1,236 research outputs found
Novel structural features of the ripple phase of phospholipids
We have calculated the electron density maps of the ripple phase of
dimyristoylphosphatidylcholine (DMPC) and palmitoyl-oleoyl phosphatidylcholine
(POPC) multibilayers at different temperatures and fixed relative humidity. Our
analysis establishes, for the first time, the existence of an average tilt of
the hydrocarbon chains of the lipid molecules along the direction of the ripple
wave vector, which we believe is responsible for the occurrence of asymmetric
ripples in these systems
Emerging trends for urban freight transport-The potential for sustainable micromobility
Aim
Active transportation referring to non-motorized modes of transport is promoted and popularized both in practice and in the scientific literature, while their use for urban freight transport has been largely neglected. Thus the main scope of the paper is to indicate the development potential of micromobility use in urban freight transport and to check its influence on urban sustainability.
Methods
The authors have hypothesized that active means of transport, with a focus on micromobility, have great development potential in freight transportation in cities. The implemented methods for analyzing the relationship between users’ characteristics, micromobility, and its impact on urban sustainable development, were logit and probit modelling. The authors’ system includes an analysis of factors connected with the topics of sustainability and micromobilty, that have met an essential scientific gap that this paper addresses.
Logistic (logit) regression is used mainly for binary, ordinal, and multi-level outcomes to find the probability of success (i.e. occurrence of some event). Probit regression, however, is primarily used in binary response models and assumes the normal distribution of data.
Results
The main finding of the article has led the authors to the statement that active means of transport, including micromobility have great development potential in freight transportation in cities.
Conclusions
Knowledge of the acceptance of micromobility solutions is essential for municipal authorities in shaping the development of urban transport systems. Thus proper strategies and actions need to be prioritized to leverage the sustainability-related co-benefits of active transport
Evidence of environmental strains on charge injection in silole based organic light emitting diodes
Using d. functional theory (DFT) computations, the authors demonstrated a
substantial skeletal relaxation when the structure of
2,5-bis-[4-anthracene-9-yl-phenyl]-1,1-dimethyl-3,4-diphenyl-silole (BAS) is
optimized in the gas-phase comparing with the mol. structure detd. from
monocrystal x-ray diffraction. The origin of such a relaxation is explained by
a strong environmental strains induced by the presence of anthracene entities.
Also, the estn. of the frontier orbital levels showed that this structural
relaxation affects mainly the LUMO that is lowered of 190 meV in the gas phase.
To check if these theor. findings would be confirmed for thin films of BAS, the
authors turned to UV photoemission spectroscopy and/or inverse photoemission
spectroscopy and electrooptical measurements. The study of the c.d. or voltage
and luminance or voltage characteristics of an ITO/PEDOT/BAS/Au device clearly
demonstrated a very unusual temp.-dependent behavior. Using a thermally
assisted tunnel transfer model, this behavior likely originated from the
variation of the electronic affinity of the silole deriv. with the temp. The
thermal agitation relaxes the mol. strains in thin films as it is shown when
passing from the cryst. to the gas phase. The relaxation of the intramol. thus
induces an increase of the electronic affinity and, as a consequence, the more
efficient electron injection in org. light-emitting diodes
Thermodynamic study of benzocaine insertion into different lipid bilayers
Despite the general consensus concerning the role played by sodium channels in the molecular mechanism of local anesthetics, the potency of anaesthetic drugs also seems to be related with their solubility in lipid bilayers. In this respect, this work represents a thermodynamic study of benzocaine insertion into lipid bilayers of different compositions by means of molecular dynamics simulation. Thus, the free energy profiles associated with benzocaine insertion into symmetric lipid bilayers composed of different proportions of dipalmitoylphosphatidylcholine and dipalmitoylphosphatidylserine were studied. From the simulation results, a maximum in the free energy (ΔG) profile was measured in the region of the lipid/solution interface. This free energy barrier appears to be very much dependent on the lipid composition of the membrane. On the other hand, the minimum free energy (ΔG) within the bilayer remained almost independent of the lipid composition of the bilayer. By repeating the study at different temperatures, it was seen how the spontaneity of benzocaine insertion into the lipid bilayer is due to an increase in the entropy associated with the process.Fil: López Cascales, José Javier. Universidad Politecnica de Cartagena; EspañaFil: Oliveira Costa, Sara D.. Universidad Politecnica de Cartagena; EspañaFil: Porasso, Rodolfo Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Matemática Aplicada de San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Ciencias Físico Matemáticas y Naturales. Departamento de Física; Argentin
M\"ossbauer, nuclear inelastic scattering and density functional studies on the second metastable state of Na2[Fe(CN)5NO]2H2O
The structure of the light-induced metastable state SII of
Na2[Fe(CN)5NO]2H2O 14 was investigated by transmission M\"ossbauer
spectroscopy (TMS) in the temperature range 15 between 85 and 135 K, nuclear
inelastic scattering (NIS) at 98 K using synchrotron 16 radiation and density
functional theory (DFT) calculations. The DFT and TMS results 17 strongly
support the view that the NO group in SII takes a side-on molecular orientation
18 and, further, is dynamically displaced from one eclipsed, via a staggered,
to a second 19 eclipsed orientation. The population conditions for generating
SII are optimal for 20 measurements by TMS, yet they are modest for
accumulating NIS spectra. Optimization 21 of population conditions for NIS
measurements is discussed and new NIS experiments on 22 SII are proposed
Control Software for the SST-1M Small-Size Telescope prototype for the Cherenkov Telescope Array
The SST-1M is a 4-m Davies--Cotton atmospheric Cherenkov telescope optimized
to provide gamma-ray sensitivity above a few TeV. The SST-1M is proposed as
part of the Small-Size Telescope array for the Cherenkov Telescope Array (CTA),
the first prototype has already been deployed. The SST-1M control software of
all subsystems (active mirror control, drive system, safety system,
photo-detection plane, DigiCam, CCD cameras) and the whole telescope itself
(master controller) uses the standard software design proposed for all CTA
telescopes based on the ALMA Common Software (ACS) developed to control the
Atacama Large Millimeter Array (ALMA). Each subsystem is represented by a
separate ACS component, which handles the communication to and the operation of
the subsystem. Interfacing with the actual hardware is performed via the OPC UA
communication protocol, supported either natively by dedicated industrial
standard servers (PLCs) or separate service applications developed to wrap
lower level protocols (e.g. CAN bus, camera slow control) into OPC UA. Early
operations of the telescope without the camera were already carried out. The
camera is fully assembled and is capable to perform data acquisition using
artificial light source.Comment: In Proceedings of the 35th International Cosmic Ray Conference
(ICRC2017), Busan, Korea. All CTA contributions at arXiv:1709.0348
Software design for the control system for Small-Size Telescopes with single-mirror of the Cherenkov Telescope Array
The Small-Size Telescope with single-mirror (SST-1M) is a 4 m Davies-Cotton
telescope and is among the proposed telescope designs for the Cherenkov
Telescope Array (CTA). It is conceived to provide the high-energy ( few TeV)
coverage. The SST-1M contains proven technology for the telescope structure and
innovative electronics and photosensors for the camera. Its design is meant to
be simple, low-budget and easy-to-build industrially.
Each device subsystem of an SST-1M telescope is made visible to CTA through a
dedicated industrial standard server. The software is being developed in
collaboration with the CTA Medium-Size Telescopes to ensure compatibility and
uniformity of the array control. Early operations of the SST-1M prototype will
be performed with a subset of the CTA central array control system based on the
Alma Common Software (ACS). The triggered event data are time stamped,
formatted and finally transmitted to the CTA data acquisition.
The software system developed to control the devices of an SST-1M telescope
is described, as well as the interface between the telescope abstraction to the
CTA central control and the data acquisition system.Comment: In Proceedings of the 34th International Cosmic Ray Conference
(ICRC2015), The Hague, The Netherlands. All CTA contributions at
arXiv:1508.0589
Prototype of the SST-1M Telescope Structure for the Cherenkov Telescope Array
A single-mirror small-size (SST-1M) Davies-Cotton telescope with a dish
diameter of 4 m has been built by a consortium of Polish and Swiss institutions
as a prototype for one of the proposed small-size telescopes for the southern
observatory of the Cherenkov Telescope Array (CTA). The design represents a
very simple, reliable, and cheap solution. The mechanical structure prototype
with its drive system is now being tested at the Institute of Nuclear Physics
PAS in Krakow. Here we present the design of the prototype and results of the
performance tests of the structure and the drive and control system.Comment: In Proceedings of the 34th International Cosmic Ray Conference
(ICRC2015), The Hague, The Netherlands. All CTA contributions at
arXiv:1508.0589
The SST-1M camera for the Cherenkov Telescope Array
The prototype camera of the single-mirror Small Size Telescopes (SST-1M)
proposed for the Cherenkov Telescope Array (CTA) project has been designed to
be very compact and to deliver high performance over thirty years of operation.
The camera is composed of an hexagonal photo-detection plane made of custom
designed large area hexagonal silicon photomultipliers and a high throughput,
highly configurable, fully digital readout and trigger system (DigiCam). The
camera will be installed on the telescope structure at the H.
Niewodnicza{\'n}ski institute of Nuclear Physics in Krakow in fall 2015. In
this contribution, we review the steps that led to the development of the
innovative photo-detection plane and readout electronics, and we describe the
test and calibration strategy adopted.Comment: In Proceedings of the 34th International Cosmic Ray Conference
(ICRC2015), The Hague, The Netherlands. All CTA contributions at
arXiv:1508.05894; Full consortium author list at http://cta-observatory.or
DigiCam - Fully Digital Compact Read-out and Trigger Electronics for the SST-1M Telescope proposed for the Cherenkov Telescope Array
The SST-1M is one of three prototype small-sized telescope designs proposed
for the Cherenkov Telescope Array, and is built by a consortium of Polish and
Swiss institutions. The SST-1M will operate with DigiCam - an innovative,
compact camera with fully digital read-out and trigger electronics. A high
level of integration will be achieved by massively deploying state-of-the-art
multi-gigabit transmission channels, beginning from the ADC flash converters,
through the internal data and trigger signals transmission over backplanes and
cables, to the camera's server link. Such an approach makes it possible to
design the camera to fit the size and weight requirements of the SST-1M
exactly, and provide low power consumption, high reliability and long lifetime.
The structure of the digital electronics will be presented, along with main
physical building blocks and the internal architecture of FPGA functional
subsystems.Comment: In Proceedings of the 34th International Cosmic Ray Conference
(ICRC2015), The Hague, The Netherlands. All CTA contributions at
arXiv:1508.0589
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