Generalized diffusion equation

Modern analyses of diffusion processes have proposed nonlinear versions of the Fokker-Planck equation to account for non-classical diffusion. These nonlinear equations are usually constructed on a phenomenological basis. Here we introduce a nonlinear transformation by defining the $q$-generating function which, when applied to the intermediate scattering function of classical statistical mechanics, yields, in a mathematically systematic derivation, a generalized form of the advection-diffusion equation in Fourier space. Its solutions are discussed and suggest that the $q$-generating function approach should be a useful tool to generalize classical diffusive transport formulations.Comment: 5 pages with 3 figure

Molecular theory of anomalous diffusion

We present a Master Equation formulation based on a Markovian random walk model that exhibits sub-diffusion, classical diffusion and super-diffusion as a function of a single parameter. The non-classical diffusive behavior is generated by allowing for interactions between a population of walkers. At the macroscopic level, this gives rise to a nonlinear Fokker-Planck equation. The diffusive behavior is reflected not only in the mean-squared displacement ($\sim t^{\gamma}$ with $0 <\gamma \leq 1.5$) but also in the existence of self-similar scaling solutions of the Fokker-Planck equation. We give a physical interpretation of sub- and super-diffusion in terms of the attractive and repulsive interactions between the diffusing particles and we discuss analytically the limiting values of the exponent $\gamma$. Simulations based on the Master Equation are shown to be in agreement with the analytical solutions of the nonlinear Fokker-Planck equation in all three diffusion regimes.Comment: Published text with additional comment

Propagation-Dispersion Equation

A {\em propagation-dispersion equation} is derived for the first passage distribution function of a particle moving on a substrate with time delays. The equation is obtained as the continuous limit of the {\em first visit equation}, an exact microscopic finite difference equation describing the motion of a particle on a lattice whose sites operate as {\em time-delayers}. The propagation-dispersion equation should be contrasted with the advection-diffusion equation (or the classical Fokker-Planck equation) as it describes a dispersion process in {\em time} (instead of diffusion in space) with a drift expressed by a propagation speed with non-zero bounded values. The {\em temporal dispersion} coefficient is shown to exhibit a form analogous to Taylor's dispersivity. Physical systems where the propagation-dispersion equation applies are discussed.Comment: 12 pages+ 5 figures, revised and extended versio

The Birth of the Idea of Bali

Page range: 71-8

A microscopic approach to nonlinear Reaction-Diffusion: the case of morphogen gradient formation

We develop a microscopic theory for reaction-difusion (R-D) processes based on a generalization of Einstein's master equation with a reactive term and we show how the mean field formulation leads to a generalized R-D equation with non-classical solutions. For the $n$-th order annihilation reaction $A+A+A+...+A\rightarrow 0$, we obtain a nonlinear reaction-diffusion equation for which we discuss scaling and non-scaling formulations. We find steady states with either solutions exhibiting long range power law behavior (for $n>\alpha$) showing the relative dominance of sub-diffusion over reaction effects in constrained systems, or conversely solutions (for $n<\alpha<n+1$) with finite support of the concentration distribution describing situations where diffusion is slow and extinction is fast. Theoretical results are compared with experimental data for morphogen gradient formation.Comment: Article, 10 pages, 5 figure

International Conference: Alternative Histories of Electronic Music, 2016

Video proceedings of the first international conference on ‘Alternative Histories of Electronic Music’ (AHEM2016), held at the Science Museum, London, 14-16 April 2016. The conference programme booklet (PDF), and video recordings of the opening address and closing remarks (MP4), may be downloaded here. Video recordings of the individual talks and keynote addresses delivered at the conference may be accessed via the video proceedings index, also downloadable here. This conference was held as part of the AHRC-funded project ‘Hugh Davies: Electronic Music Innovator’, led by Dr James Mooney (University of Leeds) in partnership with Dr Tim Boon (Science Museum). Project reference: AH/M005216/1

Molecular theory of anomalous diffusion - Application to Fluorescence Correlation Spectroscopy

The nonlinear theory of anomalous diffusion is based on particle interactions giving an explicit microscopic description of diffusive processes leading to sub-, normal, or super-diffusion as a result competitive effects between attractive and repulsive interactions. We present the explicit analytical solution to the nonlinear diffusion equation which we then use to compute the correlation function which is experimentally measured by correlation spectroscopy. The theoretical results are applicable in particular to the analysis of fluorescence correlation spectroscopy of marked molecules in biological systems. More specifically we consider the case of fluorescently labeled lipids and we find that the nonlinear correlation spectrum reproduces very well the experimental data indicating sub-diffusive molecular motion of lipid molecules in the cell membrane.Comment: 13 pages including one figure; Submitted to the Journal of Statistical Physics. arXiv admin note: text overlap with arXiv:1302.557