525 research outputs found
Thermodynamic Properties, Mesomorphic Transitions and Recycling Behaviour of Cholesteryl Laurate Using DSCTechnique
Comparative experimental and Density Functional Theory (DFT) study of the physical properties of MgB2 and AlB2
In present study, we report an inter-comparison of various physical and
electronic properties of MgB2 and AlB2. Interestingly, the sign of S(T) is +ve
for MgB2 the same is -ve for AlB2. This is consistent our band structure plots.
We fitted the experimental specific heat of MgB2 to Debye Einstein model and
estimated the value of Debye temperature (theta) and Sommerfeld constant
(gamma) for electronic specific heat. Further, from gamma the electronic
density of states (DOS) at Fermi level N(EF) is calculated. From the ratio of
experimental N (EF) and the one being calculated from DFT, we obtained value of
Lembda to be 1.84, thus placing MgB2 in the strong coupling BCS category. The
electronic specific heat of MgB2 is also fitted below Tc using pi-model and
found that it is a two gap superconductor. The calculated values of two gaps
are in good agreement with earlier reports. Our results clearly demonstrate
that the superconductivity of MgB2 is due to very large phonon contribution
from its stretched lattice. The same two effects are obviously missing in AlB2
and hence it is not superconducting. DFT calculations demonstrated that for
MgB2 the majority of states come from Sigma and Pi 2p states of boron on the
other hand Sigma band at Fermi level for AlB2 is absent. This leads to a weak
electron phonon coupling and also to hole deficiency as Pi bands are known to
be of electron type and hence obviously the AlB2 is not superconducting. The
DFT calculations are consistent with the measured physical properties of the
studied borides, i.e., MgB2 and AlB2Comment: 16 pages Text + Figs: comments/suggestions welcome
([email protected])/www.freewebs.com/vpsawana
Anomalous Thermoelectric power of over-doped Bi2Sr2CaCu2O8 superconductor
Temperature dependence of thermoelectric power S(T) of three differently
processed Bi2Sr2CaCu2O8 (Bi2212) samples, viz. as-processed melt quenched
(Bi2212-MQ), 6000C N2-annealed (Bi2212-N2) and 6000C O2-annealed (Bi2212-O2) is
reported here. All the samples possess single-phase character and their
superconducting transition temperatures (TcR=0) are 85 K, 90 K and 72 K
respectively for Bi2212-MQ, Bi2212-N2 and Bi2212-O2. While Bi2212-MQ and
Bi2212-N2 samples are in near optimum doping regime, Bi2212-O2 is an over-doped
sample. TcS=0 values obtained through S(T) data are also in line with those
deduced from the temperature dependence of resistance and DC magnetization.
Interestingly, S(T) behaviour of the optimally-doped Bi2212-MQ and Bi2212-N2
samples is seen to be positive in whole temperature range, it is found negative
for the over-doped Bi2212-O2 sample above TcS=0. These results have been seen
in the light of the recent band structure calculations and the ensuing split
Fermi surface as determined by angle-resolved photoelectron spectroscopy
(ARPES).Comment: 11 Pages Text + Figs: comments welcome ([email protected]
Design and Development of Microcontroller-Based Clinical Chemistry Analyser for Measurement of Various Blood Biochemistry Parameters
Clinical chemistry analyser is a high-performance microcontroller-based photometric biochemical analyser to measure various blood biochemical parameters such as blood glucose, urea, protein, bilirubin, and so forth, and also to measure and observe
enzyme growth occurred while performing the other biochemical tests such as ALT (alkaline amino transferase), amylase, AST (aspartate amino transferase), and so forth. These tests are of great significance in biochemistry and used for diagnostic purposes and classifying various disorders and diseases such as diabetes, liver malfunctioning, renal diseases, and so forth. An inexpensive clinical chemistry analyser developed by the authors
is described in this paper. This is an open system in which any reagent kit available in the market can be used. The system is based on the principle of absorbance transmittance photometry. System design is based around 80C31 microcontroller with RAM, EPROM, and peripheral interface devices. The developed system incorporates light source, an optical module, interference filters of various wave lengths, peltier device for maintaining required temperature of the mixture in flow cell, peristaltic pump for sample aspiration, graphic LCD display for displaying blood parameters, patients test results and kinetic test graph, 40 columns mini thermal printer, and also 32-key keyboard for executing various functions. The lab tests conducted on the instrument include versatility of the analyzer, flexibility of the software, and treatment of sample. The prototype was tested and evaluated over 1000 blood samples successfully for seventeen blood parameters. Evaluation was carried out at Government Medical College and Hospital, the Department of Biochemistry. The test results were found to be comparable with other standard
instruments
Chalcogen Height Dependence of Magnetism and Fermiology in FeTe_xSe_{1-x}
FeTexSe1-x (x=0, 0.25, 0.50, 0.75 and 1) system has been studied using
density functional theory. Our results show that for FeSe, LDA seems better
approximation in terms of magnitude of magnetic energy whereas GGA
overestimates it largely. On the other hand for FeTe, GGA is better
approximation that gives experimentally observed magnetic state. It has been
shown that the height of chalcogen atoms above Fe layers has significant effect
on band structure, electronic density of states (DOS) at Fermi level N(EF) and
Fermi surfaces. For FeSe the value of N(EF) is small so as to satisfy Stoner
criteria for ferromagnetism, (I\timesN(EF)\geq1) whereas for FeTe, since the
value of N(EF) is large, the same is close to be satisfied. Force minimization
done for FeTexSe1-x using supercell approach shows that in disordered system Se
and Te do not share same site and have two distinct z coordinates. This has
small effect on magnetic energy but no significant difference in band structure
and DOS near EF when calculated using either relaxed or average value of z for
chalcogen atoms. Thus substitution of Se at Te site decreases average value of
chalcogen height above Fe layers which in turn affect the magnetism and
Fermiology in the system. By using coherent-potential approximation for
disordered system we found that height of chalcogen atoms above Fe layer rather
than chalcogen species or disorder in the anion planes, affect magnetism and
shape of Fermi surfaces (FS), thus significantly altering nesting conditions,
which govern antiferromagnetic spin fluctuations in the system.Comment: 24 pages Text+Figs: comments/suggestions welcome
([email protected]
Aerosol optical depths at Mohal-Kullu in the northwestern Indian Himalayan high altitude station during ICARB
First time observations of spectral aerosol optical depths (AODs) at Mohal (31.9°N, 77.11°E; altitude 1154 m amsl) in the Kullu valley, located in the northwestern Indian Himalayan region, have been carried out during Integrated Campaign for Aerosols, gases and Radiation Budget (ICARB), as a part of the Indian Space Research Organisation-Geosphere Biosphere Program (ISRO-GBP). AODs at six wavelengths are obtained using Microtops-II Sunphotometer and Ozonometer. The monthly mean values of AOD at 500 nm are found to be 0.27 ± 0.04 and 0.24 ± 0.02 during March and April, 2006 respectively. However, their monthly mean values are 0.33 ± 0.04 at 380 nm and 0.20 ± 0.03 nm at 870 nm during March 2006 and 0.31 ± 0.3 at 380 nm and 0.17 ± 0.2 at 870 nm during April 2006, showing a gradual decrease in AOD with wavelength. The Angstrom wavelength exponent 'α' had a mean value of 0.72 ± 0.05, implying reduced dominance of fine particles. Further, the afternoon AOD values are higher as compared to forenoon values by ~33.0% during March and by ~9.0% during April 2006 and are attributed to the pollutant lifted up from the valley by the evolving boundary layer. Besides the long-range transportation of aerosol particles by airmass from the Great Sahara and the Thar Desert regions to the observing site, the high values of AODs have also been influenced by biomass burning and frequent incidents of forest fire at local levels
Additive Enhances Iron Ore Reducibility and Pig Iron Productivity
540-548The reducibility of iron ore with coke is an important parameter in a blast furnace process which significantly affects the production of pig iron. When iron ore and coke mixed with developed high energetic additive in blast furnace it promotes low temperature iron ore reduction and leads to coke saving. Results of proximate analysis values for moisture, ash, volatile matter and fixed carbon content were 15.28%, 16.62%, 1.02% 67.07% and 14.15%, 15.29%, 0.48% and 70.07% respectively with and without additive. Additive increased metallization of iron (Fe) content from 48.61% to 51.89% and decreased the ferrous oxide (FeO) from 12.26% to 9.28%. Additive reduced the CaO, SiO2, Al2O3 and MgO by 10.90%, 8.31%, 2.79%, and 1.47% respectively which showed improvement of quality of sinter and further reduction of the pig iron sulphur content from 0.22 to 0.08% which reflected improvement in metal product quality. Additive increased the slag chemical composition of CaO, SiO2, MgO, Al2O3 and MnO by 4.79%, 2.62%, 7.35%, 2.82 % and 19.56% respectively and decreased the FeO by 32.23%. Additive reduced the consumption of coke by 700 kg and increased production by 2% resulting saving of coke by 91 kg per ton of pig iron production. Additive increased reducibility, quality and productivity of pig iron with decrease in batch maturing period. Further it exhibited better performance in sintering process and reduced the un-agglomerated material. This paper describes the effect of additive used in the blast furnace process during industrial pig iron production
Bovine rotavirus pentavalent vaccine development in India
AbstractA bovine rotavirus pentavalent vaccine (BRV-PV) containing rotavirus human-bovine (UK) reassortant strains of serotype G1, G2, G3, G4 and G9 has been developed by the Serum Institute of India Ltd, in collaboration with the National Institute of Allergy and Infectious Diseases (NIAID), USA. The vaccine underwent animal toxicity studies and Phase I and II studies in adults, toddlers and infants. It has been found safe and immunogenic and will undergo a large Phase III study to assess efficacy against severe rotavirus gastroenteritis
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