Study on heavy metal adsorption by chitosan biopolymer

Heavy metal pollution is a serious problem to aquatic ecosystems because some of these metals are potentially toxic even at very low concentrations. Chitosan, a biopolymer produced from crustacean shells, has applications in various areas, particularly in drinking water and wastewater treatment due to its ability to remove metallic ions from solutions. The purpose of this research work was to study the adsorption of cadmium and lead ions into chitosan, produced from shrimp shells at the laboratory level. Shrimp type “penaeus monodon” (giant tiger prawn) was used to synthesis the chitosan. The main characteristic properties such as degree of deacetylation (DD); the amount of amine groups in chitosan, viscosity, crystallinity and thermal analysis were done by using Fourier transform infrared spectroscopy, Brookfield viscometer, X-ray spectroscopy, thermo gravimetric analysis (TGA) and differential thermal analysis (DTA). Chitosan, with a degree of deacetylation between 80%- 95% was used in the experimental part and the flake sizes were smaller than 0.25mm. Experimental work involved the determination of the adsorption isotherms and kinetic studies for each metallic ion in a batch system. Effect of Degree of deacetylation (DD) of the chitosan, effect of initial pH of the metal ion solution, effect of particle size, effect of initial heavy metal concentration, and effect of chitosan dosage were studied. The results showed that the adsorption capacity depends strongly on pH of the solution, DD of chitosan and slightly depends on the particle size. According to the results, pH values at 6.5 for cadmium and pH values at 4.5 for lead show higher adsorption capacity. High DD chitosan showed higher adsorption capacity mainly due to the higher number of active amino groups in high DD sample. Simplified kinetic models such as pseudo-first-order, pseudo-second-order, Elovich model and intra-particle diffusion model were used to determine the rate limiting step. Both linear and non-linear According to the kinetic models pseudo second order model best described the adsorption process. Both linear and non-linear models and Elovich model best described the adsorption process. Multilinearity in the intraparticle diffusion model suggested that the adsorption of heavy metal consists of two major steps, due to the different pore sizes of chitosan. Equilibrium experimental data were analyzed by using two different isotherm models namely, Langmuir and Freundlich. According to the results, adsorption process of cadmium and lead heavy metals is heterogeneous and multilayer adsorption as it best fit with the Freundlich isotherm model. According to the thermodynamic experiments, adsorption process is favorable and physical adsorption was predominant in the adsorption process. Desorption of the heavy metals was possible by using different regeneration solutions

Study of Adsorption Characteristics of Cadmium into Chitosan biopolymer to be used for waste water treatments

Pollution by heavy metals is a serious threat to aquatic ecosystems because some of these metals are potentially toxic even at very low concentrations. Chitosan, a biopolymer produced from crustacean shells, has applications in various areas, particularly in drinking water and wastewater treatment due to its ability to remove metallic ions from solutions. The purpose of this research work was to study the adsorption of cadmium on chitosan produced from shrimp shells at a laboratory level. Chitosan, with a degree of deacetylation of approximately 70%, was used in the experimental part and the flake sizes were smaller than 0.25mm. Experimental work involved the determination of the adsorption isotherms for each metallic ion in a batch system. The resulting isotherms were fitted using Langmuir model and the parameters of the equation were determined. Kinetic studies of adsorption for metallic ions at different concentrations and with different particle sizes were performed in batch system. Simplified models such as pseudo-first-order, pseudo-secondorder, and intra-particle diffusion equations were used to determine the rate controlling step. The results showed that the adsorption capacity depends strongly on pH and on the species of metallic ions in the solution. Batch adsorption experiments were performed at two differentdegrees of deacetylation (DD) values, time period ranging from 15 minutes to 3 hours and pH of solutions ranging from 3 to 7. The study showed that the solution pH strongly affects the adsorption capacity of chitosan

Adsorption of cadmium and lead heavy metals by Chitosan Biopolymer : a study on equilibrium Isotherms and kinetics

Since heavy metal pollution is a significant aspect to aquatic ecosystems, the objective of this research work was to investigate adsorption characteristics of chitosan as an alternative adsorbent material. In this study, chitosan, synthesized from locally available shrimp type “penaeus monodon” was used to observe adsorption characteristics of cadmium (Cd) and lead (Pb) heavy metals from aqueous solution. Batch kinetic experiment studies were conducted for changing initial pH, initial concentration of metal ions, particle size and degree of deacetylation (DD) of chitosan. Simplified models such as, pseudo first order, pseudo second order and intra-particle diffusion models were used to analyze the experimental data. The result showed that the adsorption capacity strongly depends on pH and DD. It was clearly seen that higher adsorption of heavy metals occur at comparatively high pH and high DD. Equilibrium experimental data were analyzed by using two different isotherm models namely, Langmuir and Freundlich. The characteristic parameters for each isotherm and related correlation coefficients were determined by using mathematical modeling software. Isotherms show that adsorption process of Cd and Pb is a heterogeneous process

Effect of deacetylation conditions on synthesis of chitosan using shrimp type "penaeus monodon"

In this study synthesis of chitosan from shrimp type penaeus monodon and effect of degree of deacetylation conditions were studied. Chitin was extracted from shrimp shells and deacetylation process was done to synthesize chitosan under different conditions. Characterization of the synthesized chitosan was done using Fourier Transmission Infrared spectroscopy (FTIR) and X-ray diffraction (XRD) techniques. The effect of NaOH concentration, reaction temperature, and reflux time on the deacetylation process was investigated. Degree of deacetylation of chitosan was determined using infrared spectroscopy technique. Mainly, the increasing of NaOH concentration, temperature, number of deacetylation time and reflux time can enhance the degree of deacetylation (DD) of chitosan

Alginate: Pharmaceutical and Medical Applications

Due to their outstanding properties in terms of mild gelation conditions and simple functionalization, biocompatibility, low toxicity, biodegradability, non-antigenicity and chelating ability, as well as relatively low cost, alginates have been widely used in a variety of biomedical applications including tissue engineering and drug delivery systems. Smart alginate hydrogels for on-demand drug release in response to environmental stimuli and 3D bioprinting will play an important role in the future. These and the introduction of appropriate cell interactive features will be crucial for many tissue engineering applications. The focus of the present chapter is to highlight the great potential of the alginates as biomaterial for biomedical applications and to discuss the role that alginate-based materials are likely to play in biomedical applications in the future.info:eu-repo/semantics/publishedVersio