Green\u27s Law Revisited: Tidal Long-Wave Propagation in Channels with Strong Topography

Green\u27s Law states that tidal long-wave elevation ζ and tidal transport Q vary with width b and depth h according to ζ ≌ b−1/2h−1/4 and Q ≌ b+1/2h+/4. This solution is of limited utility because it is restricted to inviscid, infinitesimal waves in channels with no mean flow and weak topography (those with topographic scale L ≫ wavelength λ). An analytical perturbation model including finite-amplitude effects, river flow, and tidal flats has been used to show that (1) wave behavior to lowest order is a function of only two nondimensional parameters representing, respectively, the strength of friction at the bed and the rate of topographic convergence/divergence; (2) two different wave equations with nearly constant coefficients can be derived that together cover most physically relevant values of these parameters, even very strong topography; (3) a single, incident wave in a strongly convergent or divergent geometry may mimic a standing wave by having a ≡ 90° phase difference between Q and ζ and a very large phase speed, without the presence of a reflected wave; (4) channels with strong friction and/or strong topography (L ≪ λ) show very large deviations from Green/s Law; and (5) these deviations arise because both frictional damping and the direct dependence of |Q| and |ζ| on topography (topographic funnelling) must be considered

Is a Higher Calling Enough? Incentive Compensation in the Church (CRI 2009-011)

We study the compensation and productivity of more than 2,000 Methodist ministers in a 43-year panel data set. The church appears to use pay-for-performance incentives for its clergy, as their compensation follows a sharing rule by which pastors receive approximately 3% of the incremental revenue from membership increases. Ministers receive the strongest rewards for attracting new parishioners who switch from other congregations within their denomination. Monetary incentives are weaker in settings where ministers have less control over their measured performance

Circulatory Processes in the Columbia River Estuary

Covers tidal circulation, density distribution, vertical mixing, salt transport, and low-frequency flow processes, with contributions to estuarine circulation theory

Transition probabilities in OH A 2 sigma + - X 2 pi i: Bands with v prime = 0 and 1, v double prime = 0 to 4

Experimental results for relative vibrational band transition probabilities for v prime = 0 and 1, and v double prime = 0 to 4 in the A-X electronic system of OH are presented. The measurements, part of a larger set involving v prime = 0 to 4 and v double prime = 0 to 6, were made using spectrally dispersed laser-induced fluorescence (LIF) in the burnt gases of a flame. These Einstein coefficients will be useful in dynamics experiments for quantitative LIF determinations of OH radical concentrations in high v double prime

Iridium(I) and Iridium(III) Complexes Supported by a Diphenolate Imidazolyl-Carbene Ligand

Deprotonation of 1,3-di(2-hydroxy-5-tert-butylphenyl)imidazolium chloride (1a) followed by reaction with chloro-1,5-cyclooctadiene Ir(I) dimer affords the anionic Ir(I) complex [K][{OCO}Ir(cod)] (2: OCO = 1,3-di(2-hydroxy-5-tert-butylphenyl)imidazolyl; cod = 1,5-cyclooctadiene), the first Ir complex stabilized by a diphenolate imidazolyl-carbene ligand. In the solid state 2 exhibits square-planar geometry, with only one of the phenoxides bound to the metal center. Oxidation of 2 with 2 equiv of [FeCp_2][PF_6] generates the Ir(III) complex [{OCO}Ir(cod)(MeCN)][PF_6] (3). Reaction of 3 with H_2 results in the liberation of cyclooctane and a species capable of catalyzing the hydrogenation of cyclohexene to cyclohexane. Displacement of cyclooctadiene from 3 can be achieved by heating in acetonitrile to form [{OCO}Ir(MeCN)3][PF_6] (4) or by reaction with either PMe_3 or PCy_3 to generate [{OCO}Ir(PMe_3)_3][PF_6] (5) or [{OCO}Ir(PCy_3)_2(MeCN)][PF_6] (6), respectively. 6 reacts with CO in acetonitrile to give an equilibrium mixture of 6 and [{OCO}Ir(PCy_3)_2(CO)][PF_6] (7) and with chloride to generate [{OCO}Ir(PCy_3)_(2)Cl] (8). The solid-state structure of 8 shows that the diphenolate imidazolyl-carbene ligand is distorted from planarity; DFT calculations suggest this is due to an antibonding interaction between the phenolates and the metal center in the highest occupied molecular orbital (HOMO) of the complex. 8 undergoes two successive reversible one-electron oxidations in CH_(2)Cl_2 at −0.22 and at 0.58 V (vs ferrocene/ferrocenium); EPR spectra, mass spectroscopy, and DFT calculations suggest that the product of the first oxidation is [{OCO}Ir(PCy_3)_(2)Cl]+ (8+), with the unpaired electron occupying a molecular orbital that is delocalized over both the metal center and the diphenolate imidazolyl-carbene ligand

Livestock Market Integration and Price Discovery: Case of Mali

Replaced with revised version of paper 02/22/11.cointegration, structural breaks, market integration, Agricultural and Food Policy, Demand and Price Analysis, International Development, Livestock Production/Industries,

Estimation of Columbia River Virgin Flow: 1879 to 1928

The Columbia River has historically been a major source of economic activity for the Pacific Northwest, and is one of the more heavily modified rivers in the United States today. Understanding human and climate-induced changes in its hydrologic properties is, therefore, a topic of considerable interest. Long streamflow records are essential to determining how runoff has changed over time. Daily streamflow records of the Columbia River at The Dalles dates back to June 1978. However, the observed daily flow does not alone provide enough information to understand or separate anthropogenic and climate effects. It is necessary also to have an estimate of virgin flow of the river to provide a historical perspective of water resources development, separate anthropogenic and climate effects, and compare present water use scenarios with those of the past decades. The United State Geological Survey (USGS) has calculated a monthly averaged adjusted river flow at The Dalles for 1879-1999 that accounts for the effects of flow regulation. The Bonneville Power Administration (BPA) has estimated the monthly averaged virgin (or naturalized) flow at The Dalles, i.e., the flow in the absence of both flow regulation and irrigation depletion for 1929-89. We have estimated the monthly virgin flow of the Columbia River at The Dalles from records of irrigated area for the missing years, i.e., for the period 1879-1928. In addition, a filtered version of the daily observed flows were combined with monthly virgin flow corrections to obtain estimates of daily virgin flows with realistic higher moments and spectral properties. Examination of the virgin flow record shows that climate change since late 19th century has caused a decrease of \u3e7% in its annual average flow volume. The decrease in flow due to irrigation diversion during the same period is also ~7%. Broadly speaking, there are three periods of Columbia River flow management. Before 1900, mainstem dams were absent and flow diversions relatively small. Numerous dams were constructed between 1900 and 1970, and irrigation depletion increased 500%. Since about 1970, river flows have been managed on a system-wide basin, effecting significant interannual transfers of flows for the first time