7,422 research outputs found
Effects of the Spin-Orbit Coupling and the Superconductivity in simple-cubic alpha-Polonium
We have investigated the mechanism of stabilizing the simple-cubic (SC)
structure in polonium (alpha- Po), based on the phonon dispersion calculations
using the first-principles all-electron band method. We have demonstrated that
the stable SC structure results from the suppression of the Peierls instability
due to the strong spin-orbit coupling (SOC) in alpha-Po. Further, we have
explored the possible superconductivity in alpha-Po, and predicted that it
becomes a superconductor with Tc ~ 4 K. The transverse soft phonon mode at q ~
2/3 R, which is greatly influenced by the SOC, plays an important role both in
the structural stability and the superconductivity in alpha-Po. We have
discussed effects of the SOC and the volume variation on the phonon dispersions
and superconducting properties of alpha-Po.Comment: 5pages, 5figure
Pressure-induced Phonon Softenings and the Structural and Magnetic Transitions in CrO
To investigate the pressure-induced structural transitions of chromium
dioxide (CrO), phonon dispersions and total energy band structures are
calculated as a function of pressure. The first structural transition has been
confirmed at P 10 GPa from the ground state tetragonal CrO
(t-CrO) of rutile type to orthorhombic CrO (o-CrO) of
CaCl type. The half-metallic property is found to be preserved in
o-CrO. The softening of Raman-active B phonon mode, which is
responsible for this structural transition, is demonstrated. The second
structural transition is found to occur for P 61.1 GPa from ferromagnetic
(FM) o-CrO to nonmagnetic (NM) monoclinic CrO (m-CrO) of
MoO type, which is related to the softening mode at {\bf q} =
R(1/2,0,1/2). The third structural transition has been newly identified at P=
88.8 GPa from m-CrO to cubic CrO of CaF type that is a FM
insulator
Correlation Assisted Phonon Softenings and the Mott-Peierls Transition in VO
To explore the driving mechanisms of the metal-insulator transition (MIT) and
the structural transition in VO2, we have investigated phonon dispersions of
rutile VO2 (R-VO2) in the DFT and the DFT+U (U : Coulomb correlation) band
calculations. We have found that the phonon softening instabilities occur in
both cases, but the softened phonon mode only in the DFT+U describes properly
both the MIT and the structural transition from R-VO2 to monoclinic VO2
(M1-VO2). This feature demonstrates that the Coulomb correlation effect plays
an essential role of assisting the Peierls transition in R-VO2. We have also
found from the phonon dispersion of M1-VO2 that M1 structure becomes unstable
under high pressure. We have predicted a new phase of VO2 at high pressure that
has a monoclinic CaCl2-type structure with metallic nature
Naphthalimide Trifluoroacetyl Acetonate: A Hydrazine-Selective Chemodosimetric Sensor
The trifluoroacetyl acetonate naphthalimide derivative 1 has been synthesized in good yield. In acetonitrile solution, compound 1 reacts selectively with hydrazine (NH2NH2) to give a five-membered ring. This leads to OFF-ON fluorescence with a maximum intensity at 501 nm as well as easily discernible color changes. Based on a readily discernible and reproducible 3.9% change in overall fluorescence intensity, the limit of detection for 1 is 3.2 ppb (0.1 mu M), which is below the accepted limit for hydrazine set by the U.S. Environmental Protection Agency (EPA). Compound 1 is selective for hydrazine over other amines, including NH4OH, NH2OH, ethylenediamine, methylamine, n-butylamine, piperazine, dimethylamine, triethylamine, pyridine, and is not perturbed by environmentally abundant metal ions. When supported on glass-backed silica gel TLC plates, compound 1 acts as a fluorimetric and colorimetric probe for hydrazine vapor at a partial pressure of 9.0 mm Hg, with selectivity over other potentially interfering volatile analytes, including ammonia, methylamine, n-butylamine, formaldehyde, acetaldehyde, H2O2, HCl, and CO2 being observed. Probe 1 can also be used for the detection of hydrazine in HeLa cells and does so without appreciable interference from other biologically abundant amines and metal ions.U.S. National Science Foundation CHE-1057904Robert A. Welch Foundation F-1018CRI project grant from National Research Foundation of Korea (NRF)Korea government (MSIP) 2009-0081566Chemistr
Second Stage Short Run (X,vc) and (X,sc) Control Charts
In their'70 paper titled "Mean and Variance Control Chart Limits Based on a Small Number of Subgroups" (Journal of Quality Technology, Volume 2, Number 1, pp. 9-16), Yang and Hillier originally derived equations for calculating the factors required to determine second stage short run control limits for ) v,X c( and )s ,X( c charts. Two issues have restricted the applicability of this particular control chart methodology. These are the limited tabulated values of factors Yang and Hillier present and no example to illustrate the use of the methodology. This paper addresses the first issue by presenting a computer program that accurately calculates the factors regardless of the values of the required inputs. An example shows how to incorporate the methodology into a two stage short run control charting procedure. The computer program is available at http://program.20m.com.
Multimedia Distribution Process Tracking for Android and iOS
The crime of illegally filming and distributing images or videos worldwide is
increasing day by day. With the increasing penetration rate of smartphones,
there has been a rise in crimes involving secretly taking pictures of people's
bodies and distributing them through messengers. However, little research has
been done on these related issue. The crime of distributing media using the
world's popular messengers, WhatsApp and Telegram, is continuously increasing.
It is also common to see criminals distributing illegal footage through various
messengers to avoid being caught in the investigation network. As these crimes
increase, there will continue to be a need for professional investigative
personnel, and the time required for criminal investigations will continue to
increase. In this paper, we propose a multimedia forensic method for tracking
footprints by checking the media information that changes when images and
videos shot with a smartphone are transmitted through instant messengers. We
have selected 11 of the world's most popular instant messengers and two secure
messengers. In addition, we selected the most widely used Android and iOS
operating systems for smartphones. Through this study, we were able to confirm
that it is possible to trace footprints related to the distribution of instant
messengers by analyzing transmitted images and videos. Thus, it was possible to
determine which messengers were used to distribute the video when it was
transmitted through multiple messengers.Comment: 10 page
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