One-dimensional coordination polymers containing penta-supertetrahedral sulfide clusters linked by dipyridyl ligands

通讯作者地址: Feng, PY (通讯作者), Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA 地址: 1. Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA 2. Calif State Univ Long Beach, Dept Chem & Biochem, Long Beach, CA 90840 USA 电子邮件地址: [email protected] new one-dimensional coordination polymers [Zn8S(SC6H5)(14).C12H10N2](1), [Zn7CoS(SC6H5)14(.)C(13)H(14)N(2)](2) and [Zn8S(SC6H5)14(.)C(13)H(14)N(2)](3) have been prepared containing penta-supertetrahedral clusters and linear crosslinking dipyridyl ligands; the two complexes show optical transitions with band gaps of similar to 3.44 eV (1) and similar to 3.54 eV (2)