Defect chemistry and transport properties of BaxCe0.85M0.15O3-d

The site-incorporation mechanism of M3+ dopants into A2+B4+O3 perovskites controls the overall defect chemistry and thus their transport properties. For charge-balance reasons, incorporation onto the A2+-site would require the creation of negatively charged point defects (such as cation vacancies), whereas incorporation onto the B4+-site is accompanied by the generation of positively charged defects, typically oxygen vacancies. Oxygen-vacancy content, in turn, is relevant to proton-conducting oxides in which protons are introduced via the dissolution of hydroxyl ions at vacant oxygen sites. We propose here, on the basis of x-ray powder diffraction studies, electron microscopy, chemical analysis, thermal gravimetric analysis, and alternating current impedance spectroscopy, that nominally B-site doped barium cerate can exhibit dopant partitioning as a consequence of barium evaporation at elevated temperatures. Such partitioning and the presence of significant dopant concentrations on the A-site negatively impact proton conductivity. Specific materials examined are BaxCe0.85M0.15O3-d (x = 0.85 - 1.20; M = Nd, Gd, Yb). The compositional limits for the maximum A-site incorporation are experimentally determined to be: (Ba0.919Nd0.081)(Ce0.919Nd0.081)O3, (Ba0.974Gd0.026)(Ce0.872Gd0.128)O2.875, and Ba(Ce0.85Yb0.15)O2.925. As a consequence of the greater ability of larger cations to exist on the Ba site, the H2O adsorption and proton conductivities of large-cation doped barium cerates are lower than those of small-cation doped analogs

Condensation in an Economic Model with Brand Competition

We present a linear agent based model on brand competition. Each agent belongs to one of the two brands and interacts with its nearest neighbors. In the process the agent can decide to change to the other brand if the move is beneficial. The numerical simulations show that the systems always condenses into a state when all agents belong to a single brand. We study the condensation times for different parameters of the model and the influence of different mechanisms to avoid condensation, like anti monopoly rules and brand fidelity.Comment: Accepted in: International Journal of Modern Physics

Particle Currents in a Space-Time dependent and CP-violating Higgs Background: a Field Theory Approach

Motivated by cosmological applications like electroweak baryogenesis, we develop a field theoretic approach to the computation of particle currents on a space-time dependent and CP-violating Higgs background. We consider the Standard Model model with two Higgs doublets and CP violation in the scalar sector, and compute both fermionic and Higgs currents by means of an expansion in the background fields. We discuss the gauge dependence of the results and the renormalization of the current operators, showing that in the limit of local equilibrium, no extra renormalization conditions are needed in order to specify the system completely.Comment: 21 pages, LaTeX file, uses epsf.sty. 4 figures available as a compressed .ep

The CP properties of the lightest Higgs boson with sbottom effects

In the framework of the recently proposed gluino-axion model, using the effective potential method and taking into account the top-stop as well as the bottom-sbottom effects, we discuss the CP--properties of the lightest Higgs boson, in particular its CP--odd composition, which can offer new opportunities at collider searches. It is found that although the CP-odd composition of the lightest Higgs increases slightly with the inclusion of the sbottom effects, it never exceeds %0.17 for all values of the renormalization scale Q ranging from top mass to TeV scaleComment: 24 pp, 12 eps fig

On One-Loop Gap Equations for the Magnetic Mass in d=3 Gauge Theory

Recently several workers have attempted determinations of the so-called magnetic mass of d=3 non-Abelian gauge theories through a one-loop gap equation, using a free massive propagator as input. Self-consistency is attained only on-shell, because the usual Feynman-graph construction is gauge-dependent off-shell. We examine two previous studies of the pinch technique proper self-energy, which is gauge-invariant at all momenta, using a free propagator as input, and show that it leads to inconsistent and unphysical result. In one case the residue of the pole has the wrong sign (necessarily implying the presence of a tachyonic pole); in the second case the residue is positive, but two orders of magnitude larger than the input residue, which shows that the residue is on the verge of becoming ghostlike. This happens because of the infrared instability of d=3 gauge theory. A possible alternative one-loop determination via the effective action also fails. The lesson is that gap equations must be considered at least at two-loop level.Comment: 21 pages, LaTex, 2 .eps figure

Modeling soil-water-plant relationships in the cerrado soils of Brasil: the case of maize (Zea mays L.).

A soil-water balance simulation model developed for the Cerrado soils of central Brazil is presented. The model calculates daily soil water evaporation, plant transpiration and soil-water balance for fourteen soil layers of 15 mm each. The model includes a subroutine to calculated capillary water movement. Computer simulations of daily soil water levels at five soil depths (15, 30, 45, 60 and 90 cm) for a field of maize are compared with actual field measurements over an-8--day period. Results indicated that the developed model can, in general, estimate the soil-water balance of the various depths within +/- 10% of actual measurements

Thirty-two Goldbach Variations

We give thirty-two diverse proofs of a small mathematical gem--the fundamental Euler sum identity zeta(2,1)=zeta(3) =8zeta(\bar 2,1). We also discuss various generalizations for multiple harmonic (Euler) sums and some of their many connections, thereby illustrating both the wide variety of techniques fruitfully used to study such sums and the attraction of their study.Comment: v1: 34 pages AMSLaTeX. v2: 41 pages AMSLaTeX. New introductory material added and material on inequalities, Hilbert matrix and Witten zeta functions. Errors in the second section on Complex Line Integrals are corrected. To appear in International Journal of Number Theory. Title change

Self-consistently Improved Finite Temperature Effective Potential for Gauge Theories

The finite temperature effective potential of the Abelian Higgs Model is studied using the self-consistent composite operator method, which sums up the contributions of daisy and superdaisy diagrams. The effect of the momentum dependence of the effective masses is estimated by using a Rayleigh-Ritz variational approximation.Comment: 29 pages, 7 figures not included, Plain Tex, BUHEP-93-12, to appear in Physical Review D49. (additional comments on renormalization and a more quantitative comparison with previous results have been included, one more figure, two new references, two references updated

Scale-independent mixing angles

A radiatively-corrected mixing angle has to be independent of the choice of renormalization scale to be a physical observable. At one-loop in MS-bar, this only occurs for a particular value, p*, of the external momentum in the two-point functions used to define the mixing angle: p*^2=(M1^2+M2^2)/2, where M1, M2 are the physical masses of the two mixed particles. We examine two important applications of this to the Minimal Supersymmetric Standard Model: the mixing angle for a) neutral Higgs bosons and b) stops. We find that this choice of external momentum improves the scale independence (and therefore provides a more reliable determination) of these mixing angles.Comment: 14 pages, 11 ps figures Version to appear in PR

Self-interactions of the lightest MSSM Higgs boson in the large pseudoscalar-mass limit

We investigate the decoupling properties of the Higgs-sector-induced one-loop corrections in the lightest Higgs-boson self-couplings, in the framework of the Minimal Supersymmetric Standard Model (MSSM). The renormalized n-point vertex functions with external Higgs particles in the MSSM and in the SM are derived to the one-loop level and compared in the MA >> MZ limit. The computation has been done in a general R_{xi} gauge and the on-shell renormalization scheme is chosen. By a comparison of the renormalized lightest Higgs-boson h^0 vertex functions with respect to the corresponding SM ones, we find that the differences between the predictions of both models are summarized in the lightest Higgs-boson mass correction Delta Mh. Consequently, the radiative corrections are absorbed in the Higgs-boson mass, and the trilinear and quartic h^0 self-couplings acquire the same structure as the couplings of the SM Higgs-boson. Therefore, decoupling of the heavy MSSM Higgs bosons occurs and the MSSM h^0 self-interactions converge to the SM ones in the MA >> MZ limit.Comment: LaTeX, 26 pages, 1 figure. Sections 4 and 5 summarized in one section. Some references added. Published version in Phys. Rev.