2 research outputs found
High Magnetic Field NMR Studies of LiVGeO, a quasi 1-D Spin System
We report Li pulsed NMR measurements in polycrystalline and single
crystal samples of the quasi one-dimensional S=1 antiferromagnet
LiVGeO, whose AF transition temperature is K.
The field () and temperature () ranges covered were 9-44.5 T and
1.7-300 K respectively. The measurements included NMR spectra, the spin-lattice
relaxation rate (), and the spin-phase relaxation rate (),
often as a function of the orientation of the field relative to the crystal
axes. The spectra indicate an AF magnetic structure consistent with that
obtained from neutron diffraction measurements, but with the moments aligned
parallel to the c-axis. The spectra also provide the -dependence of the AF
order parameter and show that the transition is either second order or weakly
first order. Both the spectra and the data show that has at
most a small effect on the alignment of the AF moment. There is no spin-flop
transition up to 44.5 T. These features indicate a very large magnetic
anisotropy energy in LiVGeO with orbital degrees of freedom playing an
important role. Below 8 K, varies substantially with the orientation
of in the plane perpendicular to the c-axis, suggesting a small energy
gap for magnetic fluctuations that is very anisotropic.Comment: submitted to Phys. Rev.