Determining the continuous thermo-optic coefficients of chalcogenide glass thin films in the MIR region using FTIR transmission spectra

A new method (FTIR continuous dn / dT method, n is refractive index and T temperature) for measuring the continuous thermo-optic coefficients of thin transparent films in the mid-infrared (MIR) spectral region is introduced. The technique is based on Fourier transform infrared (FTIR) transmission spectra measured at different temperatures. It is shown that this method can successfully determine the thermo-optic coefficient of chalcogenide glass thin films (of batch compositions Ge20Sb10Se70 at. % (atomic %) and Ge16As24Se15.5Te44.5 at. %) over the wavelength range from 2 to 25 µm. The measurement precision error is less than ±11.5 ppm / ºC over the wavelength range from 6 to 20 µm. The precision is much better than that provided by the prism minimum deviation method or an improved Swanepoel method

Experimental observation of gain in a resonantly pumped Pr3+-doped chalcogenide glass mid-infrared fibre amplifier notwithstanding the signal excited-state absorption

We demonstrate a maximum gain of 4.6 dB at a signal wavelength of 5.28 μm in a 4.1 μm resonantly pumped Pr3+- doped selenide-based chalcogenide glass fibre amplifier of length 109 mm, as well as a new signal excited-stated absorption (ESA) at signal wavelengths around 5.5 μm. This work is to the best of our knowledge is the first experimental demonstration of gain at mid-infrared (MIR) wavelengths in a Pr3+-doped chalcogenide fibre amplifier. The signal ESA of Pr3+ ions is attributed to the transition 3H6→(3F4, 3F3) after the pump ESA (3H5→3H6) at a pump wavelength of 4.1 μm, which absorbs the MIR signal at wavelengths of 5.37, 5.51 and 5.57 μm, and so spoils the amplifier’s performance at these wavelengths. Thus, this signal ESA should be suppressed in a resonantly pumped Pr3+-doped chalcogenide fibre amplifier