Dicarba-closo-dodecarborane-containing half-sandwich complexes of ruthenium, osmium, rhodium and iridium : biological relevance and synthetic strategies

This review describes how the incorporation of dicarba-closo-dodecarboranes into half-sandwich complexes of ruthenium, osmium, rhodium and iridium might lead to the development of a new class of compounds with applications in medicine. Such a combination not only has unexplored potential in traditional areas such as Boron Neutron Capture Therapy agents, but also as pharmacophores for the targeting of biologically important proteins and the development of targeted drugs. The synthetic pathways used for the syntheses of dicarba-closo-dodecarboranes-containing half-sandwich complexes of ruthenium, osmium, rhodium and iridium are also reviewed. Complexes with a wide variety of geometries and characteristics can be prepared. Examples of addition reactions on the metal centre, B–H activation, transmetalation reactions and/or direct formation of metal–metal bonds are discussed (103 references)

New Internal Stress Driven on-Chip Micromachines for Extracting Mechanical Properties of Thin Films

A new concept of micromachines has been developed for measuring the mechanical properties of thin metallic films. The actuator is a beam undergoing large internal stresses built up during the deposition process. Al thin films are deposited partly on the actuator beam and on the substrate. By etching the structure, the actuator contracts and pulls the Al film. Full stress strain curves can be generated by designing a set of micromachines with various actuator lengths. In the present study, the displacements have been measured by scanning electronic microscopy. The stress is derived from simple continuum mechanics relationships. The tensile properties of Al films of various thicknesses have been tested. A marked increase of the strength with decreasing film thickness is observed.Comment: Submitted on behalf of TIMA Editions (http://irevues.inist.fr/tima-editions

Non-Existence of Time-Periodic Solutions of the Dirac Equation in a Reissner-Nordstrom Black Hole Background

It is shown analytically that the Dirac equation has no normalizable, time-periodic solutions in a Reissner-Nordstrom black hole background; in particular, there are no static solutions of the Dirac equation in such a background field. The physical interpretation is that Dirac particles can either disappear into the black hole or escape to infinity, but they cannot stay on a periodic orbit around the black hole.Comment: 24 pages, 2 figures (published version

An alternative approach to efficient simulation of micro/nanoscale phonon transport

Starting from the recently proposed energy-based deviational formulation for solving the Boltzmann equation [J.-P. Peraud and N. G. Hadjiconstantinou, Phys. Rev. B 84, 2011], which provides significant computational speedup compared to standard Monte Carlo methods for small deviations from equilibrium, we show that additional computational benefits are possible in the limit that the governing equation can be linearized. The proposed method exploits the observation that under linearized conditions (small temperature differences) the trajectories of individual deviational particles can be decoupled and thus simulated independently; this leads to a particularly simple and efficient algorithm for simulating steady and transient problems in arbitrary three-dimensional geometries, without introducing any additional approximation.Comment: 4 pages, 2 figure

Protecting clean critical points by local disorder correlations

We show that a broad class of quantum critical points can be stable against locally correlated disorder even if they are unstable against uncorrelated disorder. Although this result seemingly contradicts the Harris criterion, it follows naturally from the absence of a random-mass term in the associated order-parameter field theory. We illustrate the general concept with explicit calculations for quantum spin-chain models. Instead of the infinite-randomness physics induced by uncorrelated disorder, we find that weak locally correlated disorder is irrelevant. For larger disorder, we find a line of critical points with unusual properties such as an increase of the entanglement entropy with the disorder strength. We also propose experimental realizations in the context of quantum magnetism and cold-atom physics.Comment: 5 pages, 3 figures; published versio

A quantum de Finetti theorem in phase space representation

The quantum versions of de Finetti's theorem derived so far express the convergence of n-partite symmetric states, i.e., states that are invariant under permutations of their n parties, towards probabilistic mixtures of independent and identically distributed (i.i.d.) states. Unfortunately, these theorems only hold in finite-dimensional Hilbert spaces, and their direct generalization to infinite-dimensional Hilbert spaces is known to fail. Here, we address this problem by considering invariance under orthogonal transformations in phase space instead of permutations in state space, which leads to a new type of quantum de Finetti's theorem that is particularly relevant to continuous-variable systems. Specifically, an n-mode bosonic state that is invariant with respect to this continuous symmetry in phase space is proven to converge towards a probabilistic mixture of i.i.d. Gaussian states (actually, n identical thermal states).Comment: 5 page

Soft-tissue specimens from pre-European extinct birds of New Zealand

We provide the first complete review of soft tissue remains from New Zealand birds that became extinct prior to European settlement (c. AD 1800). These rare specimens allow insights into the anatomy and appearance of the birds that are not attainable from bones. Our review includes previously unpublished records of ‘lost’ specimens, and descriptions of recently discovered specimens such as the first evidence of soft tissues from the South Island goose (Cnemiornis calcitrans). Overall, the soft tissue remains are dominated by moa (with specimens from each of the six genera), but also include specimens from Finsch's duck (Chenonetta finschi) and the New Zealand owlet-nightjar (Aegotheles novaezealandiae). All desiccated soft tissue specimens that have radiocarbon or stratigraphic dates are late Holocene in age, and most have been found in the semi-arid region of Central Otago

Scaling of Entanglement Entropy in the Random Singlet Phase

We present numerical evidences for the logarithmic scaling of the entanglement entropy in critical random spin chains. Very large scale exact diagonalizations performed at the critical XX point up to L=2000 spins 1/2 lead to a perfect agreement with recent real-space renormalization-group predictions of Refael and Moore [Phys. Rev. Lett. {\bf 93}, 260602 (2004)] for the logarithmic scaling of the entanglement entropy in the Random Singlet Phase with an effective central charge ${\tilde{c}}=c\times \ln 2$. Moreover we provide the first visual proof of the existence the Random Singlet Phase thanks to the quantum entanglement concept.Comment: 4 pages, 3 figure