87 research outputs found
Homogeneous photosensitization of complex TiO 2 nanostructures for efficient solar energy conversion
TiO 2 nanostructures-based photoelectrochemical (PEC) cells are under worldwide attentions as the method to generate clean energy. For these devices, narrow-bandgap semiconductor photosensitizers such as CdS and CdSe are commonly used to couple with TiO 2 in order to harvest the visible sunlight and to enhance the conversion efficiency. Conventional methods for depositing the photosensitizers on TiO 2 such as dip coating, electrochemical deposition and chemical-vapor-deposition suffer from poor control in thickness and uniformity, and correspond to low photocurrent levels. Here we demonstrate a new method based on atomic layer deposition and ion exchange reaction (ALDIER) to achieve a highly controllable and homogeneous coating of sensitizer particles on arbitrary TiO 2 substrates. PEC tests made to CdSe-sensitized TiO 2 inverse opal photoanodes result in a drastically improved photocurrent level, up to ∼15.7 mA/cm 2 at zero bias (vs Ag/AgCl), more than double that by conventional techniques such as successive ionic layer adsorption and reaction
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Hyperbranched TiO2-CdS nano-heterostructures for highly efficient photoelectrochemical photoanodes.
Quasi-1D-hyperbranched TiO2 nanostructures are grown via pulsed laser deposition and sensitized with thin layers of CdS to act as a highly efficient photoelectrochemical photoanode. The device properties are systematically investigated by optimizing the height of TiO2 scaffold structure and thickness of the CdS sensitizing layer, achieving photocurrent values up to 6.6 mA cm-2 and reaching saturation with applied biases as low as 0.35 VRHE. The high internal conversion efficiency of these devices is to be found in the efficient charge generation and injection of the thin CdS photoactive film and in the enhanced charge transport properties of the hyperbranched TiO2 scaffold. Hence, the proposed device represents a promising architecture for heterostructures capable of achieving high solar-to-hydrogen efficiency
Dopant-Free Donor (D)–p–D–p–D Conjugated Hole- Transport Materials for Efficient and Stable Perovskite Solar Cells
Three novel hole-transporting materials (HTMs) using the 4-methoxytriphenylamine (MeOTPA) core were designed and synthesized. The energy levels of the HTMs were tuned to match the perovskite energy levels by introducing symmetrical electron-donating groups linked with olefinic bonds as the bridge. The methylammonium lead triiodide (MAPbI(3)) perovskite solar cells based on the new HTM Z34 (see main text for structure) exhibited a remarkable overall power conversion efficiency (PCE) of 16.1% without any dopants or additives, which is comparable to 16.7% obtained by a p-doped 2,2,7,7-tetrakis-(N,N-di-4-methoxyphenylamino)-9,9-spirobifluorene (spiro-OMeTAD)-based device fabricated under the same conditions. Importantly, the devices based on the three new HTMs show relatively improved stability compared to devices based on spiro-OMeTAD when aged under ambient air containing 30% relative humidity in the dark
Enhancing Efficiency of Perovskite Solar Cells via N-doped Graphene: Crystal Modification and Surface Passivation
Controlling the morphology and surface passivation in perovskite solar cells is paramount in obtaining optimal opto-electronic properties. This study incorporates N-doped graphene nanosheets in the perovskite layer, which simultaneously induces an improved morphology and surface passivation at the perovskite/spiro interface, resulting in enhancement in all photovoltaic parameters
Over 20% PCE perovskite solar cells with superior stability achieved by novel and low-cost hole-transporting materials
The exploration of alternative low-cost molecular hole-transporting materials (HTMs) for both highly efficient and stable perovskite solar cells (PSCs) is a relatively new research area. Two novel HTMs using the thiophene core were designed and synthesized (Z25 and Z26). The perovskite solar cells based on Z26 exhibited a remarkable overall power conversion efficiency (PCE) of 20.1%, which is comparable to 20.6% obtained with spiroOMeTAD. Importantly, the devices based-on Z26 show better stability compared to devices based on Z25 and spiroOMeTAD when aged under ambient air of 30% or 85% relative humidity in the dark and under continuous full sun illumination at maximum power point tracking respectively. The presented results demonstrate a simple strategy by introducing double bonds to design hole-transporting materials for highly efficient and stable perovskite solar cells with low cost, which is important for commercial application
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