Bioaccessibility and reliable human health risk assessment of heavy metals in typical abandoned industrial sites of southeastern China

Heavy metal pollution caused by a large number of abandoned industrial sites cannot be underestimated, but its human health risks have not been accurately assessed. This study investigated the pollution of heavy metals in soils of the typical abandoned industrial sites in southeastern China. Based on the bioaccessibility of different heavy metals (Pb, Ni, Cu, Zn, Cd, Cr) in the industrial soils, the human health risks were accurately evaluated, and the controlling factors were quantitatively assessed. The results showed that the heavy metals in each typical abandoned industrial sites had a high degree of spatial heterogeneity. Among them, Cd was the most susceptible to relevant discrete input from external factors such as human activities, followed by Zn, Pb, Cr, Ni and Cu. The bioaccessible concentration of heavy metals by the physiological-based extraction test (PBET) had a good correlation (R2 = 0.58 ∼ 0.86) with its bioavailable concentration by diethylenetriaminepentaacetic acid (DTPA) extraction. The regression model based on soil parameters had great potential to predict the bioaccessibility of heavy metals in abandoned industrial sites (R2 = 0.49 ∼ 0.95). The total concentration of heavy metals, Fe, soil texture and pH were the controlling factors of the metal bioaccessibility. Compared with the total concentration, the hazard index (HI) and carcinogenic risk (CR) values calculated based on gastrointestinal bioaccessibility were decreased by 39.0∼77.9% and 68.2∼79.9% in adults, and 45.3∼88.0% and 73.9∼83.5% in children, respectively. This work provides a feasible theoretical basis for reliable assessment of the human health risks of heavy metals in the abandoned industrial sites in the future

In Vitro Bioaccessibility and Health Risk Assessment of Arsenic and Zinc Contaminated Soil Stabilized by Ferrous Sulfate: Effect of Different Dietary Components

Iron-based materials have good stability in reducing the mobility and toxicity of heavy metals, but the behavior and human health risks of heavy metals could be affected by dietary components. This study investigated the effect of typical diets (lettuce, cooked rice and apples) on the bioaccessibility and morphological changes of arsenic (As) and zinc (Zn) in contaminated site after stabilization by ferrous sulfate (FeSO4). The results showed that the bioaccessibility of As and Zn were increased in a co-digestion system of food. The augmented effect on As bioaccessibility mainly occurred in the gastric phase: apple > lettuce > cooked rice (p apple > cooked rice (p 4 weakened the dissolution effect of dietary components on As bioaccessibility, and reduced As bioaccessibility in the gastric and intestinal phases by 34.0% and 37.9% (p 4 reduced the hazard quotient (HQ) and carcinogenic risk (CR) values of the contaminated soil by 33.97% and 33.59%, respectively. This study provides a reference for a better understanding of more realistic strategies to modulate exposure risks of heavy metal-contaminated sites

Sources, Indicators, and Assessment of Soil Contamination by Potentially Toxic Metals

Soil pollution caused by potentially toxic metals has become a worldwide environmental issue. Geogenic processes and anthropogenic activities are two important sources of soil pollution. Soils may inherit toxic metals from parent materials; however, soil pollution mostly results from industrial and agricultural activities. Contamination by metals can be indicated by the changes in chemical, biochemical, and microbial properties of soils and plant responses. The total concentration of toxic metals in soil is still the most widely used indicator for risk assessment although extractable amounts have been reported to be more closely related to plant uptake. Several models have been proposed for assessing soil contamination by toxic metals, but none of them are commonly accepted for application to a wide range of soils. This review paper highlights how toxic metal contamination negatively affects soil and environmental quality, impacts food quality and security, and poses a threat to human health. Further research is needed to not only improve soil contamination diagnosis, modeling, and regulatory standards but also for remediation efficiency

Sources, Indicators, and Assessment of Soil Contamination by Potentially Toxic Metals

Soil pollution caused by potentially toxic metals has become a worldwide environmental issue. Geogenic processes and anthropogenic activities are two important sources of soil pollution. Soils may inherit toxic metals from parent materials; however, soil pollution mostly results from industrial and agricultural activities. Contamination by metals can be indicated by the changes in chemical, biochemical, and microbial properties of soils and plant responses. The total concentration of toxic metals in soil is still the most widely used indicator for risk assessment although extractable amounts have been reported to be more closely related to plant uptake. Several models have been proposed for assessing soil contamination by toxic metals, but none of them are commonly accepted for application to a wide range of soils. This review paper highlights how toxic metal contamination negatively affects soil and environmental quality, impacts food quality and security, and poses a threat to human health. Further research is needed to not only improve soil contamination diagnosis, modeling, and regulatory standards but also for remediation efficiency

Production of 5-Hydroxymethylfurfural from Chitin Biomass: A Review

Chitin biomass, a rich renewable resource, is the second most abundant natural polysaccharide after cellulose. Conversion of chitin biomass to high value-added chemicals can play a significant role in alleviating the global energy crisis and environmental pollution. In this review, the recent achievements in converting chitin biomass to high-value chemicals, such as 5-hydroxymethylfurfural (HMF), under different conditions using chitin, chitosan, glucosamine, and N-acetylglucosamine as raw materials are summarized. Related research on pretreatment technology of chitin biomass is also discussed. New approaches for transformation of chitin biomass to HMF are also proposed. This review promotes the development of industrial technologies for degradation of chitin biomass and preparation of HMF. It also provides insight into a sustainable future in terms of renewable resources