Nanoscopic optical sensors based on functional supramolecular hybrid materials

[EN] This review highlights how the combination of supramolecular principles and nanoscopic solid structures enables the design of new hybrid sensing ensembles with improved sensitivity and/or selectivity and for the targeting of analytes for which selectivity is hard to achieve by conventional methods. Such ideas are bridging the gap between molecules, materials sciences and nanotechnology. Relevant examples will be detailed, taking into account functional aspects such as (1) enhanced coordination of functionalized solids, (2) enhanced signalling through preorganization, (3) signalling by assembly-disassembly of nanoscopic objects, (4) biomimetic probes utilizing discrimination by polarity and size and (5) distinct switching and gating protocols. These strategies are opening new prospects for sensor research and signalling paradigms at the frontier between nanotechnology, smart materials and supramolecular chemistry. © 2010 Springer-Verlag.Financial support from the Ministerio de Ciencia y Tecnologia (project MAT2009-14564-C04), the Generalitat Valencia (project PROMETEO/2009/016) and the Innovationsfonds (BAM/Bundesministerium fur Wirtschaft und Technologie) is gratefully acknowledged.Martínez Mañez, R.; Sancenón Galarza, F.; Hecht, M.; Biyikal, M.; Rurack, K. (2011). Nanoscopic optical sensors based on functional supramolecular hybrid materials. Analytical and Bioanalytical Chemistry. 399:55-74. https://doi.org/10.1007/s00216-010-4198-2S5574399Lehn JM (1995) Supramolecular chemistry: concepts and perspectives. VCH, WeinheimSteed JW, Atwood JL (2000) Supramolecular chemistry. Wiley, HobokenRurack K, Martínez-Máñez R (eds) (2010) The supramolecular chemistry of organic-inorganic hybrid materials. 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