Comment on: Failure of the Work-Hamiltonian Connection for Free-Energy Calculations [Phys Rev Lett 100, 020601 (2008), arXiv:0704.0761]

We comment on a Letter by Vilar and Rubi [arXiv:0704.0761].Comment: one page, including one figure; to appear in Phys Rev Let

A quantum version of free energy - irreversible work relations

We give a quantum version of the Jarzynski relation between the distribution of work done over a certain time-interval on a system and the difference of equilibrium free energies. The main new ingredient is the identification of work depending on the quantum history of the system and the proper definition of various quantum ensembles over which the averages should be made. We also discuss a number of different regimes that have been considered by other authors and which are unified in the present set-up. In all cases, and quantum or classical, it is a general relation between heat and time-reversal that makes the Jarzynski relation so universally valid

Fluctuation Theorem in Rachet System

Fluctuation Theorem(FT) has been studied as far from equilibrium theorem, which relates the symmetry of entropy production. To investigate the application of this theorem, especially to biological physics, we consider the FT for tilted rachet system. Under, natural assumption, FT for steady state is derived.Comment: 6 pages, 2 figure

Shortcuts to Thermodynamic Computing: The Cost of Fast and Faithful Erasure

Landauer's Principle states that the energy cost of information processing must exceed the product of the temperature and the change in Shannon entropy of the information-bearing degrees of freedom. However, this lower bound is achievable only for quasistatic, near-equilibrium computations -- that is, only over infinite time. In practice, information processing takes place in finite time, resulting in dissipation and potentially unreliable logical outcomes. For overdamped Langevin dynamics, we show that counterdiabatic potentials can be crafted to guide systems rapidly and accurately along desired computational paths, providing shortcuts that allows for the precise design of finite-time computations. Such shortcuts require additional work, beyond Landauer's bound, that is irretrievably dissipated into the environment. We show that this dissipated work is proportional to the computation rate as well as the square of the information-storing system's length scale. As a paradigmatic example, we design shortcuts to erase a bit of information metastably stored in a double-well potential. Though dissipated work generally increases with erasure fidelity, we show that it is possible perform perfect erasure in finite time with finite work. We also show that the robustness of information storage affects the energetic cost of erasure---specifically, the dissipated work scales as the information lifetime of the bistable system. Our analysis exposes a rich and nuanced relationship between work, speed, size of the information-bearing degrees of freedom, storage robustness, and the difference between initial and final informational statistics.Comment: 19 pages, 7 figures; http://csc.ucdavis.edu/~cmg/compmech/pubs/scte.ht

Fluctuation theorems: Work is not an observable

The characteristic function of the work performed by an external time-dependent force on a Hamiltonian quantum system is identified with the time-ordered correlation function of the exponentiated system's Hamiltonian. A similar expression is obtained for the averaged exponential work which is related to the free energy difference of equilibrium systems by the Jarzynski work theorem

Probability distributions of the work in the 2D-Ising model

Probability distributions of the magnetic work are computed for the 2D Ising model by means of Monte Carlo simulations. The system is first prepared at equilibrium for three temperatures below, at and above the critical point. A magnetic field is then applied and grown linearly at different rates. Probability distributions of the work are stored and free energy differences computed using the Jarzynski equality. Consistency is checked and the dynamics of the system is analyzed. Free energies and dissipated works are reproduced with simple models. The critical exponent $\delta$ is estimated in an usual manner.Comment: 12 pages, 6 figures. Comments are welcom

Directed flow in non-adiabatic stochastic pumps

We analyze the operation of a molecular machine driven by the non-adiabatic variation of external parameters. We derive a formula for the integrated flow from one configuration to another, obtain a "no-pumping theorem" for cyclic processes with thermally activated transitions, and show that in the adiabatic limit the pumped current is given by a geometric expression.Comment: 5 pages, 2 figures, very minor change

Statistical properties of entropy production derived from fluctuation theorems

Several implications of well-known fluctuation theorems, on the statistical properties of the entropy production, are studied using various approaches. We begin by deriving a tight lower bound on the variance of the entropy production for a given mean of this random variable. It is shown that the Evans-Searles fluctuation theorem alone imposes a significant lower bound on the variance only when the mean entropy production is very small. It is then nonetheless demonstrated that upon incorporating additional information concerning the entropy production, this lower bound can be significantly improved, so as to capture extensivity properties. Another important aspect of the fluctuation properties of the entropy production is the relationship between the mean and the variance, on the one hand, and the probability of the event where the entropy production is negative, on the other hand. Accordingly, we derive upper and lower bounds on this probability in terms of the mean and the variance. These bounds are tighter than previous bounds that can be found in the literature. Moreover, they are tight in the sense that there exist probability distributions, satisfying the Evans-Searles fluctuation theorem, that achieve them with equality. Finally, we present a general method for generating a wide class of inequalities that must be satisfied by the entropy production. We use this method to derive several new inequalities which go beyond the standard derivation of the second law.Comment: 14 pages, 1 figure; Submitted to Journal of Statistical Mechanios: Theory and Experimen

Work distribution functions for hysteresis loops in a single-spin system

We compute the distribution of the work done in driving a single Ising spin with a time-dependent magnetic field. Using Glauber dynamics we perform Monte-Carlo simulations to find the work distributions at different driving rates. We find that in general the work-distributions are broad with a significant probability for processes with negative dissipated work. The special cases of slow and fast driving rates are studied analytically. We verify that various work fluctuation theorems corresponding to equilibrium initial states are satisfied while a steady state version is not.Comment: 9 pages, 15 figure

Jarzynski Equality for an Energy-Controlled System

The Jarzynski equality (JE) is known as an exact identity for nonequillibrium systems. The JE was originally formulated for isolated and isothermal systems, while Adib reported an JE extended to an isoenergetic process. In this paper, we extend the JE to an energy-controlled system. We make it possible to control the instantaneous value of the energy arbitrarily in a nonequilibrium process. Under our extension, the new JE is more practical and useful to calculate the number of states and the entropy than the isoenergetic one. We also show application of our JE to a kind of optimization problems.Comment: 6 pages, 1 figur