3 research outputs found
Accumulation Kinetics and Equilibrium Partitioning Coefficients for Semivolatile Organic Pollutants in Forest Litter
Soils
are important stores of environmentally cycling semivolatile
organic contaminants (SVOCs) and represent relevant atmospheric secondary
sources whenever environmental conditions favor re-emission. The exchange
between air and soil is controlled by resistances posed by interfacial
matrices such as the ubiquitously distributed vegetation litter. For
the first time, this study focused on the experimental characterization
of accumulation parameters for SVOCs in litter under real field conditions.
The logarithm of the litter-air equilibrium partitioning coefficient
ranged 6.8–8.9 and had a similar dependence on log<i>K</i><sub>OA</sub> as that of plant foliage and soil data. Uptake and
release rates were also <i>K</i><sub>OA</sub> dependent
with values (relevant for real environmental conditions) ranging 30,000–150,000
d<sup>–1</sup> and 0.0004–0.0134 d<sup>–1</sup>, respectively. The overall mass transfer coefficient <i>v</i> controlling litter-air exchange (0.03–1.4 cm s<sup>–1</sup>) was consistent with previously reported data of <i>v</i> for foliage in forest canopies after normalization on leaf area
index. Obtained data suggest that litter holds the potential for influencing
atmospheric fugacity in proximity to soil, likely affecting overall
exchange of SVOCs between the soil reservoir and the atmosphere