Robust and Biocompatible Functionalization of ZnS Nanoparticles by Catechol-Bearing Poly(2-Methyl-2-Oxazoline)s.

Zinc sulfide (ZnS) nanoparticles (NPs) are particularly interesting materials for their electronic and luminescent properties. Unfortunately, their robust and stable functionalization and stabilization, especially in aqueous media, has represented a challenging and not yet completely accomplished task. In this work, we report the synthesis of colloidally stable, photoluminescent and biocompatible core\u2013polymer shell ZnS and ZnS:Tb NPs by employing a water-in-oil miniemulsion (ME) process combined with surface functionalization via catechol-bearing poly-2-methyl-2-oxazoline (PMOXA) of various molar masses. The strong binding of catechol anchors to the metal cations of the ZnS surface, coupled with the high stability of PMOXA against chemical degradation, enable the formation of suspensions presenting excellent colloidal stability. This feature, combined with the assessed photoluminescence and biocompatibility, make these hybrid NPs suitable for optical bioimaging

Behavior of RC beams shear strengthened with bonded or unbonded FRP wraps

Author name used in this manuscript: J. G. Teng2009-2010 > Academic research: refereed > Publication in refereed journalAccepted ManuscriptPublishe

Interaction between Steel Stirrups and Shear-Strengthening FRP Strips in RC Beams

RC beams shear strengthened with either fiber-reinforced polymer (FRP) U-jackets/U-strips or side strips commonly fail due to debonding of the bonded FRP shear reinforcement. As such debonding occurs in a brittle manner at relatively small shear crack widths, some of the internal steel stirrups may not have reached yielding. Consequently, the yield strength of internal steel stirrups in such a strengthened RC beam cannot be fully used. In this paper, a computational model for shear interaction between FRP strips and steel stirrups is first presented, in which a general parabolic crack shape function is employed to represent the widening process of a single major shear crack in an RC beam. In addition, appropriate bond-slip relationships are adopted to accurately depict the bond behavior of FRP strips and steel stirrups. Numerical results obtained using this computational model show that a substantial adverse effect of shear interaction generally exists between steel stirrups and FRP strips for RC beams shear strengthened with FRP side strips. For RC beams shear strengthened with FRP U-strips, shear interaction can still have a significant adverse effect when FRP strips with a high axial stiffness are used. Therefore, for accurate evaluation of the shear resistance of RC beams shear strengthened with FRP strips, this adverse effect of shear interaction should be properly considered in design.Department of Civil and Environmental Engineerin

Enzymatically crosslinked poly(2-alkyl-2-oxazoline) networks for 3D cell culture

Molecularly designed, random copolymer-bioconjugates based on poly(2-methyl-2-oxazoline) (PMOXA) and poly(2-ethyl-2-oxazoline) (PEOXA) are crosslinked in the presence of sortase A (SA) and human articular chondrocytes (hACs), to yield cellularized polymer networks. Their gelation kinetics and mechanical properties are finely tuned by varying the concentration of SA, while a cell viability >90% is achieved after several weeks of culture, even in the absence of any cell-adhesive cue

Behavior of RC Beams Shear Strengthened with Bonded or Unbonded FRP Wraps

Reinforced concrete (RC) beams shear-strengthened with fiber-reinforced polymer (FRP) fully wrapped around the member usually fail due to rupture of FRP, commonly preceded by gradual debonding of the FRP from the beam sides. To gain a better understanding of the shear resistance mechanism of such beams, particularly the interaction between the FRP, concrete, and internal steel stirrups, nine beams were tested in the present study: three as control specimens, three with bonded FRP full wraps, and three with FRP full wraps left unbonded to the beam sides. The use of unbonded wraps was aimed at a reliable estimation of the FRP contribution to shear resistance of the beam and how bonding affects this contribution. The test results show that the unbonded FRP wraps have a slightly higher shear strength contribution than the bonded FRP wraps, and that for both types of FRP wraps, the strain distributions along the critical shear crack are close to parabolic at the ultimate state. FRP rupture of the strengthened beams occurred at a value of maximum FRP strain considerably lower than the rupture strain found from tensile tests of flat coupons, which may be attributed to the effects of the dynamic debonding process and deformation of the FRP wraps due to the relative movements between the two sides of the critical shear crack. Test results also suggest that while the internal steel stirrups are fully used at beam shear failure by FRP rupture, the contribution of the concrete to the shear capacity may be adversely affected at high values of tensile strain in FRP wraps.Department of Civil and Environmental EngineeringAuthor name used in this manuscript: J. G. Ten