3 research outputs found
Additional file 1 of Cardiorespiratory fitness and metabolic risk in Chinese population: evidence from a prospective cohort study
Additional file 1: Supplementary Table 1. Associations between baseline CRF and relative change in CRF and relative changes in metabolic indicators
Hybrid of Co<sub>3</sub>Sn<sub>2</sub>@Co Nanoparticles and Nitrogen-Doped Graphene as a Lithium Ion Battery Anode
A facile strategy was designed for the fabrication of hybrid of Co<sub>3</sub>Sn<sub>2</sub>@Co nanoparticles (NPs) and nitrogen-doped graphene (NG) sheets through a hydrothermal synthesis, followed by annealing process. Core–shell architecture of Co<sub>3</sub>Sn<sub>2</sub>@Co pin on NG is designed for the dual encapsulation of Co<sub>3</sub>Sn<sub>2</sub> with adaptable ensembles of Co and NG to address the structural and interfacial stability concerns facing tin-based anodes. In the resulted unique architecture of Co<sub>3</sub>Sn<sub>2</sub>@Co–NG hybrid, the sealed cobalt cover prevents the direct exposer of Sn with electrolyte because of encapsulated structure and keeps the structural and interfacial integrity of Co<sub>3</sub>Sn<sub>2</sub>. However, the elastically strong, flexible and conductive NG overcoat accommodates the volume changes and therefore brings the structural and electrical stabilization of Co<sub>3</sub>Sn<sub>2</sub>@Co NPs. As a result, Co<sub>3</sub>Sn<sub>2</sub>@Co–NG hybrid exhibits extraordinary reversible capacity of 1615 mAh/g at 250 mA/g after 100 cycles with excellent capacity retention of 102%. The hybrid bears superior rate capability with reversible capacity of 793.9 mAh/g at 2500 mA/g and Coulombic efficiency nearly 100%
pH-Responsive Nanoparticle Superlattices with Tunable DNA Bonds
Stimuli-responsive
nanomaterials with reconfigurable structures
and properties have garnered significant interest in the fields of
optics, electronics, magnetics, and therapeutics. DNA is a powerful
and versatile building material that provides programmable structural
and dynamic properties, and indeed, sequence-dependent changes in
DNA have already been exploited in creating switchable DNA-based architectures.
However, rather than designing a new DNA input sequence for each intended
dynamic change, it would be useful to have one simple, generalized
stimulus design that could provide multiple different structural outputs.
In pursuit of this goal, we have designed, synthesized, and characterized
pH-dependent, switchable nanoparticle superlattices by utilizing i-motif
DNA structures as pH-sensitive DNA bonds. When the pH of the solution
containing such superlattices is changed, the superlattices reversibly
undergo: (i) a lattice expansion or contraction, a consequence of
the pH-induced change in DNA length, or (ii) a change in crystal symmetry,
a consequence of both pH-induced DNA “bond breaking”
and “bond forming” processes. The introduction of i-motifs
in DNA colloidal crystal engineering marks a significant step toward
being able to dynamically modulate crystalline architectures and propagate
local molecular motion into global structural change via exogenous
stimuli