Kinetic conversion of CO to CH4 in the Solar System

Some of the most interesting chemistry in the Solar System involves changes in the oxidation state of the simple carbon species. The chemical pathways for the conversion of CH4 to CO and CO2 are for the most part known. The reverse process, the reduction of CO to CH4, is, however, poorly understood. This is surprising in view of the importance of the reduction process in the chemistry of the Solar System. Recently we investigated the chemical kinetics of a hitherto unsuspected reaction. It is argued that the formation of the methoxy radical (CH3O) from H+H2CO may play an essential role in the reduction of CO to CH4. The rate coefficient for this reaction has been estimated using the approximate theory of J. Troe and transition state theory. We will discuss the implications of this reaction for the chemistry of CO on Jupiter, in the solar nebula, for interpreting the laboratory experiments of A. Bar-Nun and A. Shaviv and A. Bar-Nun and S. Chang, and for organic synthesis in the prebiotic terrestrial atmosphere. The possible relation of CO reduction in the solar nebula and polyoxymethylene observed in comet Halley will be discussed

ARPES and NMTO Wannier Orbital Theory of LiMo6_{6}O17_{17} - Implications for Unusually Robust Quasi-One Dimensional Behavior

We present the results of a combined study by band theory and angle resolved photoemission spectroscopy (ARPES) of the purple bronze, Li$_{1-x}$Mo$_{6}$O$_{17}$. Structural and electronic origins of its unusually robust quasi-one dimensional (quasi-1D) behavior are investigated in detail. The band structure, in a large energy window around the Fermi energy, is basically 2D and formed by three Mo $t_{2g}$-like extended Wannier orbitals, each one giving rise to a 1D band running at a 120$^\circ$ angle to the two others. A structural "dimerization" from $\mathbf{c}/2$ to $\mathbf{c}$ gaps the $xz$ and $yz$ bands while leaving the $xy$ bands metallic in the gap, but resonantly coupled to the gap edges and, hence, to the other directions. The resulting complex shape of the quasi-1D Fermi surface (FS), verified by our ARPES, thus depends strongly on the Fermi energy position in the gap, implying a great sensitivity to Li stoichiometry of properties dependent on the FS, such as FS nesting or superconductivity. The strong resonances prevent either a two-band tight-binding model or a related real-space ladder picture from giving a valid description of the low-energy electronic structure. We use our extended knowledge of the electronic structure to newly advocate for framing LiMo$_{6}$O$_{17}$ as a weak-coupling material and in that framework can rationalize both the robustness of its quasi-1D behavior and the rather large value of its Luttinger liquid (LL) exponent $\alpha$. Down to a temperature of 6$\,$K we find no evidence for a theoretically expected downward renormalization of perpendicular single particle hopping due to LL fluctuations in the quasi-1D chains.Comment: 53 pages, 17 Figures, 6 year

Matter-wave bistability in coupled atom-molecule quantum gases

We study the matter-wave bistability in coupled atom-molecule quantum gases, in which heteronuclear molecules are created via an interspecies Feshbach resonance involving either two-species Bose or two-species Fermi atoms at zero temperature. We show that the resonant two-channel Bose model is equivalent to the nondegenerate parametric down-conversion in quantum optics, while the corresponding Fermi model can be mapped to a quantum optics model that describes a single-mode laser field interacting with an ensemble of inhomogeneously broadened two-level atoms. Using these analogy and the fact that both models are subject to the Kerr nonlinearity due to the two-body s-wave collisions, we show that under proper conditions, the population in the molecular state in both models can be made to change with the Feshbach detuning in a bistable fashion.Comment: 6 pages, 5 figure

Spatio-temporal vortex beams and angular momentum

We present a space-time generalization of the known spatial (monochromatic) wave vortex beams carrying intrinsic orbital angular momentum (OAM) along the propagation direction. Generic spatio-temporal vortex beams are polychromatic and can carry intrinsic OAM at an arbitrary angle to the mean momentum. Applying either (i) a transverse wave-vector shift or (ii) a Lorentz boost to a monochromatic Bessel beam, we construct a family of either (i) time-diffracting or (ii) non-diffracting spatio-temporal Bessel beams, which are exact solutions of the Klein-Gordon wave equations. The proposed spatio-temporal OAM states are able to describe either photon or electron vortex states (both relativistic and nonrelativistic), and can find applications in particle collisions, optics of moving media, quantum communications, and astrophysics.Comment: 9 pages, 6 figures, to appear in Phys. Rev.

Non-degenerate four-wave mixing in rubidium vapor: transient regime

We investigate the transient response of the generated light from Four-Wave Mixing (FWM) in the diamond configuration using a step-down field excitation. The transients show fast decay times and oscillations that depend on the detunings and intensities of the fields. A simplified model taking into account the thermal motion of the atoms, propagation, absorption and dispersion effects shows qualitative agreement with the experimental observations with the energy levels in rubidium (5S1/2, 5P1/2, 5P3/2 and 6S1/2). The atomic polarization comes from all the contributions of different velocity classes of atoms in the ensemble modifying dramatically the total transient behavior of the light from FWM.Comment: 11 pages, 11 figures, to be published in Physical Review

Resistive destabilization of cycloidal electron flow and universality of (near‐) Brillouin flow in a crossed‐field gap

It is shown that a small amount of dissipation, caused by current flow in a lossy external circuit, can produce a disruption of steady‐state cycloidal electron flow in a crossed‐field gap, leading to the establishment of a turbulent steady state that is close to, but not exactly, Brillouin flow. This disruption, which has nothing to do with a diocotron or cyclotron instability, is fundamentally caused by the failure of a subset of the emitted electrons to return to the cathode surface as a result of resistive dissipation. This mechanism was revealed in particle simulations, and was confirmed by an analytic theory. These near‐Brillouin states differ in several interesting respects from classic Brillouin flow, the most important of which is the presence of a microsheath and a time‐varying potential minimum very close to the cathode surface. They are essentially identical to that produced when (i) injected current exceeds a certain critical value [P. J. Christenson and Y. Y. Lau, Phys. Plasmas 1, 3725 (1994)] or (ii) a small rf electric field is applied to the gap [P. J. Christenson and Y. Y. Lau, Phys. Rev. Lett. 76, 3324 (1996)]. It is speculated that such near‐Brillouin states are generic in vacuum crossed‐field devices, due to the ease with which the cycloidal equilibrium can be disrupted. Another novel aspect of this paper is the introduction of transformations by which the nonlinear, coupled partial differential equations in the Eulerian description (equation of motion, continuity equation, Poisson equation, and the circuit equation) are reduced to an equivalent system of very simple linear ordinary differential equations. © 1996 American Institute of Physics.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/71350/2/PHPAEN-3-12-4455-1.pd

Investigation of the drivers of logistics outsourcing in the United Kingdom's pharmaceutical manufacturing industry

Logistics outsourcing is a practice commonly used by firms to allow them to access capabilities that they lack internally. Although the main drivers of outsourcing in general are fairly well known, the question of what explains logistics outsourcing decisions within the UK pharmaceutical manufacturing industry, in particular, remains under-researched. Therefore, this study aims to bridge the aforementioned gap in the literature. We surveyed 49 drug manufacturers located in the UK using a web-based questionnaire. The data collected were analysed using logistics regression, exploratory factor analysis, and t-tests. We found that UK drug manufacturers regard improving quality and reliability and reducing logistics costs as the most significant reasons for outsourcing logistics services. We also found a direct positive relationship between the service provider's techno-commercial offerings and delivery performance, and the likelihood of being selected to provide these services. We further explored materials transportation, product delivery, research and development, and clinical trials, which are among the most frequently outsourced logistics activities in the UK pharmaceutical manufacturing industry. The study contributes to the wider literature on logistics outsourcing, and more specifically to that on the UK pharmaceutical manufacturing industry. Findings from this research can also be used to guide outsourcing practitioners’ decisions about the selection of logistics service providers. In addition, the study can help to enhance the service providers' understanding of why firms buy logistics services and which services they are likely to buy

Advanced ceramic coating development for industrial/utility gas turbine applications

The effects of ceramic coatings on the lifetimes of metal turbine components and on the performance of a utility turbine, as well as of the turbine operational cycle on the ceramic coatings were determined. When operating the turbine under conditions of constant cooling flow, the first row blades run 55K cooler, and as a result, have 10 times the creep rupture life, 10 times the low cycle fatigue life and twice the corrosion life with only slight decreases in both specific power and efficiency. When operating the turbine at constant metal temperature and reduced cooling flow, both specific power and efficiency increases, with no change in component lifetime. The most severe thermal transient of the turbine causes the coating bond stresses to approach 60% of the bond strengths. Ceramic coating failures was studied. Analytic models based on fracture mechanics theories, combined with measured properties quantitatively assessed both single and multiple thermal cycle failures which allowed the prediction of coating lifetime. Qualitative models for corrosion failures are also presented

A conjecture on the origin of dark energy

The physical origin of holographic dark energy (HDE) is investigated. The main existing explanations, namely the UV/IR connection argument of Cohen et al, Thomas' bulk holography argument, and Ng's spacetime foam argument, are shown to be not satisfactory. A new explanation of the HDE model is then proposed based on the ideas of Thomas and Ng. It is suggested that the dark energy might originate from the quantum fluctuations of spacetime limited by the event horizon of the universe. Several potential problems of the explanation are also discussed.Comment: 11 pages, no figure