
large excess entropy change, attributed to magneto-elastic coupling, but only
in compositions with no ferromagnetic order in the high-temperature austenite
phase. Furthermore, a molecular field model corresponding to antiferromagnetism
of the low-temperature phases is in good agreement, and nearly independent of
composition, despite significant differences in overall magnetic response of
these materials
Calorimetric and magnetic study for NiMnIn and relative cooling power in paramagnetic inverse magnetocaloric systems
The non-stoichiometric Heusler alloy NiMnIn undergoes a
martensitic phase transformation in the vicinity of 345 K, with the high
temperature austenite phase exhibiting paramagnetic rather than ferromagnetic
behavior, as shown in similar alloys with lower-temperature transformations.
Suitably prepared samples are shown to exhibit a sharp transformation, a
relatively small thermal hysteresis, and a large field-induced entropy change.
We analyzed the magnetocaloric behavior both through magnetization and direct
field-dependent calorimetry measurements. For measurements passing through the
first-order transformation, an improved method for heat-pulse relaxation
calorimetry was designed. The results provide a firm basis for the analytic
evaluation of field-induced entropy changes in related materials. An analysis
of the relative cooling power (RCP), based on the integrated field-induced
entropy change and magnetizing behavior of the Mn spin system with
ferromagnetic correlations, shows that a significant RCP may be obtained in
these materials by tuning the magnetic and structural transformation
temperatures through minor compositional changes or local order changes
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