Note on the derivative of the hyperbolic cotangent

In a letter to Nature (Ford G W and O'Connell R F 1996 Nature 380 113) we presented a formula for the derivative of the hyperbolic cotangent that differs from the standard one in the literature by an additional term proportional to the Dirac delta function. Since our letter was necessarily brief, shortly after its appearance we prepared a more extensive unpublished note giving a detailed explanation of our argument. Since this note has been referenced in a recent article (Estrada R and Fulling S A 2002 J. Phys. A: Math. Gen. 35 3079) we think it appropriate that it now appear in print. We have made no alteration to the original note

Use of mathematical derivatives (time-domain differentiation) on chromatographic data to enhance the detection and quantification of an unknown 'rider' peak

Two samples of an anticancer prodrug, AQ4N, were submitted for HPLC assay and showed an unidentified impurity that eluted as a 'rider' on the tail of the main peak. Mathematical derivatization of the chromatograms offered several advantages over conventional skimmed integration. A combination of the second derivative amplitude and simple linear regression gave a novel method for estimating the true peak area of the impurity peak. All the calculation steps were carried out using a widely available spreadsheet program. (C) 2003 Elsevier B.V. All rights reserved

Contributions of Vacuum and Plasmon Modes to the Force on a Small Sphere near a Plate

The force on a small sphere with a plasma model dielectric function and in the presence of a perfectly reflecting plane is considered. The contribution of both the vacuum modes of the quantized electromagnetic field and of plasmon modes in the sphere are discussed. In the case that the plasmon modes are in their ground state, quasi-oscillatory terms from the vacuum and plasmon parts cancel one another, leading a monotonic attractive force. If the plasmon modes are not in the ground state, the net force is quasi-oscillatory. In both cases, the sphere behaves in the same way as does an atom in either its ground state or an excited state.Comment: 7 pages, no figures, talk presented at "Quantum Fields under External Conditions - 2005", Barcelona, Spain, September 200

Lightcone fluctuations in flat spacetimes with nontrivial topology

The quantum lightcone fluctuations in flat spacetimes with compactified spatial dimensions or with boundaries are examined. The discussion is based upon a model in which the source of the underlying metric fluctuations is taken to be quantized linear perturbations of the gravitational field. General expressions are derived, in the transverse trace-free gauge, for the summation of graviton polarization tensors, and for vacuum graviton two-point functions. Because of the fluctuating light cone, the flight time of photons between a source and a detector may be either longer or shorter than the light propagation time in the background classical spacetime. We calculate the mean deviations from the classical propagation time of photons due to the changes in the topology of the flat spacetime. These deviations are in general larger in the directions in which topology changes occur and are typically of the order of the Planck time, but they can get larger as the travel distance increases.Comment: 25 pages, 5 figures, some discussions added and a few typos corrected, final version to appear in Phys. Rev.

The Paradox of Virtual Dipoles in the Einstein Action

The functional integral of pure Einstein 4D quantum gravity admits abnormally large and long-lasting "dipolar fluctuations", generated by virtual sources with the property Int d^4x Sqrt{g(x)} Tr T(x) = 0. These fluctuations would exist also at macroscopic scales, with paradoxical consequences. We set out their general features and give numerical estimates of possible suppression processes.Comment: LaTeX, 5 pages; reference adde

A Causal Algebra for Liouville Exponentials

A causal Poisson bracket algebra for Liouville exponentials on a cylinder is derived using an exchange algebra for free fields describing the in and out asymptotics. The causal algebra involves an even number of space-time points with a minimum of four. A quantum realisation of the algebra is obtained which preserves causality and the local form of non-equal time brackets.Comment: 10 page

Quantum measurement and decoherence

Distribution functions defined in accord with the quantum theory of measurement are combined with results obtained from the quantum Langevin equation to discuss decoherence in quantum Brownian motion. Closed form expressions for wave packet spreading and the attenuation of coherence of a pair of wave packets are obtained. The results are exact within the context of linear passive dissipation. It is shown that, contrary to widely accepted current belief, decoherence can occur at high temperature in the absence of dissipation. Expressions for the decoherence time with and without dissipation are obtained that differ from those appearing in earlier discussions

Wigner Distribution Function Approach to Dissipative Problems in Quantum Mechanics with emphasis on Decoherence and Measurement Theory

We first review the usefulness of the Wigner distribution functions (WDF), associated with Lindblad and pre-master equations, for analyzing a host of problems in Quantum Optics where dissipation plays a major role, an arena where weak coupling and long-time approximations are valid. However, we also show their limitations for the discussion of decoherence, which is generally a short-time phenomenon with decay rates typically much smaller than typical dissipative decay rates. We discuss two approaches to the problem both of which use a quantum Langevin equation (QLE) as a starting-point: (a) use of a reduced WDF but in the context of an exact master equation (b) use of a WDF for the complete system corresponding to entanglement at all times