Creep in Primary Consolidation with Rate of Loading Approach

The debate on creep in primary consolidation is analysed with a power law model following an approach in which creep is considered as rate of loading. According to this approach, primary consolidation is one type of rate of loading. To verify this approach, two types of tests, standard oedometer test and oedometer test with drainage prevented, are conducted on three types of soils (two from NGES and the other from Port of Guangzhou). The result: creep exponents obtained from two kinds of tests agree well with each other. Moreover, the approach is further validated by tracking, for over 80 years, the data from settlement of the case history San Jacinto Monument, which is inconsistent with data calculated from the classical method. In the end, procedure of this approach, with which long term settlement is predicted, is illustrated, and this approach is compared with the classical method

Difference of gut microbiota between patients with negative and positive HBeAg in chronic hepatitis B and the effect of tenofovir alafenamide on intestinal flora

BackgroundSevere liver diseases, such as liver fibrosis, cirrhosis, and liver cancer, are mainly caused by hepatitis B virus (HBV). This study investigated the differences between gut microbiota in HBeAg-positive and negative groups of patients with chronic hepatitis B (CHB) and investigated the effect of tenofovir alafenamide (TAF) on gut microbiota.MethodsThis prospective study included patients with CHB not taking nucleoside antivirals (No-NAs group, n = 95) and those taking TAF (TAF group, n = 60). We divided CHB patients into two groups according to the HBeAg status of the subjects on the day of data collection. Phase 1 are HBeAg-negative patients and phase 2 are HBeAg-positive patients. We investigated the improvement of clinical symptoms by TAF, as well as differences in gut microbiota between different groups by 16S rRNA high-throughput sequencing.ResultsGut microbiota demonstrated significant differences between patients with HBeAg-positive and -negative CHB. Both the No-NAs and TAF Phase 2 subgroups demonstrated significantly increased microbiota richness and diversity, showing greater heterogeneity. Additionally, the Phase 2 subgroup exhibited a low abundance of pathways associated with glucose metabolism and amino acid metabolism. The TAF group demonstrated a significantly decreased HBV load, alanine aminotransferase, and aspartate aminotransferase and a significant increase in prealbumin compared with the No-NAs group. No significant difference was found in uric acid, creatinine, blood calcium, inorganic phosphorus, eGFR, and β2-microglobulin concentrations between the two groups. Additionally, the urea level in the TAF group was significantly lower than that in the No-NAs group, but with no significant effect on other indicators such as eGFR and β2-microglobulin.ConclusionThis study revealed significant differences in gut microbiota composition and function between patients with HBeAg-positive and -negative CHB

Remarkable nucleation and growth of ultrafine particles from vehicular exhaust

High levels of ultrafine particles (UFPs; diameter of less than 50 nm) are frequently produced from new particle formation under urban conditions, with profound implications on human health, weather, and climate. However, the fundamental mechanisms of new particle formation remain elusive, and few experimental studies have realistically replicated the relevant atmospheric conditions. Previous experimental studies simulated oxidation of one compound or a mixture of a few compounds, and extrapolation of the laboratory results to chemically complex air was uncertain. Here, we show striking formation of UFPs in urban air from combining ambient and chamber measurements. By capturing the ambient conditions (i.e., temperature, relative humidity, sunlight, and the types and abundances of chemical species), we elucidate the roles of existing particles, photochemistry, and synergy of multipollutants in new particle formation. Aerosol nucleation in urban air is limited by existing particles but negligibly by nitrogen oxides. Photooxidation of vehicular exhaust yields abundant precursors, and organics, rather than sulfuric acid or base species, dominate formation of UFPs under urban conditions. Recognition of this source of UFPs is essential to assessing their impacts and developing mitigation policies. Our results imply that reduction of primary particles or removal of existing particles without simultaneously limiting organics from automobile emissions is ineffective and can even exacerbate this problem

Remarkable nucleation and growth of ultrafine particles from vehicular exhaust

High levels of ultrafine particles (UFPs; diameter of less than 50 nm) are frequently produced from new particle formation under urban conditions, with profound implications on human health, weather, and climate. However, the fundamental mechanisms of new particle formation remain elusive, and few experimental studies have realistically replicated the relevant atmospheric conditions. Previous experimental studies simulated oxidation of one compound or a mixture of a few compounds, and extrapolation of the laboratory results to chemically complex air was uncertain. Here, we show striking formation of UFPs in urban air from combining ambient and chamber measurements. By capturing the ambient conditions (i.e., temperature, relative humidity, sunlight, and the types and abundances of chemical species), we elucidate the roles of existing particles, photochemistry, and synergy of multipollutants in new particle formation. Aerosol nucleation in urban air is limited by existing particles but negligibly by nitrogen oxides. Photooxidation of vehicular exhaust yields abundant precursors, and organics, rather than sulfuric acid or base species, dominate formation of UFPs under urban conditions. Recognition of this source of UFPs is essential to assessing their impacts and developing mitigation policies. Our results imply that reduction of primary particles or removal of existing particles without simultaneously limiting organics from automobile emissions is ineffective and can even exacerbate this problem

Modélisation et simulation numérique d'un procédé de fabrication des mousses d'aluminium et des matériaux MPPC

Cette étude est consacrée à la modélisation et à la simulation d un procédée d élaboration de la mousse d aluminium et du métal poreux polymère composite (MPPC). La méthode numérique proposée consiste à utiliser un système des modèles numériques appliqués dans la hydromécanique et le transfert thermique de l écoulement de l aluminium fondu. L objet de ce travail est de contrôler les paramètres d élaboration, ainsi de prévoir le défaut dans les mousses métalliques. Après avoir étudié la bibliographie dans ce domaine, le deuxième chapitre de la thèse présente le procédé expérimental d élaboration des mousses d aluminium et de MPPC. Le troisième chapitre concerne la modélisation numérique en 2D macroscopique par un régime dynamique en appliquant un système des modèles numériques. Avec les équations des conservations, l écoulement d infiltration d aluminium fondu est modélisé par un modèle des milieux poreux ; le modèle multiphasique est utilisé pour suivre le mouvement de l interface entre l aluminium liquide et l air. De plus, le modèle de rayonnement thermique et de convection naturelle sont établis pour déterminer la température ; le modèle de solidification permet de prédire la durée de refroidissement. Ensuit dans le quatrième chapitre, l écoulement et la solidification microscopique sont modélisés en utilisant le modèle sphérique en régime dynamique. Enfin, dans la dernière partie, le modèle de tetrakaidecahedron est utilisé en 3D afin d observer le trajet et la vitesse de l écoulement d aluminium liquideThis study is dedicated to the modeling and numerical simulation of a manufacture process of aluminum foam and porous metal polymer composite (MPPC). The proposed numerical method consists in using a system of the numeric models which apply in the hydromechanics and the thermal transfer of the flow of the molten aluminum. The object of this work is control of the parameters of manufacture, as well as to predict the defect in the material. After having studied the bibliography in this field, the second chapter of this thesis presents the experimental process of manufacture of the aluminum foam and MPPC with the method of infiltration at negative pressure. The third chapter concerns the 2D macroscopic modeling in dynamic manner. It applies a system of the numeric models. In order to modeling the infiltrative flow of molten aluminum, the conservation equations (of mass, of momentum and of energy) is applied by the model of the porous media; the multiphase model is used to follow the movement of the interface between the liquid aluminum and the air. Furthermore, the model of thermal radiation and the model of natural convection are built to determine the temperature; the model of solidification allows predicting the duration of cooling. Followed in the fourth chapter, the microscopic flow and solidification of molten aluminum are dynamically modeled by using the spherical model. Finally, in the last part, the 3D model of tetrakaidecahedron is used to observe the path and the speed of the flow of liquid aluminumTROYES-SCD-UTT (103872102) / SudocSudocFranceF

pH-Mediated Antibacterial Dyeing of Cotton with Prodigiosins Nanomicelles Produced by Microbial Fermentation

This study developed a novel pH-mediated antimicrobial dyeing process of cotton with prodigiosins nanomicelles produced by microbial fermentation. The average diameter of the pigment nanomicelles was 223.8 nm (range of 92.4–510.2 nm), and the pigment concentration was 76.46 mg/L. It was found that the superior dyeing effect of cotton fabric was achieved by adjusting the dye bath pH. When the pH was three, dyed cotton under 90 °C for 60 min exhibited the greatest color strength with good rubbing, washing and perspiration color fastness. By the breaking strength test and XRD analysis, it was concluded that the cotton dyed under the optimum condition almost suffered no damage. In addition, due to the presence of prodigiosins, dyed cotton fabric under the optimal process showed outstanding bacteriostatic rates of 99.2% and 85.5% against Staphylococcus aureus and Escherichia coli, respectively. This research provided an eco-friendly and widely-applicable approach for antimicrobial intracellular pigments with the property of pH-sensitive solubility in water to endow cellulose fabric with color and antibacterial activity

Preparation of Biocolorant and Eco-Dyeing Derived from Polyphenols Based on Laccase-Catalyzed Oxidative Polymerization

Natural products have been believed to be a promising source to obtain ecological dyes and pigments. Plant polyphenol is a kind of significant natural compound, and tea provides a rich source of polyphenols. In this study, biocolorant derived from phenolic compounds was generated based on laccase-catalyzed oxidative polymerization, and eco-dyeing of silk and wool fabrics with pigments derived from tea was investigated under the influence of pH variation. This work demonstrated that the dyeing property was better under acidic conditions compared to alkalinity, and fixation rate was the best when pH value was 3. Furthermore, breaking strength of dyed fabrics sharply reduced under the condition of pH 11. Eventually, the dyeing method was an eco-friendly process, which was based on bioconversion, and no mordant was added during the process of dyeing

Biodegradation of Microplastic Derived from Poly(ethylene terephthalate) with Bacterial Whole-Cell Biocatalysts

At present, the pollution of microplastic directly threatens ecology, food safety and even human health. Polyethylene terephthalate (PET) is one of the most common of microplastics. In this study, the micro-size PET particles were employed as analog of microplastic. The engineered strain, which can growth with PET as sole carbon source, was used as biocatalyst for biodegradation of PET particles. A combinatorial processing based on whole-cell biocatalysts was constructed for biodegradation of PET. Compared with enzymes, the products can be used by strain growth and do not accumulated in culture solution. Thus, feedback inhibition of products can be avoided. When PET was treated with the alkaline strain under high pH conditions, the product concentration was higher and the size of PET particles decreased dramatically than that of the biocatalyst under neutral conditions. This shows that the method of combined processing of alkali and organisms is more efficient for biodegradation of PET. The novel approach of combinatorial processing of PET based on whole-cell biocatalysis provides an attractive avenue for the biodegradation of micplastics

Control of micro-wettability of pore-throat on shale oil occurrence: A case study of laminated shale of Permian Lucaogou Formation in Jimusar Sag, Junggar Basin, NW China

The control of micro-wettability of pore-throat on shale oil occurrence in different types of reservoir spaces remains unclear. Take the shale oil reservoir of the Permian Lucaogou Formation in the Jimusar Sag, Junggar Basin as an example, the reservoir space in laminated shale and the control of micro-wettability of pore-throat on shale oil occurrence were studied by using scanning electron microscope (SEM), multi-stage pyrolysis, quantitative fluorescence, nuclear magnetic resonance (NMR) and other techniques. The results show that there are mainly two types of laminated shale in the Lucaogou Formation, namely laminated shale rich in volcanic materials + terrigenous felsic, and laminated shale rich in volcanic materials + carbonate. The former type contains feldspar dissolution pores and intergranular pores, mainly with felsic mineral components around the pore-throats, which are water-wet and control the free shale oil. The latter type contains carbonate intercrystalline pores and organic pores, mainly with oil-wet mineral components around the pore-throats, which control the adsorbed shale oil. The oil-wet mineral components around the pore-throats are conducive to oil accumulation, but reduce the proportion of free oil. In the Lucaogou Formation, free oil, with high maturity and light quality, mainly occurs in the laminated shale rich in volcanic materials + terrigenous felsic