Inelastic fingerprints of hydrogen contamination in atomic gold wire systems

We present series of first-principles calculations for both pure and hydrogen contaminated gold wire systems in order to investigate how such impurities can be detected. We show how a single H atom or a single H2 molecule in an atomic gold wire will affect forces and Au-Au atom distances under elongation. We further determine the corresponding evolution of the low-bias conductance as well as the inelastic contributions from vibrations. Our results indicate that the conductance of gold wires is only slightly reduced from the conductance quantum G0=2e^2/h by the presence of a single hydrogen impurity, hence making it difficult to use the conductance itself to distinguish between various configurations. On the other hand, our calculations of the inelastic signals predict significant differences between pure and hydrogen contaminated wires, and, importantly, between atomic and molecular forms of the impurity. A detailed characterization of gold wires with a hydrogen impurity should therefore be possible from the strain dependence of the inelastic signals in the conductance.Comment: 5 pages, 3 figures, Contribution to ICN+T2006, Basel, Switzerland, July-August 200

The retina visual cycle is driven by cis retinol oxidation in the outer segments of cones

Vertebrate rod and cone photoreceptors require continuous supply of chromophore for regenerating their visual pigments after photoactivation. Cones, which mediate our daytime vision, demand a particularly rapid supply of 11-cis retinal chromophore in order to maintain their function in bright light. An important contribution to this process is thought to be the chromophore precursor 11-cis retinol, which is supplied to cones from Müller cells in the retina and subsequently oxidized to 11-cis retinal as part of the retina visual cycle. However, the molecular identity of the cis retinol oxidase in cones remains unclear. Here, as a first step in characterizing this enzymatic reaction, we sought to determine the subcellular localization of this activity in salamander red cones. We found that the onset of dark adaptation of isolated salamander red cones was substantially faster when exposing directly their outer vs. their inner segment to 9-cis retinol, an analogue of 11-cis retinol. In contrast, this difference was not observed when treating the outer vs. inner segment with 9-cis retinal, a chromophore analogue which can directly support pigment regeneration. These results suggest, surprisingly, that the cis-retinol oxidation occurs in the outer segments of cone photoreceptors. Confirming this notion, pigment regeneration with exogenously added 9-cis retinol was directly observed in the truncated outer segments of cones, but not in rods. We conclude that the enzymatic machinery required for the oxidation of recycled cis retinol as part of the retina visual cycle is present in the outer segments of cones

In-situ Particle Acceleration in Collisionless Shocks

The outflows from gamma ray bursts, active galactic nuclei and relativistic jets in general interact with the surrounding media through collisionless shocks. With three dimensional relativistic particle-in-cell simulations we investigate such shocks. The results from these experiments show that small--scale magnetic filaments with strengths of up to percents of equipartition are generated and that electrons are accelerated to power law distributions N(E)~E^{-p} in the vicinity of the filaments through a new acceleration mechanism. The acceleration is locally confined, instantaneous and differs from recursive acceleration processes such as Fermi acceleration. We find that the proposed acceleration mechanism competes with thermalization and becomes important at high Lorentz factors.Comment: 4 pages, 2 figures, submitted to Il nuovo cimento (4th Workshop Gamma-Ray Bursts in the Afterglow Era, Rome, 18-22 October 2004

Non-Fermi Power law Acceleration in Astrophysical Plasma Shocks

Collisionless plasma shock theory, which applies for example to the afterglow of gamma ray bursts, still contains key issues that are poorly understood. In this paper we study charged particle dynamics in a highly relativistic collisionless shock numerically using ~10^9 particles. We find a power law distribution of accelerated electrons, which upon detailed investigation turns out to originate from an acceleration mechanism that is decidedly different from Fermi acceleration. Electrons are accelerated by strong filamentation instabilities in the shocked interpenetrating plasmas and coincide spatially with the power law distributed current filamentary structures. These structures are an inevitable consequence of the now well established Weibel-like two-stream instability that operates in relativistic collisionless shocks. The electrons are accelerated and decelerated instantaneously and locally; a scenery that differs qualitatively from recursive acceleration mechanisms such as Fermi acceleration. The slopes of the electron distribution power laws are in concordance with the particle power law spectra inferred from observed afterglow synchrotron radiation in gamma ray bursts, and the mechanism can possibly explain more generally the origin of non-thermal radiation from shocked inter- and circum-stellar regions and from relativistic jets.Comment: 4 pages accepted for publication in ApJ Letters. High resolution figures are available online at http://www.astro.ku.dk/users/hededal/040855

Phonon-induced linewidths of graphene electronic states

The linewidths of the electronic bands originating from the electron-phonon coupling in graphene are analyzed based on model tight-binding calculations and experimental angle-resolved photoemission spectroscopy (ARPES) data. Our calculations confirm the prediction that the high-energy optical phonons provide the most essential contribution to the phonon-induced linewidth of the two upper occupied $\sigma$ bands near the $\bar{\Gamma}$-point. For larger binding energies of these bands, as well as for the $\pi$ band, we find evidence for a substantial lifetime broadening from interband scattering $\pi \rightarrow \sigma$ and $\sigma \rightarrow \pi$, respectively, driven by the out-of-plane ZA acoustic phonons. The essential features of the calculated $\sigma$ band linewidths are in agreement with recent published ARPES data [F. Mazzola et al., Phys.~Rev.~B. 95, 075430 (2017)] and of the $\pi$ band linewidth with ARPES data presented here.Comment: 7 pages, 4 figure

Controlled Contact to a C60 Molecule

The conductance of C60 on Cu(100) is investigated with a low-temperature scanning tunneling microscope. At the transition from tunneling to the contact regime the conductance of C60 adsorbed with a pentagon-hexagon bond rises rapidly to 0.25 conductance quanta G0. An abrupt conductance jump to G0 is observed upon further decreasing the distance between the instrument's tip and the surface. Ab-initio calculations within density functional theory and non-equilibrium Green's function techniques explain the experimental data in terms of the conductance of an essentially undeformed C60. From a detailed analysis of the crossover from tunneling to contact we conclude that the conductance in this region is strongly affected by structural fluctuations which modulate the tip-molecule distance.Comment: 4 pages, 3 figure