Variation of the glass transition temperature with rigidity and chemical composition

The effects of flexibility and chemical composition in the variation of the glass transition temperature are obtained by using the Lindemann criteria, that relates melting temperature with atomic vibrations. Using this criteria and that floppy modes at low frequencies enhance in a considerable way the average cuadratic displacement, we show that the consequence is a modified glass transition temperature. This approach allows to obtain in a simple way the empirically modified Gibbs-DiMarzio law, which has been widely used in chalcogenide glasses to fit the changes in the glass transition temperature with the chemical composition . The method predicts that the constant that appears in the law depends upon the ratio of two characteristic frequencies (or temperatures). Then, the constant for the Se-Ge-As glass is estimated by using the experimental density of vibrational states, and the result shows a very good agreement with the experimental fit from glass transition temperature variation

Self-organization with equilibration: a model for the intermediate phase in rigidity percolation

Recent experimental results for covalent glasses suggest the existence of an intermediate phase attributed to the self-organization of the glass network resulting from the tendency to minimize its internal stress. However, the exact nature of this experimentally measured phase remains unclear. We modify a previously proposed model of self-organization by generating a uniform sampling of stress-free networks. In our model, studied on a diluted triangular lattice, an unusual intermediate phase appears, in which both rigid and floppy networks have a chance to occur, a result also observed in a related model on a Bethe lattice by Barre et al. [Phys. Rev. Lett. 94, 208701 (2005)]. Our results for the bond-configurational entropy of self-organized networks, which turns out to be only about 2% lower than that of random networks, suggest that a self-organized intermediate phase could be common in systems near the rigidity percolation threshold.Comment: 9 pages, 6 figure

Self-organized criticality in the intermediate phase of rigidity percolation

Experimental results for covalent glasses have highlighted the existence of a new self-organized phase due to the tendency of glass networks to minimize internal stress. Recently, we have shown that an equilibrated self-organized two-dimensional lattice-based model also possesses an intermediate phase in which a percolating rigid cluster exists with a probability between zero and one, depending on the average coordination of the network. In this paper, we study the properties of this intermediate phase in more detail. We find that microscopic perturbations, such as the addition or removal of a single bond, can affect the rigidity of macroscopic regions of the network, in particular, creating or destroying percolation. This, together with a power-law distribution of rigid cluster sizes, suggests that the system is maintained in a critical state on the rigid/floppy boundary throughout the intermediate phase, a behavior similar to self-organized criticality, but, remarkably, in a thermodynamically equilibrated state. The distinction between percolating and non-percolating networks appears physically meaningless, even though the percolating cluster, when it exists, takes up a finite fraction of the network. We point out both similarities and differences between the intermediate phase and the critical point of ordinary percolation models without self-organization. Our results are consistent with an interpretation of recent experiments on the pressure dependence of Raman frequencies in chalcogenide glasses in terms of network homogeneity.Comment: 20 pages, 18 figure

How Do State–Business Relations Shape Sustainable Development?

The achievement of the UN Sustainable Development Goals will depend on the ways in which states and businesses engage with one another. While state–business interactions can take many forms, they inherently involve processes of negotiation through which actors in both camps pursue their own interests. Successfully accelerating sustainability, generating inclusion or reducing inequalities will depend on whether such negotiations build on and support interdependencies, create trust, and develop shared ideas about challenges and potential solutions. But the factors that determine the nature and outcomes of state–business relations are not yet well-enough understood, particularly in relation to goals beyond economic growth, where trade-offs are often more apparent.UK Department for International Developmen

New multivariable capabilities of the INCA program

The INteractive Controls Analysis (INCA) program was developed at NASA's Goddard Space Flight Center to provide a user friendly, efficient environment for the design and analysis of control systems, specifically spacecraft control systems. Since its inception, INCA has found extensive use in the design, development, and analysis of control systems for spacecraft, instruments, robotics, and pointing systems. The (INCA) program was initially developed as a comprehensive classical design analysis tool for small and large order control systems. The latest version of INCA, expected to be released in February of 1990, was expanded to include the capability to perform multivariable controls analysis and design

Addressing Market Constraints to Providing Nutrient-Rich Foods: An Exploration of Market Systems Approaches

This Evidence Report asks how a market systems approach could be applied to improve poor households’ access to nutrient-dense foods. By ‘market systems approach’ we mean methods that identify and address underlying constraints in market transactions, their supporting functions and the institutional environment in which markets operate, and which are preventing markets from delivering desired outcomes. The report builds on a developing body of research on value chain approaches to nutrition, which has highlighted challenges in developing commercially viable business models that can deliver affordable, available, appropriate and acceptable foods. It explores how market systems approaches could be used to improve the diagnosis of constraints preventing a market from achieving these outcomes, and to develop interventions that change the way the market system works. The report does not seek to make specific recommendations for policy or practice, but rather sets out how a market systems approach could be applied to nutrition in different contexts in order to develop such recommendations.UK Department for International Developmen

Asymmetry of jets, lobe size and spectral index in radio galaxies and quasars

We investigate the correlations between spectral index, jet side and extent of the radio lobes for a sample of nearby FRII radio galaxies. In Dennett-Thorpe et al. (1997) we studied a sample of quasars and found that the high surface brightness regions had flatter spectra on the jet side (explicable as a result of Doppler beaming) whilst the extended regions had spectral asymmetries dependent on lobe length. Unified schemes predict that asymmetries due to beaming will be much smaller in narrow-line radio galaxies than in quasars: we therefore investigate in a similar manner, a sample of radio galaxies with detected jets. We find that spectral asymmetries in these objects are uncorrelated with jet sidedness at all brightness levels, but depend on relative lobe volume. Our results are not in conflict with unified schemes, but suggest that the differences between the two samples are due primarily to power or redshift, rather than to orientation. We also show directly that hotspot spectra steepen as a function of radio power or redshift. Whilst a shift in observed frequency due to the redshift may account for some of the steepening, it cannot account for all of it, and a dependence on radio power is required.Comment: accepted for publication in MNRAS, 10 pages; typos/minor correctio

Time Domain Simulations of Arm Locking in LISA

Arm locking is a technique that has been proposed for reducing laser frequency fluctuations in the Laser Interferometer Space Antenna (LISA), a gravitational-wave observatory sensitive in the milliHertz frequency band. Arm locking takes advantage of the geometric stability of the triangular constellation of three spacecraft that comprise LISA to provide a frequency reference with a stability in the LISA measurement band that exceeds that available from a standard reference such as an optical cavity or molecular absorption line. We have implemented a time-domain simulation of arm locking including the expected limiting noise sources (shot noise, clock noise, spacecraft jitter noise, and residual laser frequency noise). The effect of imperfect a priori knowledge of the LISA heterodyne frequencies and the associated 'pulling' of an arm locked laser is included. We find that our implementation meets requirements both on the noise and dynamic range of the laser frequency.Comment: Revised to address reviewer comments. Accepted by Phys. Rev.

Simulator test to study hot-flow problems related to a gas cooled reactor

An advance study of materials, fuel injection, and hot flow problems related to the gas core nuclear rocket is reported. The first task was to test a previously constructed induction heated plasma GCNR simulator above 300 kW. A number of tests are reported operating in the range of 300 kW at 10,000 cps. A second simulator was designed but not constructed for cold-hot visualization studies using louvered walls. A third task was a paper investigation of practical uranium feed systems, including a detailed discussion of related problems. The last assignment resulted in two designs for plasma nozzle test devices that could be operated at 200 atm on hydrogen

Reinforced structural plastics

Reinforced polyimide structures are described. Reinforcing materials are impregnated with a suspension of polyimide prepolymer and bonded together by heat and pressure to form a cured, hard-reinforced, polyimide structure