Fast preparation route to high-performances textured Sr-doped Ca 3 Co 4 O 9 thermoelectric materials through precursor powder modification

This work presents a short and very efficientmethod to produce high performance textured Ca3Co4O9thermoelectric materials through initial powders modifica-tion. Microstructure has shown good grain orientation, andlow porosity while slightly lower grain sizes were obtained insamples prepared from attrition milled powders. All samplesshow the high density of around 96% of the theoretical value.These similar characteristics are reflected in, approximately,the same electrical resistivity and Seebeck coefficient valuesfor both types of samples. However, in spite of similar powerfactor (PF) at low temperatures, it is slightly higher at hightemperature for the attrition milled samples. On the otherhand, the processing time reduction (from 38 to 2 h) whenusing attrition milled precursors, leads to lower mechanicalproperties in these samples. All these data clearly point out tothe similar characteristics of both kinds of samples, with adrastic processing time decrease when using attrition milledprecursors, which is of the main economic importance whenconsidering their industrial production

Study by Hall probe mapping of the trapped flux modification produced by local heating in YBCOHTS bulks for different surface/volume ratios

The aim of this report is to compare the trapped field distribution under a local heating created at the sample edge for different sample morphologies. Hall probe mappings of the magnetic induction trapped in YBCO bulk samples maintained out of thermal equilibrium were performed on YBCO bulk single domains, YBCO single domains with regularly spaced hole arrays, and YBCO superconducting foams. The capability of heat draining was quantified by two criteria: the average induction (B) decay and the size of the thermally affected zone caused by a local heating of the sample. Among the three investigated sample shapes, the drilled single domain displays a trapped induction which is weakly affected by the local heating while displaying a high trapped field. Finally, a simple numerical modelling of the heat flux spreading into a drilled sample is used to suggest some design rules about the hole configuration and their size

Measurement of the magnetic field inside the holes of a drilled bulk high-Tc superconductor

We use macroscopic holes drilled in a bulk YBCO superconductor to probe its magnetic properties in the volume of the sample. The sample is subjected to an AC magnetic flux with a density ranging from 30mT to 130mT and the flux in the superconductor is probed by miniature coils inserted in the holes. In a given hole, three different penetration regimes can be observed: (i) the shielded regime, where no magnetic flux threads the hole; (ii) the gradual penetration regime, where the waveform of the magnetic field has a clipped sine shape whose fundamental component scales with the applied field; and (iii) the flux concentration regime, where the waveform of the magnetic field is nearly a sine wave, with an amplitude exceeding that of the applied field by up to a factor of two. The distribution of the penetration regimes in the holes is compared with that of the magnetic flux density at the top and bottom surfaces of the sample, and is interpreted with the help of optical polarized light micrographs of these surfaces. We show that the measurement of the magnetic field inside the holes can be used as a local characterization of the bulk magnetic properties of the sample