Boundary lubrication, thermal and oxidative stability of a fluorinated polyether and a perfluoropolyether triazine

Boundary lubricating characteristics, thermal stability, and oxidation-corrosion stability were determined for a fluorinated polyether and a perfluoropolyether triazine. A ball-on-disk apparatus, a tensimeter, and oxidation-corrosion apparatus were used. Results were compared to data for a polyphenyl ether and a C-ether. The polyether and triazine yielded better boundary lubricating characteristics than either the polyphenyl ether or C-ether. The polyphenyl ether had the greatest thermal stability (443 C) while the other fluids had stabilities in the range 389 to 397 C. Oxidation-corrosion results indicated the following order of stabilities: perfluoropolyether trizine greater than polyphenyl ether greater than C-ether greater than fluorinated polyether

Apparatus for establishing flow of a fluid mass having a known velocity

An apparatus for establishing a flow of fluid mass, such as gas, having a known velocity is introduced. The apparatus is characterized by an hermetically sealed chamber conforming to a closed-loop configuration and including a throat and a plurality of axially displaceable pistons for sweeping through the throat a stream of gas including a core and an unsheared boundary layer. Within the throat there is a cylindrical coring body concentrically related to the throat for receiving the core, and a chamber surrounding the cylindrical body for drawing off the boundary layer, whereby the velocity of the core is liberated from the effects of the velocity of the boundary layer

Fuel quality-processing study. Volume 2: Literature survey

The validity of initial assumptions about raw materials choices and relevant upgrading processing options was confirmed. The literature survey also served to define the on-site (at the turbine location) options for fuel treatment and exhaust gas treatment. The literature survey also contains a substantial compilation of specification and physical property information about liquid fuel products relevant to industrial gas turbines

Infrared emission spectrophotometric study of the changes produced by TiN coating of metal surfaces in an operating EHD contact

Infrared emission spectra and related measurements were obtained from an operating ball/plate elastohydrodynamic (EHD) sliding contact under a variety of operating conditions. In order to be able to compare the effect of the ball surface, some of the balls were coated with a thin layer of titanium nitride (TiN) by vapor deposition. Polyphenyl ether (5P4E) was used as lubricant and 1 percent of 1,1,2-trichloroethane (TCE) as a surface-probing additive. TiN is chemically inert and its thermal conductivity is lower than that of steel. Therefore, the overall temperatures with TiN coated balls were higher. Nevertheless, no scuffing was observed with the coated balls under conditions giving rise to scuffing with the uncoated balls. Tractions were lower with the TiN coated balls and always when TCE was added to the 5P4E. These findings were found to be inversely related to the degree of polarization of the spectral emission bands. The intensity and the dichrosim of these bands were related to shear rates and inlet conditions of the EHD contact

Methods for structural design at elevated temperatures

A procedure which can be used to design elevated temperature structures is discussed. The desired goal is to have the same confidence in the structural integrity at elevated temperature as the factor of safety gives on mechanical loads at room temperature. Methods of design and analysis for creep, creep rupture, and creep buckling are presented. Example problems are included to illustrate the analytical methods. Creep data for some common structural materials are presented. Appendix B is description, user's manual, and listing for the creep analysis program. The program predicts time to a given creep or to creep rupture for a material subjected to a specified stress-temperature-time spectrum. Fatigue at elevated temperature is discussed. Methods of analysis for high stress-low cycle fatigue, fatigue below the creep range, and fatigue in the creep range are included. The interaction of thermal fatigue and mechanical loads is considered, and a detailed approach to fatigue analysis is given for structures operating below the creep range

The effects of metals and inhibitors on thermal oxidative degradation reactions of unbranched perfluoroalkylethers

Thermal oxidative degradation studies were performed on unbranched perfluoroalkylethers at 288 C in oxygen. Metals and alloys studied included Ti, Al, and Ti (4 Al, 4 Mn). The mechanism of degradation was by chain scission. Ti and Al promoted less degradation than Ti (4 Al, 4 Mn). The two inhibitors investigated (a perfluorophenyl phosphine and a phosphatriazine) reduced degradation rates by several orders of magnitude. Both inhibitors were effective for the same duration (75 to 100 hours). The phosphatriazine appeared to provide more surface protection

Age, Growth, and Mortality of Atlantic Croaker, Micropogonias undulatus, in the Chesapeake Bay Region, With a Discussion of Apparent Geographic Changes in Population Dynamics

Atlantic croaker, Micropogonias undulatus, collected from commercial catches in Chesapeake Bay and in Virginia and North Carolina coastal waters during 1988-1991 (n=1,967) were aged from transverse otolith sections. Ages 1-8 were recorded, but eight-year-old fish were rare. Marginal increment analysis showed that for ages 1-7, annuli are formed once a year during the period April-May. Otolith age readings were precise: \u3e99% agreement within and between readers. Observed lengths-at-age were highly variable and growth rate decreased after the first year. Despite the high variability in sizes-at-age, observed lengths for ages 1-7 fit the von Bertalanffy growth model (r2=0.99; n=753) well. No differences in growth were found between sexes. Total annual instantaneous mortality (Z) estimated from maximum age and from a catch curve of Chesapeake Bay commercial catches ranged from 0.55 to 0.63. Our results do not indicate the existence of a group of larger, older Atlantic croaker in Chesapeake Bay compared with more southern waters and suggest that the hypothesis of a basically different population dynamics pattern for this species north and south of Cape Hatteras, North Carolina, should be reevaluated

Tribology: The Story of Lubrication and Wear

Topics addressed include: lubrication and design of high speed rolling element bearings, high speed gears, and traction drives