2,653 research outputs found

    Boundary Dynamics Driven Entanglement

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    We will show how it is possible to generate entangled states out of unentangled ones on a bipartite system by means of dynamical boundary conditions. The auxiliary system is defined by a symmetric but not self-adjoint Hamiltonian and the space of self-adjoint extensions of the bipartite system is studied. It is shown that only a small set of them leads to separable dynamics and they are characterized. Various simple examples illustrating this phenomenon are discussed, in particular we will analyze the hybrid system consisting on a planar quantum rotor and a spin system under a wide class of boundary conditions.Comment: 26 pages, 5 figure

    Dynamic heterogeneity in the glass-like monoclinic phases of some halogen methane compounds

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    In this work we study the heterogeneity of the dynamics on the low-temperature monoclinic phases of the simple molecular glassy systems CBrnCl4−nCBrnCl4−n, n = 0, 1, 2. In these systems the disorder comes exclusively from reorientational jumps mainly around the C3 molecular axes. The different time scales are determined by means of the analysis of the spin-lattice relaxation time obtained through Nuclear Quadrupole Resonance (NQR) technique. Results are compared with those obtained from dielectric spectroscopy, from which two α- and β-relaxation times appear. NQR results enable us to ascribe with no doubt that the existence of two relaxations is due to dynamical heterogeneities which are the consequence of the different molecular surroundings of the molecules in the asymmetric unit cell of systems here studied.Fil: Zuriaga, Mariano Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; ArgentinaFil: Perez, S. C.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; ArgentinaFil: Pardo, L. C.. Universidad Politecnica de Catalunya; EspañaFil: Tamarit, J. L.. Universidad Politecnica de Catalunya; Españ

    Gerber–Shiu distribution at Parisian ruin for Lévy insurance risk processes

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    Inspired by works of Landriault et al. [11, 12], we study the Gerber{Shiu distribution at Parisian ruin with exponential implementation delays for a spectrally negative Levy insurance risk process. To be more specific, we study the so-called Gerber{Shiu distribution for a ruin model where at each time the surplus process goes negative, an independent exponential clock is started. If the clock rings before the surplus becomes positive again then the insurance company is ruined. Our methodology uses excursion theory for spectrally negative Levy processes and relies on the theory of so-called scale functions. In particular, we extend recent results of Landriault et al. [11, 12]

    A Synchrotron Mössbauer Spectroscopy Study of a Hydrated Iron-Sulfate at High Pressures

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    Szomolnokite is a monohydrated ferrous iron sulfate mineral, FeSO₄·H₂O, where the ferrous iron atoms are in octahedral coordination with four corners shared with SO4 and two with H₂O groups. While somewhat rare on Earth, szomolnokite has been detected on the surface of Mars along with several other hydrated sulfates and is suggested to occur near the surface of Venus. Previous measurements have characterized the local environment of the iron atoms in szomolnokite using Mössbauer spectroscopy at a range of temperatures and 1 bar. Our study represents a step towards understanding the electronic environment of iron in szomolnokite under compression at 300 K. Using a hydrostatic helium pressure-transmitting medium, we explored the pressure dependence of iron’s site-specific behavior in a synthetic szomolnokite powdered sample up to 95 GPa with time-domain synchrotron Mössbauer spectroscopy. At 1 bar, the Mössbauer spectrum is well described by two Fe²⁺-like sites and no ferric iron, consistent with select conventional Mössbauer spectra evaluations. At pressures below 19 GPa, steep gradients in the hyperfine parameters are most likely due to a structural phase transition. At 19 GPa, a fourth site is required to explain the time spectrum with increasing fractions of a low quadrupole splitting site, which could indicate the onset of another transition. Above 19 GPa we present three different models, including those with a high- to low-spin transition, that provide reasonable scenarios of electronic environment changes of the iron in szomolnokite with pressure. We summarize the complex range of Fe²⁺ spin transition characteristics at high-pressures by comparing szomolnokite with previous studies on ferrous-iron bearing phases
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