The FORS1 catalogue of stellar magnetic field measurements

The FORS1 instrument on the ESO Very Large Telescope was used to obtain low-resolution circular polarised spectra of nearly a thousand different stars, with the aim of measuring their mean longitudinal magnetic fields. A catalogue of FORS1 magnetic measurements would provide a valuable resource with which to better understand the strengths and limitations of this instrument and of similar low-dispersion, Cassegrain spectropolarimeters. However, FORS1 data reduction has been carried out by a number of different groups using a variety of reduction and analysis techniques. Our understanding of the instrument and our data reduction techniques have both improved over time. A full re-analysis of FORS1 archive data using a consistent and fully documented algorithm would optimise the accuracy and usefulness of a catalogue of field measurements. Based on the ESO FORS pipeline, we have developed a semi-automatic procedure for magnetic field determinations, which includes self-consistent checks for field detection reliability. We have applied our procedure to the full content of circular spectropolarimetric measurements of the FORS1 archive. We have produced a catalogue of spectro-polarimetric observations and magnetic field measurements for about 1400 observations of about 850 different objects. The spectral type of each object has been accurately classified. We have also been able to test different methods for data reduction is a systematic way. The resulting catalogue has been used to produce an estimator for an upper limit to the uncertainty in a field strength measurement of an early type star as a function of the signal-to-noise ratio of the observation. While FORS1 is not necessarily an optimal instrument for the discovery of weak magnetic fields, it is very useful for the systematic study of larger fields, such as those found in Ap/Bp stars and in white dwarfs.Comment: Accepted for publication by A&

A common behavior in the late X-ray afterglow of energetic GRB-SN systems

The possibility to divide GRBs in different subclasses allow to understand better the physics underlying their emission mechanisms and progenitors. The induced gravitational collapse scenario proposes a binary progenitor to explain the time-sequence in GRBs-SNe. We show the existence of a common behavior of the late decay of the X-ray afterglow emission of this subclass of GRBs, pointing to a common physical mechanism of their late emission, consistent with the IGC picture.Comment: 3 pages, to appear in the proceedings of the Gamma-Ray Burst Symposium 2012 - IAA-CSIC - Marbella, editors: Castro-Tirado, A. J., Gorosabel, J. and Park, I.

Induced gravitational collapse at extreme cosmological distances: the case of GRB 090423

CONTEXT: The induced gravitational collapse (IGC) scenario has been introduced in order to explain the most energetic gamma ray bursts (GRBs), Eiso=10^{52}-10^{54}erg, associated with type Ib/c supernovae (SNe). It has led to the concept of binary-driven hypernovae (BdHNe) originating in a tight binary system composed by a FeCO core on the verge of a SN explosion and a companion neutron star (NS). Their evolution is characterized by a rapid sequence of events: [...]. AIMS: We investigate whether GRB 090423, one of the farthest observed GRB at z=8.2, is a member of the BdHN family. METHODS: We compare and contrast the spectra, the luminosity evolution and the detectability in the observations by Swift of GRB 090423 with the corresponding ones of the best known BdHN case, GRB 090618. RESULTS: Identification of constant slope power-law behavior in the late X-ray emission of GRB 090423 and its overlapping with the corresponding one in GRB 090618, measured in a common rest frame, represents the main result of this article. This result represents a very significant step on the way to using the scaling law properties, proven in Episode 3 of this BdHN family, as a cosmological standard candle. CONCLUSIONS: Having identified GRB 090423 as a member of the BdHN family, we can conclude that SN events, leading to NS formation, can already occur already at z=8.2, namely at 650 Myr after the Big Bang. It is then possible that these BdHNe originate stem from 40-60 M_{\odot} binaries. They are probing the Population II stars after the completion and possible disappearance of Population III stars.Comment: 9 pages, 9 figures, to appear on A&

A white dwarf merger as progenitor of the anomalous X-ray pulsar 4U 0142+61?

It has been recently proposed that massive fast-rotating highly-magnetized white dwarfs could describe the observational properties of some of Soft Gamma-Ray Repeaters (SGRs) and Anomalous X-Ray Pulsars (AXPs). Moreover, it has also been shown that high-field magnetic (HFMWDs) can be the outcome of white dwarf binary mergers. The products of these mergers consist of a hot central white dwarf surrounded by a rapidly rotating disk. Here we show that the merger of a double degenerate system can explain the characteristics of the peculiar AXP 4U 0142+61. This scenario accounts for the observed infrared excess. We also show that the observed properties of 4U 0142+6 are consistent with an approximately 1.2 M_{\sun} white dwarf, remnant of the coalescence of an original system made of two white dwarfs of masses 0.6\, M_{\sun} and 1.0\, M_{\sun}. Finally, we infer a post-merging age $\tau_{\rm WD}\approx 64$ kyr, and a magnetic field $B\approx 2\times 10^8$ G. Evidence for such a magnetic field may come from the possible detection of the electron cyclotron absorption feature observed between the $B$ and $V$ bands at $\approx 10^{15}$ Hz in the spectrum of 4U 0142+61.Comment: to appear in ApJ Letter

Early optical spectra of nova V1369 Cen show presence of Lithium

We present early high resolution spectroscopic observations of the nova V1369 Cen. We have detected an absorption feature at 6695.6 \AA\, that we have identified as blue--shifted $^7$Li I $\lambda$6708 \AA. The absorption line, moving at -550 km/s, was observed in five high-resolution spectra of the nova obtained at different epochs. On the basis of the intensity of this absorption line we infer that a single nova outburst can inject in the Galaxy $M_{Li} =$ 0.3 - 4.8 $\times 10^{-10}$ M$_{\odot}$. Given the current estimates of Galactic nova rate, this amount is sufficient to explain the puzzling origin of the overabundance of Lithium observed in young star populations.Comment: 6 pages, 5 figures, accepted for publication in ApJLetter

Endocrine Disruptors and Leydig Cell Function

During the past decades, a large body of information concerning the effects of endocrine disrupting compounds (EDCs) on animals and humans has been accumulated. EDCs are of synthetic or natural origin and certain groups are known to disrupt the action of androgens and to impair the development of the male reproductive tract and external genitalia. The present overview describes the effects of the different classes of EDCs, such as pesticides, phthalates, dioxins, and phytoestrogens, including newly synthesized resveratrol analogs on steroidogenesis in Leydig cells. The potential impact of these compounds on androgen production by Leydig cells during fetal development and in the adult age is discussed. In addition, the possible role of EDCs in connection with the increasing frequency of abnormalities in reproductive development in animals and humans is discussed

Target analysis and retrospective screening of multiple mycotoxins in pet food using UHPLC-Q-Orbitrap HRMS

A comprehensive strategy combining a quantitative method for 28 mycotoxins and a post-target screening for other 245 fungal and bacterial metabolites in dry pet food samples were developed using an acetonitrile-based extraction and an ultrahigh-performance liquid chromatography coupled to high-resolution mass spectrometry (UHPLC-Q-Orbitrap HRMS) method. The proposed method showed satisfactory validation results according to Commission Decision 2002/657/EC. Average recoveries from 72 to 108% were obtained for all studied mycotoxins, and the intra-/inter-day precision were below 9 and 14%, respectively. Results showed mycotoxin contamination in 99% of pet food samples (n = 89) at concentrations of up to hundreds µg/kg, with emerging Fusarium mycotoxins being the most commonly detected mycotoxins. All positive samples showed co-occurrence of mycotoxins with the simultaneous presence of up to 16 analytes per sample. In the retrospective screening, up to 54 fungal metabolites were tentatively identified being cyclopiazonic acid, paspalitrem A, fusaric acid, and macrosporin, the most commonly detected analytes

Simultaneous determination of afb1 and afm1 in milk samples by ultra high performance liquid chromatography coupled to quadrupole orbitrap mass spectrometry

Milk is the world’s most consumed beverage, not counting water. Even though investigations on milk aflatoxin (AF) M1 contamination are regularly conducted, there is limited information on the contamination of milk with its parent compound, AFB1. Hence, the aim of this study was to develop a quick, easy, cheap, effective, rugged, and safe (QuEChERS)-based method for the simultaneous analysis of AFB1 and AFM1 in milk, using ultrahigh performance liquid chromatography coupled with high resolution mass spectrometry (UHPLC-Q-Orbitrap HRMS). The recoveries were in a range of 75–96% at 0.005, 0.01, and 0.05 µg/L spiking levels, with repeatability and reproducibility results expressed as relative standard deviations (RSDs) lower than 7% and 16%, respectively. The limits of detection (LODs) and quantification (LOQs) were 0.001 and 0.002 µg/L for AFM1 and AFB1, respectively. The LODs and LOQs that were obtained showed the suitability of the developed method for the determination of trace amounts of the selected mycotoxins in milk samples, and were up to ten times lower than those that had been reported in previous works using triple quadrupole mass analyzers. The matrix effect was evaluated and matrix-matched calibrations were used for quantification. The validated method was applied to 40 Italian milk samples. Neither AFB1 nor AFM1 were found above the LOD in any of the analyzed samples

Target analysis and retrospective screening of mycotoxins and pharmacologically active substances in milk using an ultra-high-performance liquid chromatography/high-resolution mass spectrometry approach

Milk is a nutritious food suitable for infants and adults, and it plays an important role in the human diet. However, it may also be a vehicle for food contaminants. In this report, we developed a method using ultra-high-performance liquid chromatography coupled with high-resolution mass spectrometry (UHPLC-Q-Exactive Orbitrap HRMS; Thermo Fisher Scientific, Waltham, MA) for simultaneous identification of target pharmacologically active substances and mycotoxins in milk. We also used the Q-Orbitrap operating in full scan mode to identify other possible drugs and microbial metabolites that occurred in samples. Fifty-six commercially available milk samples from the Italian market were analyzed. Investigated analytes were extracted using a QuEChERS (quick, easy, cheap, effective, rugged, and safe) approach. Method detection and quantification limits and performance criteria set by European regulations were fulfilled. Pharmacologically active substances were detected in 49% of samples (range 0.007–4.53 ng/mL), including nontarget mycotoxins. Retrospective analysis allowed us to identify other antibiotics and pharmacologically active substances, as well as nonregulated fungal/bacterial metabolites at a relatively high incidence. From the obtained values, the need for continuous monitoring of contaminants in the milk production chain is clear. This is the first study to assess the presence of pharmacologically active substances, mycotoxins, and other microbial metabolites in Italian milk samples using the UHPLC-Q-Orbitrap HRMS system