The coordination chemistry of saturated molecules

Our understanding of bonding in transition metal complexes, as well as our ability to use that understanding in the synthesis and application of new species, has evolved over the last 100 years; and in some sense this special feature on the coordination chemistry of saturated molecules may be considered to represent its culmination. The nature of complexes between transition metal ions and neutral molecules such as ammonia was first correctly described by Werner around the beginning of the 20th century. Interpretations in terms of electronic bonding theories followed soon after. The key feature, of course, is the availability of a low-energy filled "lone pair" orbital available for donation to a vacant orbital on the electron-accepting metal ion

A MULTIATTRIBUTE UTILITY ANALYSIS OF TECHNOLOGICAL CHOICE IN THE CALIFORNIA WILD RICE INDUSTRY

Technological choice and competitive strategy issues are reviewed and then a framework for choosing between two competing technologies is proposed.The two competing technologies differ in their ability to store and process wild rice over a marketing year. The traditional technologies requires almost immediate processing of the harvested wild rice while the experimental technology allows harvested wild rice to be stored and processed over the course of the marketing year. Technological choice is explored using multiattribute utility analysis and two economic evaluations. The economic evaluations are payback period analysis and internal rate of return analysis given uncertain demand conditions. The experimental technology is shown to be the dominant technological choice under both multiattribute utility analysis and the economic analyses.Research and Development/Tech Change/Emerging Technologies,

SOCIAL, ECONOMIC, AND INSTITUTIONAL INCENTIVES TO DRAIN OR PRESERVE PRAIRIE WETLANDS

Land Economics/Use,

A Versatile Ligand Platform that Supports Lewis Acid Promoted Migratory Insertion

A helping hand: Incorporation of Group 2 Lewis acids into a macrocycle appended to a phosphine ligand attached to a rhenium carbonyl complex promotes otherwise unfavorable transformations of coordinated CO (see scheme; M=Ca, Sr). These Lewis acids form relatively weak M-O bonds, thereby enabling release of organic products from the metal center

State-Space Interpretation of Model Predictive Control

A model predictive control technique based on a step response model is developed using state estimation techniques. The standard step response model is extended so that integrating systems can be treated within the same framework. Based on the modified step response model, it is shown how the state estimation techniques from stochastic optimal control can be used to construct the optimal prediction vector without introducing significant additional numerical complexity. In the case of integrated or double integrated white noise disturbances filtered through general first-order dynamics and white measurement noise, the optimal filter gain is parametrized explicitly in terms of a single parameter between 0 and 1, thus removing the requirement for solving a Riccati equation and equipping the control system with useful on-line tuning parameters. Parallels are drawn to the existing MPC techniques such as Dynamic Matrix Control (DMC), Internal Model Control (IMC) and Generalized Predictive Control (GPC)

Oxidative aromatization of olefins with dioxygen catalyzed by palladium trifluoroacetate

Molecular oxygen can replace sacrificial olefins as the hydrogen acceptor in the palladium trifluoroacetate catalyzed dehydrogenation of cyclohexene and related cyclic olefins into aromatics. One of the major drawbacks of the homogeneous system is the tendency of the palladium trifluoroacetate to precipitate as palladium(0) at elevated temperatures. The use of better ligands affords catalysts that can operate at higher temperatures, although they are less reactive than palladium trifluoroacetate

JT9D jet engine performance deterioration

The analytical techniques utilized to examine the effects of flight loads and engine operating conditions on performance deterioration are presented. The role of gyroscopic, gravitational, and aerodynamic loads are shown along with the effect of variations in engine build clearances. These analytical results are compared to engine test data along with the correlation between analytically predicted and measured clearances and rub patterns. Conclusions are drawn and important issues are discussed

An Estimation of the Regulatory Cost on California Agricultural Producers

This paper develops an estimation of the cost of regulations on California agricultural producers which can be used as a baseline for comparing regulatory environments. The estimated regulatory cost in relationship to operating costs for producers is between $2.19 billion to$2.21 billion. The range on percentage of income allocated to regulatory cost is between 5.24% and 9.19%.Environmental Economics and Policy,

Intra- and Intermolecular C−H Activation by Bis(phenolate)pyridineiridium(III) Complexes

A bis(phenolate)pyridine pincer ligand (henceforth abbreviated as ONO) has been employed to support a variety of iridium complexes in oxidation states I, III, and IV. Complexes (ONO)IrL_2Me (L = PPh_3, PEt_3) react with I_2 to cleave the Ir–C bond and liberate MeI, apparently via a mechanism beginning with electron transfer to generate an intermediate Ir(IV) complex, which can be isolated and characterized for the case L = PEt_3. The PPh_3 complex is transformed in benzene at 65 °C to the corresponding phenyl complex, with loss of methane, and subsequently to a species resulting from metalation of a PPh_3 ligand. Labeling and kinetics studies indicate that PPh_3 is the initial site of C–H activation, even though the first observed product is that resulting from intermolecular benzene activation. C–H activation of acetonitrile has also been observed