Role of process type and process conditions on phase content and physical properties of thermal sprayed TiO2 coatings

Thermal spray represents an advantageous technique for depositing large-area titanium dioxide coat- ings that are of interest for both traditional wear-resistant coatings as well as functional applications such as photo- induced decontamination surfaces. Numerous past studies have examined the phase evolution and properties of TiO2 coatings using different thermal spray processes or parameters. In this paper, an integrated study of thermal sprayed TiO2 was conducted with different thermal spray devices and process parameters for a single feedstock powder comprising the metastable anatase phase. The aforementioned variables are correlated with in-flight par- ticle state (particle temperature and velocity), phase evolution, and coating physical properties. The results are represented through the framework of process maps which connect process parameters with material properties. Based on the phase characterization, an initial exploration of the metastable phase evolution during thermal spray deposition of TiO2 is proposed. Furthermore, the sprayed TiO2 coat- ings show varying degrees of electrical conductivity associated with process-induced stoichiometric changes (vacancy generation) in the TiO2. The effects of these stoichiometric changes as well as extrinsic microstructural attributes (pores, cracks, interfaces), contribute to the complex electrical response of the coatings. This integrated study provides insights into the process–microstructure– property relationship with the ultimate goal of tailoring the functionality of spray deposited oxide thick films

Monitoring and Improving the Reliability of Plasma Spray Processes

Monitoring and improving of process reliability are prevalent issues in thermal spray technology. They are intended to accomplish specific quality characteristics by controlling the process. For this, implicit approaches are in demand to rapidly conclude on relevant coating properties, i.e., they are not directly measured, but it is assumed that the monitored variables are in fact suggestive for them. Such monitoring can be performed in situ (during the running process) instead of measuring coating characteristics explicitly (directly) and ex situ (after the process). Implicit approaches can be based on extrinsic variables (set from outside) as well as on intrinsic parameters (internal, not directly adjustable) having specific advantages and disadvantages, each. In this work, the effects of atmospheric plasma spray process variables are systemized in process schemes. On this basis, different approaches to contribute to improved process reliability are described and assessed paying particular attention to in-flight particle diagnostics. Finally, a new test applying spray bead analysis is introduced and first results are presented

The 2016 Thermal Spray Roadmap

Considerable progress has been made over the last decades in thermal spray technologies, practices and applications. However, like other technologies, they have to continuously evolve to meet new problems and market requirements. This article aims to identify the current challenges limiting the evolution of these technologies and to propose research directions and priorities to meet these challenges. It was prepared on the basis of a collection of short articles written by experts in thermal spray who were asked to present a snapshot of the current state of their specific field, give their views on current challenges faced by the field and provide some guidance as to the R&D required to meet these challenges. The article is divided in three sections that deal with the emerging thermal spray processes, coating properties and function, and biomedical, electronic, aerospace and energy generation applications