Generation linewidth of an auto-oscillator with a nonlinear frequency shift: Spin-torque nano-oscillator

It is shown that the generation linewidth of an auto-oscillator with a nonlinear frequency shift (i.e. an auto-oscillator in which frequency depends on the oscillation amplitude) is substantially larger than the linewidth of a conventional quasi-linear auto-oscillator due to the renormalization of the phase noise caused by the nonlinearity of the oscillation frequency. The developed theory, when applied to a spin-torque nano-contact auto-oscillator, predicts a minimum of the generation linewidth when the nano-contact is magnetized at a critical angle to its plane, corresponding to the minimum nonlinear frequency shift, in good agreement with recent experiments.Comment: 4 pages, 2 figure

Revealing the Exciton Fine Structure in PbSe Nanocrystal Quantum Dots

We measure the photoluminescence (PL) lifetime, $\tau$, of excitons in colloidal PbSe nanocrystals (NCs) at low temperatures to 270~mK and in high magnetic fields to 15~T. For all NCs (1.3-2.3~nm radii), $\tau$ increases sharply below 10~K but saturates by 500~mK. In contrast to the usual picture of well-separated ``bright" and ``dark" exciton states (found, e.g., in CdSe NCs), these dynamics fit remarkably well to a system having two exciton states with comparable - but small - oscillator strengths that are separated by only 300-900 $\mu$eV. Importantly, magnetic fields reduce $\tau$ below 10~K, consistent with field-induced mixing between the two states. Magnetic circular dichroism studies reveal exciton g-factors from 2-5, and magneto-PL shows $>$10\% circularly polarized emission.Comment: To appear in Physical Review Letter

Lineshape distortion in a nonlinear auto-oscillator near generation threshold: Application to spin-torque nano-oscillators

The lineshape in an auto-oscillator with a large nonlinear frequency shift in the presence of thermal noise is calculated. Near the generation threshold, this lineshape becomes strongly non-Lorentzian, broadened, and asymmetric. A Lorentzian lineshape is recovered far below and far above threshold, which suggests that lineshape distortions provide a signature of the generation threshold. The theory developed adequately describes the observed behavior of a strongly nonlinear spin-torque nano-oscillator.Comment: 4 pages, 3 figure

Interactions Between Spermine-Derivatized Tentacle Porphyrins And The Human Telomeric DNA G-Quadruplex

G-rich DNA sequences have the potential to fold into non-canonical G-Quadruplex (GQ) structures implicated in aging and human diseases, notably cancers. Because stabilization of GQs at telomeres and oncogene promoters may prevent cancer, there is an interest in developing small molecules that selectively target GQs. Herein, we investigate the interactions of meso-tetrakis-(4-carboxysperminephenyl)porphyrin (TCPPSpm4) and its Zn(II) derivative (ZnTCPPSpm4) with human telomeric DNA (Tel22) via UV-Vis, circular dichroism (CD), and fluorescence spectroscopies, resonance light scattering (RLS), and fluorescence resonance energy transfer (FRET) assays. UV-Vis titrations reveal binding constants of 4.7 × 10⁶ and 1.4 × 10⁷ M⁻¹ and binding stoichiometry of 2–4:1 and 10–12:1 for TCPPSpm4 and ZnTCPPSpm4, respectively. High stoichiometry is supported by the Job plot data, CD titrations, and RLS data. FRET melting indicates that TCPPSpm4 stabilizes Tel22 by 36 ± 2 °C at 7.5 eq., and that ZnTCPPSpm4 stabilizes Tel22 by 33 ± 2 °C at ~20 eq.; at least 8 eq. of ZnTCPPSpm4 are required to achieve significant stabilization of Tel22, in agreement with its high binding stoichiometry. FRET competition studies show that both porphyrins are mildly selective for human telomeric GQ vs duplex DNA. Spectroscopic studies, combined, point to end-stacking and porphyrin self-association as major binding modes. This work advances our understanding of ligand interactions with GQ DNA

Generation of two-photon EPR and Wstates

In this paper we present a scheme for generation of two-photon EPR and W states in the cavity QED context. The scheme requires only one three-level Rydberg atom and two or three cavities. The atom is sent to interact with cavities previously prepared in vacuum states, via two-photon process. An appropriate choice of the interaction times one obtains the mentioned state with maximized fidelities. These specific times and the values of success probability and fidelity are discussed.Comment: 4 pages, 5 figure